离子键

We have measured the translational energy and the angular distributions of the fragments. The C-Br bond fission dynamics in the ultraviolet photodissociation has been analyzed. The effect of coupling between the potential energy surfaces on the product channels has been discussed.

第二部分是利用离子速度影像技术对1，2-C2H4Br2、tert-C4H9Br和iso-C4H9Br的紫外光解动力学的研究，获得了光解产物的平动能分布和角度分布信息，分析了这些分子的断键机理，研究了势能面间的相互耦合对光解产物状态的影响。

Such one-dimensional chains interconnect via hydrogen bonding and π-π interaction to form an extended undulated sheet-like structure.

经配体桥联的两个金属离子的距离是6.703〓。这样的一维链通过配体的NH部分〓Cl及溶剂分子甲醇相互之间形成的氢键连接扩展成二维波浪状结构。甲醇分子被包容在层间。

We also dabbled ion-selective electrodes and successfully designed a new compound -amide-linked manganese diporphyrin xanthene(Mn2Cl2ADPX)- as electro active materials of electrode to detect the thiocyanate.

我们还进行了离子选择性电极的研究，并且成功设计合成了一种新的化合物——酰胺键联氧杂蒽双锰卟啉——并把它作为电活性物质用于SCN-的检测。

A novel method was established for the preparation of solid phase extractor by modified xylenol orange onto silica gel.

制备了二甲酚橙键合硅胶固相萃取剂，研究了它对常见重金属离子的分离富集行为，发现对水中痕量Hg2+有较好的选择性分离富集效果。

The alkaloids were studied by gas chromatography coupled to mass spectrometry. Six major venom alkaloids were detected in worker venom which are all trans 2-methyl-6-alkyl or alkenyl pepdine according to mass spectral data and relative report on S.invicta.

通过保留时间和质谱离子碎片数据，并与国外相关报道比较分析得出：入红火蚁毒液中主要成分为2-甲基-6-烷基或烯基哌啶生物碱，仅有6位取代烃基碳链长短和烯键有无及顺反异构的差异。

After the carboxymethylation,the solubility of pachyman in the water was significantly increased,its β-D-glucan characteristic absorption peak at 890 cm-1 became weak obviously,and its methylene vibration absorption peak and CO antisymmetrical stretch vibration absorption peak appeared at 1 333 and 1 606 cm-1 respectively,which indicated that the carboxymethylation succeeded.The analysis of AFM results showed that CMP molecules existed in different morphology under different solution conditions,and that the concentration,ionic strength and solvent physical chemistry characteristics of polysaccharide solution had effects on the CMP chains conformation and the action mode between different molecular chains.The phenomena were considered to be related to hydrogen bond association and intramolecular and intermolecular electrostatic interactions of CMP.

结果表明：经过羧甲基修饰，茯苓多糖在水中的溶解性显著增加，890 cm-1 处的β-D-葡聚糖特征吸收峰明显减弱，1 333 cm-1 处出现次甲基振动吸收峰，1 606 cm-1 处出现〖JG(〗C〖ZJLX，Y〗O〖JG)〗非对称伸缩振动吸收峰，表明羧甲基化成功；原子力显微镜分析表明：在不同溶液条件下，CMP分子以不同形态存在，多糖溶液的浓度、离子强度及溶剂的物化特性均能对CMP的分子链构象及链间相互作用形式产生影响，推测可能与CMP分子内、分子间的氢键缔合及静电作用有关，CMP分子与云母基底间的吸附及静电作用也会对CMP的分子链构象及图像质量产生影响。

Metal-Organic coordination polymers are formed by self-assemblythrough coordination bonds between bidentate or multbentate organic ligands and central metal ions.

金属有机配位聚合物是通过含给电子基团的双齿或多齿有机配体和一种或几种中心金属离子通过配位键自组装而形成的。

Metal-Organic coordination polymer is formed by self-assembly through coordination bond between bidentate or multbentate organic ligand and central metal ion.

金属有机配位聚合物是通过含给电子基团的双齿或多齿有机配体和一种或几种中心金属离子通过配位键自组装而形成的。

The crystal belongs to monoiclinic with space group P2 1/n, a=1.7073(7)nm, b=1.7447(7)nm, c=2.4333(10)nm,β=109.694(7)°, Z=4,V=6.824(5)nm 3, D x=1.282g/cm 3,μ=0.793mm -1, F(000)=2696, R 1=0.0563, WR 2=0.1539. In the crystals of compound, the tin atoms rendered seven-coordinate in a distorted pengonal bipyramidal structure.

我们以 NEt3 作缚酸剂，用 Ph3 Sn Cl与 2 ，6 -吡啶二甲酸以 1∶ 1摩尔比反应时，没有得到预期产物 Ph3 Sn O2 C(2 ，6 - Py)CO2 H ，而是得到一种 Sn- Ph键断裂的离子型有机锡化合物(Scheme1 )。

Free amino group and carboxy group on short peptide and amino acid can coordinate metal ion with vacant orbital to form chelate compound.

短肽和氨基酸的自由氨基上的-NH_2、羧基上的-C=O等均可与具空轨道的金属离子产生配位键，形成螯合物。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。