离子间的

Both the and DtV$ for the glycyl dipeptides increase with increasing molality of sodium acetate. The interactions between charged center or glycyl units of the peptide and ions dominate those between alkyl groups of the peptide and the ions. The interaction between the peptides and sodium acetate is mainly pairwise. The results were interpreted successfully by the cosphere overlap model.

结果表明：甘氨酰二肽的标准偏摩尔体积和标准偏摩尔转移体积均随乙酸钠浓度的增加而增大，溶液中离子与肽带电基团/甘氨酰基团(CH2CONH)之间的相互作用大于离子与肽的非极性基团间的相互作用，乙酸钠和甘氨酰二肽之间主要是对相互作用。

The strength of the interionic interactions was found to be predominant for the dissolution of β-cyclodextrin.

离子液体阴阳离子间相互作用的强度被认为是影响β-CD溶解度的主要因素。

The main idea of the simulation is adopting Monte Carlo method and the classical over barrier model to simulate the randomicity of the charge exchange processes between projectile and metal and the dispersing of projectile's continuum movement. In each step, the movement of projectile is considered to a uniform acceleration.

本论文模拟的基本思想是在经典过垒模型下，采用蒙特卡罗方法来模拟入射离子与固体间电荷交换过程的随机性，并将入射离子连续的运动过程离散化，在每一个步长中，将入射离子的运动近似看成是匀加速直线运动。

After the carboxymethylation,the solubility of pachyman in the water was significantly increased,its β-D-glucan characteristic absorption peak at 890 cm-1 became weak obviously,and its methylene vibration absorption peak and CO antisymmetrical stretch vibration absorption peak appeared at 1 333 and 1 606 cm-1 respectively,which indicated that the carboxymethylation succeeded.The analysis of AFM results showed that CMP molecules existed in different morphology under different solution conditions,and that the concentration,ionic strength and solvent physical chemistry characteristics of polysaccharide solution had effects on the CMP chains conformation and the action mode between different molecular chains.The phenomena were considered to be related to hydrogen bond association and intramolecular and intermolecular electrostatic interactions of CMP.

结果表明：经过羧甲基修饰，茯苓多糖在水中的溶解性显著增加，890 cm-1 处的β-D-葡聚糖特征吸收峰明显减弱，1 333 cm-1 处出现次甲基振动吸收峰，1 606 cm-1 处出现〖JG(〗C〖ZJLX，Y〗O〖JG)〗非对称伸缩振动吸收峰，表明羧甲基化成功；原子力显微镜分析表明：在不同溶液条件下，CMP分子以不同形态存在，多糖溶液的浓度、离子强度及溶剂的物化特性均能对CMP的分子链构象及链间相互作用形式产生影响，推测可能与CMP分子内、分子间的氢键缔合及静电作用有关，CMP分子与云母基底间的吸附及静电作用也会对CMP的分子链构象及图像质量产生影响。

Structural analyses reveal that all species consist of a pair of hetetrometallic atoms triplybridged by bidentate pivalate ligands.

它们共同的结构特征是异金属离子间均由三个双齿的羧基桥连，在四核的化合物20和21中两个稀土离子通过两个双齿羧基相连。

According to the simulation of up-flowing ions i. e., O (superscript +, H (superscript +) and He (superscript +) distribution function and using dynamic equation during dipolarization in substorm in magnetotail, ion acceleration and energization are investigated.

根据采用动力学方程对亚暴期间磁尾磁场向偶极形弛豫过程中离子分布函数的模拟结果，研究了磁尾来自电离层的O， H和 He离子的速度及能量随时间的变化。

The study indicates that sea water and brine intrusion processes have different hydrochemical features;and that ion exchange and absorption actions between water and aquifer produce great influence to the intrusion.

研究表明，现代海水、卤水在入侵过程中的地下水水化学特征有明显不同；地下水与含水岩层间的离子交换与离子吸附作用对咸水的地下入侵过程产生重要影响。

The dissertation mainly consists of two parts:1. The Reaction Chemistry of Alkynes under Palladium Catalysis Part 1 studies the reaction α,β-unsaturated carbonyl compounds with alkenylpalladium intermediate generated by nucleopalladation, and discovered 1 the Pd-catalyzed tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls,2 the four-component tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls, 3 the tandem intramolecular oxypalladation-conjugate additionreaction of alkynoic acids with α,β-enals. These new reactions provide notonly efficient highly stereoselective methods for the synthesis of γ,δ-unsaturated,polyunsaturated carbonyl compounds and γ-lactonic aldehydes, but also thebasic transformations for a number of C-C bond formation reactions which can be usedto design synthesis of many acyclic, cyclic or polycyclic compounds.

本论文的主要工作分为两个部分：一、钯催化下炔烃的反应化学在本小组前人工作的基础上，我们详细研究了炔烃亲核钯化产生的烯基钯中间体与α，β-不饱和羰基化合物的反应，发现两价钯催化下卤离子-炔烃-α，β-不饱和醛酮的串联加成反应、卤离子-炔烃-α，β-不饱和醛酮的西组分串联加成及炔酸分子内氧钯化-串联Michael型加成反应；由此发展了γ，δ-不饱和醛酮、多不饱和羰基化合物和带有醛酮基侧链的γ-丁内酯衍生物的高立体选择性合成方法，这一过量卤离子存在下的烯基钯对α，β-不饱和羰基化合物共轭加成反应的发现，为大量碳-碳键形成反应的实现提供了基础，使我们能够从这一基本反应出发，设计和开发多种分子内、分子间的碳碳成键反应，以好的立体、区域选择性组建开链、环状及多环类型的化合物。

Cetyl pyridinium bromide monohydrate is used to exchange the metal irons in the innerlayers of sodium-based bentonite which is used as raw material and the organobentonites are obtained with orthogonal technique by changing the reaction conditions such as reaction time,reaction temperature,pH,the quantity of quaternary ammonium,and the ratio of bentonite to water.

采用正交L16(45)实验法，以Na基膨润土为原料，用溴化十六烷基吡啶为插层剂，与膨润土层间的金属离子进行离子交换，通过改变反应温度、反应时间、pH值、固液比、季铵盐添加量5个因素，得到不同条件下的有机膨润土。

Surfactant sorbed on soil increases the adsorption capacity of the soil; however, the microemulsion composed of surfactant and organic materials decreases the adsorption capacity of the soil.

增加离子强度对非离子表面活性剂的吸附无影响，却可略微增加阴离子表面活性剂的吸附。表面活性剂吸附于土壤后对憎水性污染物在土壤/水间的分配行为产生显著作用。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。