离子键

An algebraic expression consisting of three terms connected by plus or minus signs.

由一个金属离子与两个或两个以上非金属离子构成配位键的过程。

In chapter I, we introduce the Jordan-Wigner transformation in detail, and illustrate its applications with three examples: the one-dimensional S = 1 XXZ model; the bilinear-biquadratic SU(2) invariant S = 1 chain; and the ionic Hubbard chain in the strong coupling limit. In chapter II, we review the S = 1/2 transverse Ising chain in detail.

在变换后发现隐藏在自旋为1的系统里自旋为1/2的SU(2)对称性及广义的U(1)规范对称性；(3)通过将推广的强耦合极限下的一维离子型Hubbard 模型变换为SU(3)反铁磁Heisenberg 模型，严格论证了离子型Hubbard 模型从能带绝缘体到莫特绝缘体的转变区域中自发二聚化绝缘体铁电性相即键序波相的存在。

With the help of infrared spectroscopy, it is known that the linkage between dodecylamine and sodium oleate and diaspore, kaolinite, illite and pyrophyllite is fundamentally electrostatic forces, which contributes to physical adsorption. The adsorption is related with surface electric property of minerals. The effect of chemical composition of diaspores on their electrokinetics was investigated.

对于一水硬铝石矿物来说，三个主要晶面（010）、（100）和（001）上的单位面积断裂键数有如下关系：〓；一水硬铝石表面吸附的动力学模拟可以说明，一水硬铝石的（010）晶面、（100）晶面和（001）晶面，分别吸附几种捕收剂离子的吸附能大小为：（010）晶面的吸附能＞（100）晶面的吸附能＞（001）晶面的吸附能；分别吸附这些药剂离子的单位面积吸附量〓的大小顺序为：（010）晶面＞（100）晶面＞（001）晶面。

Differences of wettability and floatability between diaspore and aluminium silicate minerals are due to the differences of crystal structure between diaspore and aluminium silicate minerals, and of the part Al-O, Si-O bonds, and the metal ions on the surface of the minerals.

一水硬铝石与铝硅酸盐脉石矿物晶体结构的差异、表面断裂的Al-O和Si-O键及表面离子活性区的差别，可影响矿物表面的润湿性与可浮性，类质同象及各种晶格杂质离子也将影响浮选剂与矿物表面的相互作用和矿物可磨性。

In the thesis, we wish to report the synthesis and structures of a series of new type rigid conjugated nanometer-sized fulvene ligands, and coordination polymeric compounds based on both metal-carbon and metal-heteroatom interactions and also H-bonded supramolecular architectures generated from this new type of fulvene ligands.

基于此，我们合成了一系列刚性共轭的纳米级富烯类配体，并以之与过渡金属离子反应合成了同时基于金属-碳和金属-杂原子两种键合作用的有机-无机配位高聚物及以氢键作用为驱动力的超分子聚集体。

CMTC crystal belongs to metallorganic complex compounds and growth units are in the form of complex anions. Therefore, there are probably some unsaturated electrovalent bonds on the growth face, which undergoes a "restruction" process by bond linkages until a stable state with least surface energy is reached.

2CMTC晶体是配合物型晶体，以配位阴离子基团形式向生长界面堆积生长，因此在界面上很可能会存在着一些不饱和的离子悬键，悬键之间可能相互连接进行&重构&以达到表面自由能最小的稳定状态。

The chemical chain scissions were mainly found at carbonyl and methoxyl groups, which led to the relative decrease of amount of carbon and oxygen in these functional groups.

结果表明，Ar离子辐照PET膜引起了明显的非晶化转变和化学键断裂，断键主要发生在甲氧基和羰基功能团上，并使这两个功能团中的C和O的比分相对减少。

According to Johnson's Rule and IR spectra, their possible structures are suggested. The bonding parameters of those complexes are calculated by ESR parameters. And the crystal field parameters are calculated by using electronic spectral data. It can be seen that the vanadyl complexes in the solution are ionic complexes and that the α〓 values of those complexes decrease following the increasing of the N donor replacing the O donor of water on the equatorial plane in those complexes. This means that the covalent bonding between vanadium and ligand increases as Ser, Phen or Bipy replace water ligands. The results show the competitive coordinate law that the coordination reactivity of Phen and Bipy is much stronger than that of Ser. The simulation program of ESR is compiled by the theory of ESR in the present work.

测定了VO-丝氨酸二元体系、VO-丝氨酸-邻菲咯啉三元体系和VO-丝氨酸联吡啶三元体系在不同酸度下（pH=1.0～14.0）的乙二醇／水（V／V=1：1）溶液低温ESR谱，发现不同pH下，溶液中具有不同组成的配合物，根据不同pH下ESR谱的变化，利用Johnson的加合规则并结合红外光谱，推测了它们在溶液中的可能结构；利用波谱参数计算了配合物键参数；利用电子光谱数据计算了配合物的晶体场参数，讨沦了它们的成配特性，结果表明：VO配合物属离子型配合物，随取代水分子的配体（Ser、Phen或Bipy）数目增加，键参数减小，配合物共价性增强，同时得出这些体系中，生物配体竞争配位规律：Phen和Bipy与VO的配位能力比Ser强。

The main intermediates were detected during decomposition,such as acetic acid,oxalic acid,malonic acid,phenol,3-hydroxyhypnone,naphthalene,benzene sulfonic acid,phthalic acid,β-naphthalene etc . by ultraviolet-visiblespectroscopy,ion chromatographand gas chromatograph coupled with mass spectrophotometertechniques.The possible degradation pathway of Acid Orange Ⅱ was also speculated,that was,hydroxyl radical reacted with the azo linkage-bearing carbon of naphthol-ring,and the C—N cleaved,the azo-dye decolored and mineralized.

运用紫外光谱、离子色谱、色谱-质谱联用等方法，测定出酸性橙Ⅱ的主要降解产物有乙酸、乙二酸、丙二酸、苯酚、3-羟基苯乙酮、萘、苯磺酸、邻苯二甲酸、β-萘酚等，并依此推测酸性橙Ⅱ的降解机理，即羟基自由基攻击酸性橙Ⅱ分子上与萘环相连的C—N键，导致C—N键的断裂，进而染料脱色矿化。

The specificity of hydrogen ion catalysts, for example, is very broad, whereas many enzymes perform only a single function, such as hydrolysis of a single bond or bond type.

例如，氢离子催化剂的催化范围特性很宽，反之，许多酶执行的只是单一的功能，譬如一种单键或一种键型的水解。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。