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立方晶系

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The crystal of DPCP-ETSC belongs to the orthorhombic system, space group Pna21, and its lattice parameters are as follows: a=1.1478 (2) nm, b=1.3545 (2) nm, c=1.1994 (2) nm, V=l.8646 (4) nm^3, Z=4, Dc=1.345 g/cm^3,μ=0.194 mm^(-1), F (000)=792, R=0.0345, wR=0.0694. The intermolecular hydrogen bonds led to the formation of chain-like one-dimensional compound along c axis and extended along ab plane to form the wave-like supramolecular structure.

DPCP-ETSC晶体属于正交晶系,Pna21空间群,晶胞参数:a=1.1478(2)nm,b=1.3545(2)nm,c=1.1994(2)nm,V=1.5646(4)nm^3,Z=4,D=1.3459/立方公分,μ=0.194mm^(-1),F(000)=792,R=0.0345,wR=0.0694,此化合物通过分子间氢键形成沿c轴成链状,沿ab平面成波浪状的超分子结构。

In alkali borosilicate system, hexagonal CdS was the main crystalphase, co-precipitated with a little cubic CdS.

碱系中,以六方型CdS为主要晶相的纳米晶体,伴有少量立方型CdS析出。

The crystal belongs to triclinic, space group P-1 with α=0.775 1(2) nm, b=0.837 7(2) nm, c=1.003 7(2) nm,α=75.57(3),β=83.05(3),γ=86.08(3), D=1.296 g/cm^3, Z=2, F(000)=256,μ=0.095 mm^(-1), and the final deviation factor R=0.0545 and wR=0.146 0. X-ray analysis reveals that molecules are linked by intermolecular O-H…O hydrogen bonds formed between the adjacent molecules.

具体测定结果如下:该晶体属于三料晶系,P-1空间群,α=0.7751 (2) nm, b=0.8377 (2) nm, c=1.0037 (2) nm,α=75.57 (3),β=83.05 (3),γ=86.08 (3), D=1.296 g/立方公分,Z=2, F(000)=256,μ=0.095 mm^(-1),最终偏差因子分别为R=0.0545,wR=0.1460.X-射线衍射分析表明,分子之间通过相邻分子间形成的O-H…O氢键相连。

Several factors, such as reacting temperature, the ratio of cerous nitrate with citric acid, drying temperature, and etc.

结果表明,所得CeO2 粒子为立方晶相系,呈球形,平均粒径达到纳米级。

Energy transmission and charge transfer between rare earth ions of nanometer fluorides were discussed.

运用XRD确认了制各所得样品为立方晶系;研究了掺杂体系的光谱性质,并与高温固相法制备的产物进行了比较,讨论了掺杂体系中稀土离子间的能量传递及电荷转移过程。

The numbers of clusters made up of 1551 and 1541 bonded pairs representing the non-crystal structure occupy predominate position and the small numbers of clusters made up of 1431, 1661 and 1441 bonded pairs coexist in the non-crystal system at 4×10〓K/s cooling rate, thus there exist a large number of icosahedra clusters in the non-crystal system. The numbers of clusters made up of 1421 bonded pairs corresponding to the fcc-like structure occupy predominate position and the small numbers of clusters made up of 1422 and 1551 bonded pairs coexist in the crystal system during the 4×10〓K/s cooling process, thus the system can form the regular fcc-like structure.

在4×10〓K/s的冷速下,标征体系非晶结构的五重对称键型1551和1541所形成的小团簇数量在非晶体系中占主导位置,同时还存在少量的1431、1441和1661等其它键型形成的小团簇,这样,体系中含有大量的二十面体团簇结构;在4×10〓K/s的冷速下,标征面心立方结构的1421键型所形成的小团簇数量在晶体中占第一位,同时还存在一定量的1422、1441和1661等其它类型的键对所形成的团簇,体系最终形成面心立方结构。

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