离子键

At this level, basic concepts such as bonding, ionic and covalent bonds are briefly introduced to students.

在这一级，基本概念，如氢键，离子和共价键简要介绍给学生。

The influence of additive and phase transfer catalysts on the oxidation of cyclohexene catalyzed by those catalysts has also been investigated.

结果表明：金属卟啉和高分子键联后稳定性增加，也是烯烃氧化反应的一种有效催化剂，且催化性能随着金属离子的不同有所选择。

Three new fulvene polymeric compounds, namely 1[Ag (L3]CH2C12 , 2[Ag2(L25(H2O)(S03CF3)2]0.5C6H6 and 3 Mn(L42(C2H5OH)2 , were synthesized, respectively. Compounds 1 and 2 reported herein represent the organometallic polymers based on both Ag-N and Ag-C coordination interactions. In the solid state, compound 3 are bound together by strong intermolecular N H-O hydrogen bonding system into a supramolecular one-dimensional H-bonded chain.B.

一、富烯有机配体的合成及与金属离子的反应化学利用富烯负离子的芳酰化反应和Heck-偶联反应合成了富烯配体L1-L18，并合成了三个基于富烯配体的金属有机配位聚合物1[Ag(L3]·CH_2Cl_2、2[Ag_2(L25(H_2O)(SO_3CF_3)_2]·0.5C_6H_6和氢键驱动的超分子聚集体3Mn(L4_2(C_2H_5OH)_2。

The alkaline-earth metal complexes with mucic acid was successfully prepared via gel formation and characterized by elemental analysis,FT-IR measurements.

结果表明，粘液酸的两个羧基和四个羟基均能参与配位键的形成，而中心离子 Ca~(2+)、Sr~(2+)、Ba~(2+)与配体粘液酸的配位状况存在着一定差异。

The calculated results indicate that the energy bathers for the formation of dimethyl ether and trimethyl oxonium ion inside HSAPO-34 zeolite are 1.68 and 0.93 eV, respectively. The suggested intermediate oxonium ylide is very unstable and the energy barriers for the formation of C-C bond are over 3.0 eV by concerted pathway.

结果表明，二甲醚和三甲基氧鎓离子在HSAPO-34分子筛上的生成能垒分别为1.68和0.93eV，中间体氧鎓叶立德不能稳定存在，同时表明C-C键通过协同反应形成的能垒均超过3.0ev。

Glycyrihizic acid can cause the polarigraphic catalytic wave of oxygen. GA scavenging superoxide ion is demonstrated chemically by the catalytic wave at molecular lever.

本文报道的甘草酸及其皂甙类衍生物存在下的氧极谱催化波，从分子水平研究了GA清除超氧离子自由基〓的化学作用机制，证实清除〓的活性基团是GA分子中与C＝O基共轭的C＝C双键，并非-OH基，纠正了文献观点。

Adjacent helical chains are racemic. The Ag atom is linked to two nitrogen atoms of the 2-pyridyl and 4'-pyridyl groups from two different 2,4'-bpy ligands as well as to the oxygen atom of the counterion. In 17 and 19, the adjacent helical chains are linked to wavy two-dimensional network structures by the nitrate counterions.

相邻的螺旋链间是外消旋的，Ag 原子与分别来自两个不同2，4'-联吡啶的2-吡啶基和4'-吡啶基的氮原子以及阴离子的氧原子配位，在配合物17和19中，相邻聚合螺旋链被硝酸根离子桥连接起来，变成了一个波浪形的二维网络结构；配合物18是首次通过无桥连配体支持的Ag ××× Ag键将相邻螺旋链连接成二维非穿插的网络结构。

The energy of the complex molecule has been compensated by a hydrogen bond formed by, a proton bonding to a quinolyl nitrogen atom and a nitrate ion.

分子中有一个氢离子与另一个喹啉N原子结合并与硝酸根的氧原子形成氢键，从而使配合物分子在能量上得到补偿。

It follows that the de-protonic reaction of hydroxide group for PVA had taken place in above solution, and the coordination group for deprotonic oxygen of PVA had produced more. These ligands interact with some Fe3+ of ferric hydroxide while the ferric hydroxide in new emergence is forming,causing the formation of Fe-PVA coordination polymer-the composition of the reddish brown resinoid substance.

推定PVA部分羟基在上述条件下发生脱质子反应而提供L-配位体，Fe盐水解生成初生Fe3的Fe3+，它既有空轨道，又有较强的正电场，故能吸引PVA高分子配位体L-上的氧而形成O→Fe配位键，从而发生L-与Fe3+离子间的交联反应，生成多核Fe-PVA配位聚合物而析出红棕色树胶状物。

Background and Objective: The basic structure of salicylaldehyde amino acid Schiff base compounds includes a C=N chemical bond.

背景与目的：水杨醛氨基酸Schiff碱基本结构中含C＝N键，当基与金属离子配位后生物活性增强，表现出一定的抗癌、抑菌等活性。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。