稀土金属

This paper contains three parts: 1 Synthesis of novel titanium complexes; 2 Polymerization behaviors of alkoxyl substituted Cp Titanocenes as catalysts for styrene syndiotactic polymerization; 3 Polymerization behaviors of alkenyl substituted Cp Lanthanocenes as Methyl Methacrylate polymerization catalysts.

中文题名新型茂钛、噁唑啉钛络合物的合成、表征以及茂钛、茂稀土络合物催化性能的研究副题名外文题名 Synthesis，characterization of novel Cp，oxazoline titanium complexes and polymerization behaviors of titanocenes and lanthanocenes 论文作者张浩导师钱延龙黄吉玲学科专业应用化学研究领域\研究方向金属有机与均相催化学位级别博士学位授予单位华东理工大学学位授予日期2003 论文页码总数148页关键词金属有机化学稀土络合物噁唑啉类钛络合物茂钛络合物馆藏号BSLW /2003 /O627 /27 本论文包括三部分内容：1）有机金属钛络合物的合成；2）烷氧基取代茂钛络合物催化苯乙烯间规聚合的研究；3）烯基取代茂稀土络合物催化甲基丙烯酸甲酯聚合的研究。

The total of 36 compounds were characterized by X-ray single crystal diffraction, EA, TG, IR, luminescence, adsorption, XPS, powder XRD, M〓ssbauer spectra, EPR, magnetical measurements.

本论文利用水热法，成功设计和合成出三个系列Ln-M(M=Mn〓，Fe〓，Ag〓)共23个未见文献报道的稀土—过渡混合金属配位聚合物，同时也得到了结构新颖的仅含稀土或两种不同过渡金属的从一维到三维的聚合物13个，并对它们进行了结构、元素分析、热重分析、红外光谱、荧光、吸附、磁性、光电子能谱、粉末衍射和M〓ssbauer谱等表征。

Through the addition of rare earth oxidation La_2O_3 and CeO_2 into the electrode coating , the effect of rare earth oxidation on high temperature oxidation and sulphidation resistance is studied and the rational addition amount is suggested.

通过A402，A302，A202及Cr24Ni7不锈钢焊条熔敷金属的抗高温氧化腐蚀性能对比试验分析，设计了新的专用焊条合金系统Cr26Nil6，并在焊条药皮中分别添加微量稀土氧化物La2O3及CeO2，研究不同稀土氧化物添加量对焊条熔敷金属在空气中和含硫气氛中抗高温氧化及腐蚀性能的影响，从而确定了合理的稀土氧化物加入量。

The results showed that the addition of the rare earth alloy powder can refine and disperse oxide particles. Through energy spectrum analysis, it was found that the rare earth congregates to Ti and the interface between metal matrix and diamonds. The active La and Ce in alloy powder can reduce the oxide film on Ti particles, increase the reactivity of Ti, and promote the reaction between Ti and diamond.

通过扫描电镜，能谱分析和X射线物相分析、比较和归纳，发现加入适量的稀土-Ni合金粉，使胎体中的氧化物颗粒细小、弥散；在添加稀土合金粉的胎体中，稀土向Ti富集并向金刚石与金属基体界面偏聚。

Some essential trace elements were reported to be involved in the normal bone metabolism. Nowadays rare earth elements are widely used in many fields and more and more rare earth elements enter the environment and food chains They are enriched in bone and difficult to be excreted. Because the similarity between rare earth ions (Ln3+) and Ca2+, they will intervene and regulate bone formation and remodeling.

骨骼的正常代谢涉及多种金属离子，随着稀土的应用，通过环境和经由食物链等渠道进入人体内的稀土量也有所增加，并且在骨组织中相对富集且难排出；由于稀土与钙离子的相似性，它们将干预和调控骨的形成与再造。

Some essential trace elements were reported to be involved in the normal bone metabolism. Nowadays rare earth elements are widely used in many fields and more and more rare earth elements enter the environment and food chains. They are enriched in bone and difficult to be excreted. Because the similarity between rare earth ions Ln(superscript 3+ and Ca(superscript 2+), they will intervene and regulate bone formation and remodeling.

骨骼的正常代谢涉及多种金属离子，随着稀土的应用，通过环境和经由食物链等渠道进入人体内的稀土量也有所增加，并且在骨组织中相对富集且难排出；由于稀土与钙离子的相似性，它们将干预和调控骨的形成与再造。

The results show that HY exchanged with alkali-earth metal cation or rare-earth metal cation has higher stability than that of HY.

结果表明，用碱土金属离子或稀土金属离子交换改性的HY分子筛在烷基化反应中具有比HY更好的稳定性。

Third, quinolones" drug can make the effect with the rare-earth metal ion Tb3+ and strengthen the characteristic fluorescence of Tb3+. We can make the determination of Quinolones" drug with the character.

第三章，喹诺酮类药物可与稀土金属离子Tb~(3+)反应而增强Tb~(3+)的特征荧光，并且可利用这一特性来进行沙星类药物的测定。

Electron paramagnetic resonance spectrum is an effective tool to investigate the optical and magnetic properties of crystals and complexes doped with transition-metal and rare-earth ions.

电子顺磁共振谱是研究掺过渡和稀土金属离子晶体及络合物的微观结构、光学和磁学性质等的有力工具。

Because of the disadvantages in the electrolysis of rare earth metals, a new kind of electrode material called non-carbon anode is studied, and the corrosion mechanism is reseached.

针对稀土金属Nd的氟化物体系熔盐电解中石墨阳极所存在的一系列不足，研制了一种新型的电极材料，称其为非碳阳极；并对其在电解过程中的腐蚀机理进行了较详细的探讨，提出了还原反应、氧化反应、电解质渗透、电极组分溶解、析氧膨胀等几种可能的腐蚀原因。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。