离子键

Five new solid complexes were synthesized by the coordination of tranisition metals with a Schiff base(C17H21NO,HL) derived from adamantaneamine and salicylaldehyde ,and characterized by elemental analysis,molar conductance,infrared spectra,1H NMR spectra,thermal analysis.

合成了金刚烷胺水杨醛Schiff碱配体(C17H21NO，以HL表示)与5种过渡金属的新的配合物[MCl22]M=Mn(Ⅱ、Co、Ni、Cu、Cd，用元素分析、摩尔电导、红外光谱、1H NMR谱和热重分析对产物进行了表征；讨论了配体与中心金属离子的键合情况，并推测了配合物的结构。

In the third chapter, eight new complexes of 4, 6-dimethylpyrimidine 2-thioacetic acid with rare earth metals has been synthesized and characterized by means of elemental analysis, molar conductivity, IR,〓 NMR and TG-DTA. The general formula of the complexes is Ln〓(n=4 or 5). In the complexes, the deprotonated ligand coordinated to the rare earth metal ions in chelate bidentate mode. 4 or 5 molecular of crystal water existed in the complexes.

第三章合成了八种4，6-二甲基嘧啶-2-硫代乙酸的稀土配合物，通过元素分析、摩尔电导、红外光谱、核磁共振氢谱和热重-差热对配合物进行了表征，研究结果表明，配合物的组成为Ln〓n=4或5），在配合物中配体羧基脱去质子后采用螯合双齿的方式与稀土离子形成配位键，同时，配合物中含有4或5个结晶水。

Three parameters of lanthanide,atomic number Z,valence electron number N,ion radius r,were used to define a new topological index of bond parameter —H_z.

根据镧系元素的原子序数Z、价电子数N、离子半径r提出了一个新的键参数拓扑指数 HZ，并将HZ、镧系元素相对分子质量Mr共同与其11种理化性质进行关联，其结果显示了满意的线性相关性。

A film-forming additive, vinyl ethylene sulfite with both vinylene group and sulfite group, affects the electrochemical performance of carbonaceous mesophase spherules and LiFePO4 electrode.

研究了具有不饱和双键和亚硫酸酯双官能团的乙烯基亚硫酸乙烯酯作为锂离子电池电解液成膜添加剂对中间相碳微球和LiFePO4电极电化学性能的影响。

In addition, the orientational freedom k and the diffusion coefficient D of water molecules are reduced because of new formed hydrogen-bonding structures between water and solvated ions.

另外，水分子与NaCl离子间形成的新氢键结构降低了H2O分子的旋转自由度k和扩散系数D。

The emulsion quartz stone material protective agent's solute has certain active multi-compositions and so on of functionality siloxanes and fluorine silicon hydride, this kind groups with the active ingredient carry alcoholysis reaction the ion condition water on quartz stone material surface, thus causes the siloxanes and the fluorine siloxanes has chemistry keying connection with the quartz stone surface, from outside to inside of the quartz stone surface and stone inside pore surface forms a kind of complex network structure, this kind of network structure is extremely dense, it may filter polar and carbon dioxide, slows down the speed that water molecules go in and out the quartz stone pore, so the quartz stone will not be soaked by the water molecules, meanwhile to be a barrier to stop alkaline compounds and salt to infiltrate from an interface to another, also can have the very good physical enhancement effect.

乳液型石材防护剂的溶质是具有一定活性的多官能度的硅氧烷和氟硅烷等组成，这种带有活性成份的基团与石材表层离子态水进行醇解反应，从而使硅氧烷和氟硅氧烷与石材表面进行化学键连接，由外向内在石材表面和石材内部毛的表层形成一种结构复杂的网状结构，此种网状结构极其密实，它可将极性水分子和二氧化碳进行过滤，减缓水分子进出石材毛孔的速度，不会被水分子浸湿，同时还有阻隔石材不同界面的碱性化合物和盐份向另外一个界面渗透，同时还能起到很好的物理增强效果。

The electronic structure and electronic spectra of [Mo2Sn]2-(n = 6-9) with Mo-Mo single bond are studied by SCF-CI.

使用SCF-CI方法研究了含有Mo-Mo单键的原子簇离子体系[Mo~2Sn](n=6~9)的电子结构及电子光谱。

Therefore, the EL spectra of (Znq_2)_4 is wider than that of Znq_2. 4._2 was synthesized. The analysis of molecular spatial structure and the characterization of material performance of_2 and Liq showed that two Liq molecules and two Naq molecules were connected by Na-O-Na bond bridges to form_2. Compared with Liq,_2 exhibits stronger rigidity in planar molecular structure, larger steric hindrance and intermolecular distance, and much smaller molecular polarity, thus resulting in much longer fluorescence lifetime, much higher fluorescence quantum efficiency, wider energy bandgap and better film formability. When used as light-emitting layer in OLED,_2 shows lower formation probability of excited dimmer and exciplex formation than Liq, thus emits bluer light with higher current efficiency than Liq. When_2 ultrathin film is used as electron injection layer in OLED, it exhibits higher current density, higher luminance, lower turn-on voltage and higher current efficiency than Liq ultrathin film for the existence of sodium ions in_2 ultrathin film. 5. The summarization the relationship between molecular spatial structure and material performance of Alq_3,(Znq_2) and Liq, lead the conclusion that the molecular spatial structure of Mq_n affects its material performance in such aspects as the rigidity of planar molecular structure, intermolecular interaction, molecule stacking mode and intermolecular distance.

制备了_2，通过对_2和Liq的分子空间结构与性能进行分析与讨论，发现_2是通过两个Na-O-Na键桥将两个Liq和两个Naq连接构成的，其分子平面结构的刚性程度强于Liq，空间位阻大于Liq，分子之间的距离大于Liq，分子极性远远小于Liq；_2的荧光寿命长于Liq，荧光量子效率高于Liq，成膜性优于Liq；_2的禁带宽度比Liq大，光致发光光谱中_2的最大发射峰较Liq发生蓝移；当_2在OLED中作为发光层时，激发二聚体与激基复合物的生成几率远远小于Liq，发的光比Liq更蓝，电流效率大于Liq；_2超薄膜中有Na离子的存在，与Liq超薄膜相比，当其在OLED中作为电子注入层时，具有更大的电流密度，更高的发光强度，更低的阈值电压和更高的电流效率 5、对上述Alq_3、Znq_2和Liq的分子空间结构与材料性能之间的关系进行了归纳总结，认为Mq_n的分子空间结构主要在分子平面结构的刚性程度，相邻分子之间的相互作用，分子堆叠的方式和分子之间的距离这四个方面影响其性能。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。