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稳定性

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The results show that the atmosphere has a big influence on the thermal stability of C_(60).C_(60) begins to decompose at 423.5℃in the air,the deomposed peak temperature is 668.5℃,but very stable in the helium atmosphere,only sublimate,the crystal shape of C_(60) has a certain influence to its thermal stability.The synthesized nine kinds of nitro-fullerene derivatives all have good thermal stability and their decomposed peak temperatures all exceed 350℃.The thermal explosion temperature for 5 seconds delay of product 4 is 253℃.The category,number and position of nitryl group in nitro-fullerene derivatives all have influence on their thermal stability.

利用差热分析仪和DSC-TG综合热分析仪对C_(60)及其硝基衍生物的热稳定性进行了研究,结果表明,环境气氛对C_(60)热稳定性影响很大,C_(60)在空气中423.5℃开始分解,放热峰值温度为668.5℃,在氦气中很稳定,仅表现为升华,C_(60)的晶型对其热稳定性也有一定的影响;合成得到的九种硝基富勒烯衍生物都具有较好的热稳定性,分解峰值温度均高于350℃;产物4的5秒爆发点测试结果为253℃。

Advantages include thermal stability, non-wetting and elimination of inclusions from shot.· Roll Caster Tips- Ceramic tips offer improved thermal stability, non-wetting, and contain no shot.· Block Caster Tip- Ceramic tips offer improved thermal stability, increased hot strength and do not outgas.· Belt Caster Tips- Ceramic tips offer improved thermal stability, increased hot strength, non-wetting, and do not outgas.

优势包括热稳定性,非焊接和除去钢丸中的杂物·滚动铸造机刀片——陶瓷刀片提供热稳定性,非焊接,不包括钢丸·块铸造机刀片——陶瓷刀片提供热稳定性,增加热强度,不泄露气体·带式铸造机刀片——陶瓷刀片提供热稳定性,增加热强度,非焊接和不泄露气体。

Through the research of direct search method based on 3D FEM, and its application for the tunnel slope stability analysis, the objectives of this work in this paper are as follows:1. The dynamic programming as well as its application for 3D side slope stability analysis is studied. With the introduction of graph theory concept, one kind of glide pattern of 3D slope is constructed, and the critical slip surface with smallest safety factor is searched with the aid of one auxiliary function including safety factor;2. Using the C++ programming language, the 3D slope stability analysis and the direct search procedure is established, and this method is testified applicably by some contrast analysis, also some influence factor in analysis is discussed;3. Integrated with the different actual situation in tunnel slope, considered its excavation, timbering and rain infiltration, its stability influence and rule is researched used this method, also some processing measure is proposed.

本文通过对三维有限元直接搜索法的研究,并将其应用于隧道边坡的稳定性分析中,主要的研究内容有:1、研究了动态规划原理及其在三维边坡稳定性分析中的应用,引入图论概念,构筑出一种边坡三维滑裂面的滑动模式,借助一个包含安全系数的辅助函数并通过动态搜索求得临界滑裂面与最小安全系数;2、采用C++程序设计语言,编制出边坡三维稳定性分析以及直接搜索法的程序,通过一些算例的对比分析,验证本文方法的适用性,并讨论了三维分析中的一些影响因素。3、结合隧道边坡的不同实际情况,考虑施工开挖过程、衬砌结构及降雨渗流等方面的因素,利用本文方法研究对其稳定性的影响和规律,并提出处理措施

The presterssed anchor cable frame combined with backwall, drainage is necessary due to longtime sability and permanent utilization.Firstly,according the study of engineering of geology situation of the high slope, the mechanism of deformation failure and the major hazard of the high slope of PanMei is analysed comprehensively.And the whole slope is divided into two different geology enginnering areas:Western slope(1160 section plane -1240 section plane)and Eastern slope(1240 section plane -1320 section plane). The result of 3D numerical simulation is the same as geology judgement. Later,slope cut (1:0.75) is implemented based on the engineering comparison and criterion.Meanwhile, Limit equilibrium method , Monte Carlo Probabilistic slope stability the stability , Sensitivity analysis and Finent element method of for assessing the cutted slope stability is carried out. The result indicates that Western slope is instable, Eastern slope is relatively stable.So much attention should be paid to Western slope.Different reinforcement measures in different areas are given according to its stability and meet economical request. Gravity wall is introduced in accordance with landform in order to prevent small falling at the foot of the high slope ,which will be a threat to the high slope stability. Handling measure is also applied to Eastern slope. At last,FLAC3D numerical analysis shows the feasibility and reasonableness of the handling measure of the high slope.

论文首先研究了边坡的工程地质条件,全面分析边坡的变形破坏机制和边坡的主要地质灾害,将边坡分为西段不稳定边坡区(1160剖面~1240剖面)和东段相对稳定边坡区(1240剖面~1320剖面),通过三维数值模拟再现了边坡在自重作用下的破坏机制和过程;在此基础上通过工程类比和规范要求,确定按照1:0.75进行放坡处理,并分析了放坡后边坡的稳定性状况,分别通过极限平衡法、蒙特卡洛法概率分析、参数敏感性分析和有限元稳定性计算等多种方法对边坡在各种工况下的进行稳定性研究,计算结果表明,西段边坡较之东段边坡稳定情况差,是边坡支护的关键之处,而东段边坡相对是稳定的;边坡的综合治理措施选用的是框架锚索并结合挡土墙和排水工程,治理设计根据不同区段的稳定性情况采用不同的支护结构,做到了经济合理的要求;在边坡的坡脚设置重力式挡土墙,防治边坡小规模的崩塌,会对上部的锚索支护护造成不利影响,进而影响边坡的稳定;东段边坡的填方区也给出了治理对策;最后通过三维显示拉各朗日有限差分程序(FLAC3D)模拟了高边坡放坡和支护效果,论证了治理措施的有效性和合理性。

In this thesis,the AM1,MNDO,MINDO/3(mainly AM1)and INDO/S-CI semiempirical MO methods were used toinvestigate the excited-state intramolecular protontransfer reactions of salicylic acid derivatives—salicylic acid,methyl salicylate,salicylaldehyde,o-hydroxyaceto-phenone,salicylamide and 3-hydroxy-picolinamide (6 conformers and 2-3 anion species);2-(2'-hydroxy-5' methylphenyl) benzotriazole(4 conformers),2-(2' hydroxyphenyl) benzimidazole (3 conformers and 3anion species),Bis-2,5-(2-benzoxazolyl)hydroquinone(3 conformers),2-(2'-hydroxyphenyl)benzothiazole(2conformers) and 7-azaindole dimer (2 conformers).Theinvestigations were described as follows.Geometry optimization,relative stability andhydrogen bonding energy First,for sylicylic acid derivative molecules,the AM1,MNDO and MINDO/3 methods were used toinvestigate ground-state geometry optimization,energies,relative stabilities and hydrogen-bondingenergies on the five kinds of the molecules(designing 6 conformers and 2-3 anion species).Comparing with experimental data,the optimizedgeometry,the order of stability,the hydrogen-bonding energies and the distances between O-O in O-H..O hydrogen bonds by AM1 method were in agreementwith the experimental data,however,the C-C bondlengths optimized by MNDO and MINDO/3 were longer,C-O and O-H bond lengths were shorter;for C-N bondlengths,the results opitimized by MNDO method werethe same as those by AM1 method,nevertheless the C-Nbond lengths given by MINDO/3 method were muchshorter.For some sylicylic acid derivatives(e.g.methyl salicylate,salicylamide),the order ofstabilities on the conformers given by MNDO andMINDO/3 methods were not in agreement with theexisting conformers deduced by experimental methods,and the hydrogen bonding energies calculated by MNDO.and MINDO/3 methods were smaller.Second,the studyon the other systems found that the optimizedgeometry of the proton-transfered product with INDOmethod could not be obtained,only could theoptimized geometry of reactant be obtained,and thecalculated hydrogen bonding energies were greater.Many results of calculation indicated that the studyon the excited-state intramolecular proton transferreaction system using AM1 method was suitable andreliable.

本论文用AM1、MNDO、MINDO/3(主要是AM1)和INDO/S-CI半经验分子轨道方法对水杨酸衍生物系列——水杨酸、水杨酸甲酯、水杨醛、O-羟基乙酰苯酮、水杨酰胺和3-羟基吡啶酰胺(6种异构体和2-3种阴离子);2-(2'-羟基-5'-甲基苯基)苯并三〓唑(4种异构体);2-(2'-羟基苯基)苯并咪唑(3种异构体和3种阴离子);2,5-二间氮杂氧茚氢醌(3种异构体);2-(2'-羟基苯基)间〓杂硫茚(2种异构体)和7-〓吲哚二体(2种异构体)的激发态分子内质子转移反应在以下几个方面进行了较系统的理论研究:几何构型优化和相对稳定性及氢键能首先以水杨酸衍生物系列分子为例,用AM1、MNDO和MINDO/3方法考察了5种分子(每种分子设计6种异构体和2-3种阴离子)的基态几何构型优化,能量、相对稳定性和氢键能计算,通过和实验数据进行比较,AM1方法给出的优化几何构型、稳定性次序、氢键能和O—H。。。O氢键的0—0距离与实验数据吻合最好,MNDO和MINDO/3方法优化的C-C键长偏长,C-O键和O-H键长偏短;对于C-N键长,MNDO和AM1优化结果差别不大,而MINDO/3给出了过短的C-N键长,MNDO和MINDO/3方法给出的有些水杨酸衍生物分子(如水杨酸甲酯和水杨酰胺)异构体的稳定性次序和实验上推测的可存在异构体结果不一致,MNDO和MINDO/3方法给出的氢键能偏低,对其他体系的研究发现INDO方法常常不能得到质子转移产物的优化几何构型,只能得到反应物的优化构型,并且估算的氢键能偏高,大量的计算结果表明AM1方法对本论文研究的激发态分子内质子转移反应体系是适宜和可靠的。

According to the basic principles of neural networks and in combination with 35 examples of actual landslide projects, this paper establishes RBF and BP neural network models respectively. The comparative results of the two models show that RBF neural network model has higher accuracy and fewer errors and is more suitable for the stability evaluation of landslide. Therefore, this model is used to calculate the stability coefficients of Yellow Caoba ancient landslide and predict the stability of the landslide.

根据神经网络的基本原理,结合35个实际滑坡工程实例,分别采用RBF神经网络和BP神经网络建立滑坡稳定性评价模型,利用MATLAB编程求解,并对比了两种模型的计算结果,表明采用RBF网络模型计算出的结果精度高、误差小,更适合于对滑坡的稳定性评价;同时,运用RBF网络模型计算了黄草坝古滑坡的稳定性系数,对其稳定性进行了预测,以验证该方法的有效性。

In this paper, the effect of wheat juice boil on the nonbiological stability, biological stability, flavor stability and foam stability of beer are discussed.

本文论述了麦汁煮沸对啤酒非生物稳定性、啤酒生物稳定性、啤酒风味稳定性和泡沫稳定性的影响。

The stabilities of the extract from sanguisorba under different pH, light, heat, ultraviolet ray, oxidant, reducing agent and additive agents were studied. It was indicated the products could widely used in the condition of weak acid or neutral, while they were not stable to heat and light, so they should be used without light and at low temperature. The products had a strong ability to withstand ultraviolet ray. They could easily be oxidized and degraded by oxidant while they were not easily affected by reducing agent and were almost not affected by additive agents. The extract from the stem of sanguisorba was analyzed by UV and FTIR, showing that the structures of the active components were not changed during ultrasonic wave extracting.

研究了pH值、光、热、紫外线、氧化剂、还原剂以及添加剂对地榆提取物稳定性的影响,结果表明地榆提取物适合弱酸或中性条件下使用,使用范围比较广;但对光热稳定性较差,适合在避光低温的环境;具有很强的抗紫外线能力;氧化剂对地榆提取物稳定性影响较大,会加速其降解,还原剂对地榆提取物影响不大;其他添加剂对其稳定性几乎没有影响;并通过UV和FTIR光谱分析,超声波浸提没有对地榆根茎中有效成分的结构发生改变。

In two dimensional numerical model .Reinforced effect of spud for antis lip, anchor cable, geogrid to real slops are analyzed and evaluation of degree of safety in slop stability is given.

考虑了水对土体的上浮力和降雨对边坡稳定性的影响,并在二维模型中分析了抗滑桩、锚索、土工格栅对实际边坡稳定性的加固作用,给出了边坡稳定性稳定性评价。

An Kalman filter positioning algorithm applied in "BeiDou" and INS integrated navigation system is proposed. then, the observability、controllability and stability of it is ratiocinated and analyzed. The observability of every state is analyzed.

针对北斗卫星定位系统和惯性导航系统设计组合导航卡尔曼滤波定位算法,接着对算法的可控性和可观性进行了分析,并分析了各个状态的可观测性;从稳定性的定义出发提出并推导了分析卡尔曼滤波器稳定性的方法,并用来分析了本文算法的稳定性和渐进稳定性

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