离子结构

The influences of the inclusion of Na~+ into each conformer (C7AB, C7"AB, C7eqB, C5A, C7axB orα"B) of AD molecule on the Ramachandran angles of molecular backbone and the hydrogen bonds in AD moiety were discussed in detail. It was found that in the forming process of bidentate structures of Na~+-AD ion-complexes, the original H-bonds in AD molecule were fully broken down, accompanying with the new formation of the two Na-O bonds.

论文中详细探讨了Na~+-AD络合离子六种构象的空间构型，分析了丙氨酸二肽与Na~+作用过程中AD分子骨架Ramachandran角及分子内N(1)–H(1)…O(2)、N(2)–H(2)…O(1)、N(1)–H(1)…N(2)和N(2)–H(2)…N(1)氢键的变化，研究发现Na~+与AD分子形成双齿结构时，AD骨架中原先的氢键全部被破坏，继而形成了两个新的Na-O键；Na~+与AD分子形成单齿络合离子时，AD骨架中原先的氢键或者得到增强或者断裂之后出现新的强度更大的氢键。

Each starch reagent has its own mode of action on mineral surface, such as primary starch mainly by hydrogen bond, cationic starch by the co-action of hydrogen bond and electrostatic force (for minerals with negative charge on its surface), while carboxymethyl starch, hydroxamic acid starch and dialdehyde starch principally by chemical force accompanied with hydrogen bond and electrostatic force in part. Such chemical forces ensure the close adsorption of reagent on diaspore surface and enforces the hydrophilic of mineral surface. Also the branched chain enable the starch to cover the collector adsorbed on mineral surface, so as to depress diaspore furthermore.

不同淀粉药剂在矿物表面表现不同作用，原淀粉主要是氢键的作用，阳离子淀粉是氢键和静电力的共同作用，羧甲基淀粉、羟肟酸淀粉和双醛淀粉离子性药剂与矿物间的作用除了氢键、静电力外，更重要的是与矿物表面金属离子间产生的化学作用，使药剂能牢固地吸附在一水硬铝石矿物表面，增加矿物表面的亲水性，同时，淀粉支链结构的存在，使它能够掩盖吸附的捕收剂，达到抑制一水硬铝石的目的。

In order to complete the investigation, impersonality feasible experiment solutions and devices are designed independently to systemically investigate on activation and transfer characteristic of soil heavy metal under acid rain effect. Primary results are shown as followings:1. PH measuring results of soil solution and eluviation solution show that the ability of experimental plot the acid buffer capacity of soil is stronger under the experiment condition,there is no obvious acidification in soil which after acid rain eluviation.The result has substantial differences with that gotten by most of investigationers in similar work before.

这一结果与以往类似研究中多数研究者得到的结论存在本质区别，原因可能在于此次试验的试验条件与以往研究的试验条件不同，其中最主要一点是在本次试验中使用的土壤样品的重量比以往试验均显著增大，而且使用的是土壤结构和组成等均未经破坏的原位土，从而使入渗酸雨与承受酸雨沉降的土壤之间的比例关系更接近自然酸雨沉降过程，以此为基础得到的试验结果应该更加客观、可靠。2、酸雨对盐基离子活化迁移产生的影响勿庸置疑，但是，在盐基离子活化迁移的过程中，并没有出现预想中的重金属元素活化迁移现象，表明土壤中的重金属元素并不如理论分析的那样对酸雨沉降反应敏感。

The bismuth and europium ions were doped into Y_2O_3 red phosphor s and their structure and optical properties were investigated.

将铋离子(Bi3+)加入铕离子掺杂的氧化钇红色荧光体中，探讨了其结构与光学性质。

Lanthanides belong to the sixth cycle of the periodic table Ⅲ B family, are all solid metal, they are La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, holmium, erbium, thulium, ytterbium, and lutetium were 15 kinds of metals and their periphery are two layers of electronic 5d16s2, while the peripheral third layer f orbital but never zero to 14, so the external electronic structure of 4f0-145d16s2, and therefore these elements in oxidation number are to 3, very close chemical properties, extraction, when it is difficult to separate them they are mostly multi-element mineral mix, more difficult to increase refining, and their atomic number of 57-71, one by one to increase the number of protons the nucleus, and thus extranuclear electron of gravity is also growing, so that atomic radius decreases with increasing atomic number Z, which makes lanthanides contraction, ionic radius is also reduced, which also makes Zr, Hf, Nb and Ta, Mo and W, the atom and ionic radius very close to each other they also determine a similar nature, resulting in difficult separation, also the tribe Ⅷ of the fifth cycle, ruthenium, rhodium, palladium, and the sixth cycle, osmium, iridium, platinum is very similar in nature, thus The six elements, said platinum group elements.

镧系元素属于周期表第六周期中ⅢB族，全部是固体金属，它们是镧、铈、镨、钕、钷、钐、铕、钆、铽、镝、钬、铒、铥、镱和镥共十五种金属元素，它们的外围两层的电子均是5d16s2，而外围第三层的f轨道电子却从零增加到14个，所以外围电子结构为4f0－145d16s2，而使这些元素氧化数均为＋3，化学性质极为接近，提炼时很难分开，它们的矿石又大多是多种元素混在一起的，更增加提纯难度，它们的原子序数为57－71，核内质子数逐个增加，因而对核外电子引力也不断增强，使原子半径随原子序数Z增加而减小，这就使镧系元素收缩、离子半径也缩小，这也使得Zr和Hf，Nb和Ta、Mo和W等原子和离子半径都很接近、也决定了它们彼此性质类似，以致难以分离、也使第Ⅷ族中第五周期的钌、铑、钯和第六周期的锇、铱、铂在性质上极为相似，因而称这六个元素为铂系元素。

This special ordered nanoporous structure creates the fast electrochemical accessibility of the electrolyte and OH- ions not only to the surface of the electrode materials but also to the bulk of the CoOH2 phase,which is very helpful for making full use of the electroactive sites to take place the faradic reaction,providing an important morphological foundation for a high specific capacitance.

这种独特的有序纳米孔结构不仅提供了电解液和OH-离子快速进出电极表面的通道，而且可以使活性离子扩散到CoOH2的本体相，充分利用电极材料的电活性位发生氧化还原反应，为该材料高比电容的实现提供了重要的形貌基础。

Differences of wettability and floatability between diaspore and aluminium silicate minerals are due to the differences of crystal structure between diaspore and aluminium silicate minerals, and of the part Al-O, Si-O bonds, and the metal ions on the surface of the minerals.

一水硬铝石与铝硅酸盐脉石矿物晶体结构的差异、表面断裂的Al-O和Si-O键及表面离子活性区的差别，可影响矿物表面的润湿性与可浮性，类质同象及各种晶格杂质离子也将影响浮选剂与矿物表面的相互作用和矿物可磨性。

The results show that the calculated cell parameters are in agreement with the experimental ones. The interactions between Li—N and Al—N are strong ionic bonds in Li3AlN2. The interaction between N and H is strong covalent bond and the interaction between Li and N is strong ionic bond in LiNH2. The calculated reaction enthalpies are 23.7 and 55.3 kJ/mol, respectively, which are in agreement with the experimental ones.

结果表明：Li3AlN2的Li—N、Al—N键主要为离子键，LiNH2的N—H键主要为共价键，Li—N键主要为离子键；298 K时贮氢反应的反应焓计算值分别为23.7和55.3 kJ/mol，与实验值均符合得较好；反应中各固态、气态物质的晶胞的结构优化后的晶格常数、键长与键角等与相应的实验值均符合较好。

Describe the lattice structure of ionic compounds as a regular arrangement of alternating positive and negative ions.

描述离子化学物晶格结构是由交替排列的正负离子规律的排布构成的。

Based on the experimental results reported in literature, the dissolution and separation performance of ionic liquids for lignin, cellulose and hemicellulose are summarized. The relationship between structure of ionic liquids and their dissolution performance is analyzed, and the possible dissolution mechanism is discussed.

根据目前所报道的研究结果，总结了不同离子液体对木质素、纤维素、半纤维素的溶解作用以及对木质纤维素的分离性能，分析了离子液体的结构与其溶解性能的关系，讨论了可能的溶解机理。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。