离子结构

Because the olefinic hydroxyl groups are linked with olefinic carbon, so it can ionize H〓 ion and present the properties of weak acid, and so the olefinic hydroxyl groups change into the structure of alcoholate in the presence of alkali , but the structure of alcoholate may change into the structure of olefine alcohol again, after the Na〓 ions is removed, or when the pH value of its solution turn into pH. Because the structure of the olefine alcohol is not stable and is easy to isomerizate to become the structure of olefine ketone, so there appear the ca. 1730cm〓 C=O absorption peak in the IR spectra of the products.

明确指出了在C〓、C〓富勒醇中存在烯碳羟基与叔碳羟基等二类羟基，烯碳羟基由于与一个共轭体系相连，从而其羟基可以离解而呈现出弱酸的性质，因而在碱性条件下易形成烯醇钠盐的结构，当除去钠离子后或在酸性溶液中，烯醇钠盐结构转变为烯醇结构，但由于烯醇结构不如烯酮结构稳定，从而形成烯醇结构后，烯醇结构异构化为烯酮结构，因此在其产物的IR谱图上出现1730cm〓附近的C=0吸收信号。

From the angle of engineering application, this article analysed the corrosion characteristics and damage causes of the current structural used concrete in the region of Hangzhou gulf, on the basis of on-site survey of all the Marine concrete projects in that area. Taking HPC used in Marine as research objective, this article put great emphasis on the influence of the composition cementing material system to concrete performance, and make a preliminary probe into the action mechanism of the composite effects of various mineral materials in improving the performance of concrete by laser measuring size machine and EMPA. Through experiments, the article discussed how chloride ingression in concrete will be effected by such factors as exposure time, chloride binding, environment temperature, stress and cracks conditions; and also analysed the symptoms of these factors in the model of concrete service life prediction by conference to all related research reports both home and aboard. On the foundation of abovementioned research, this paper brought up an engineering model of service life prediction of marine concrete, which is based on chloride-induced corrosion.

本文从工程应用的角度，在对杭州湾地区既有海工混凝土工程作实地调研的基础上，研究分析杭州湾地区既有海工混凝土结构的腐蚀特点和破坏原因；以海工高性能混凝土为研究对象，着重研究复合胶凝材料体系对混凝土性能的影响，并应用激光粒度仪、EMPA等分析手段，就复合胶凝材料的作用机理进行初步探讨；试验研究混凝土暴露时间、胶凝材料对氯离子的吸附、环境温度、应力和裂缝状态等因素对混凝土中氯离子迁移运动的影响，并结合国内外相关研究报导，探讨这些因素在混凝土使用寿命预测模型中的表征；在上述研究基础上，提出以氯离子侵蚀为基础的海工混凝土使用寿命预测的工程应用模型。

After that we give a presentation of ion lysenkoism which describe the potential change between the two sides of membrane and present the Hodgkin-Huxley model and it\'s equations set.We introduce the basic conception of stochastic resonance and coherence resonance subsequently.

然后，给出了神经元的基本知识，包括神经元的基本结构，神经元细胞膜离子浓度的分布，离子电位梯度和平衡电位，神经元的静息电位、动作电位，接着本文给出了描述神经元膜两边电压变化的离子学说及Hodgkin-Huxley模型和它对应的方程。

Because of the nondirectional property of ionic bond and the fully delocalized property of pi electrons on carbon layers, translation will not change the electronic structure of carbon layers, resulting in that A-GIC and AE-GIC hare quite good lubrication as well. The electrons come from metals mainly transfer to the delocalized pi orbitals of carbon layers, and the increase of delocalized electrons will make metal graphite intercalation compound more electro-conductive than graphite itself. Because ionic bond between metals and carbon layers is weaker and its lattice energy is much less than that of typical NaCl crystal, so metals could be left from interlayers. The Mulliken populations of C-C in intercalation compounds are smaller than that of graphite, and the HOMO energy level of GIC is higher than that of graphite too. These Lead to that GIC will easier be oxidized.

由于离子键没有方向性，又由于碳层中的π电子是充分离域的，所以碳层不会由于平移而改变其电子结构，金属石墨层间化合物仍具有很好的润滑性；金属失去的电子主要转移到碳层的离域π轨道中，碳层离域电子增多使金属石墨层间化合物的导电性比石墨增强；金属与碳层间的离子键强度比较弱，其晶格能远小于典型的离子晶体，因而金属易从石墨层中脱出；金属石墨层间化合物中的C-C间Mulliken布居值小于石墨中C-C间的值，且金属石墨层间化合物的HOMO能级也高于石墨的HOMO能级，所以石墨层间化合物中的碳原子较石墨更易被氧化。

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist"s attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What"s more, PILM was mainly studied as a catalyst in oil refining process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有&三明治&结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点，但是目前国内外大量报道的PILM制备大多采用离子交换法，生产周期很长，影响因素很多，并且产物热稳定性不够高，特别是水热稳定性较差，这是其不能在实际中大规模生产和应用的主要障碍，因此制备一种高稳定性的PILM意义非常；文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物，传统的离子交换法必须将钙基蒙脱石钠化改型，其成本相当高，而自然界中大量存在的却是钙基蒙脱石，直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义，但目前这方面的报道却很少见；另外，迄今为止，PILM作为催化剂的研究领域主要在石油的炼制中应用，而在煤炭的液化中却鲜有报道，如果能在煤炭转化领域应用这一成果，其影响也将是相当大的。

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist's attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What's more, PILM was mainly studied as a catalyst in oil refinin g process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有&三明治&结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点，但是目前国内外大量报道的PILM制备大多采用离子交换法，生产周期很长，影响因素很多，并且产物热稳定性不够高，特别是水热稳定性较差，这是其不能在实际中大规模生产和应用的主要障碍，因此制备一种高稳定性的PILM意义非常；文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物，传统的离子交换法必须将钙基蒙脱石钠化改型，其成本相当高，而自然界中大量存在的却是钙基蒙脱石，直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义，但目前这方面的报道却很少见；另外，迄今为止，PILM作为催化剂的研究领域主要在石油的炼制中应用，而在煤炭的液化中却鲜有报道，如果能在煤炭转化领域应用这一成果，其影响也将是相当大的。

The intensity ratio of TO and LO inMCT was observed to be different. Such difference was explained in terms of the different Ramangeometry arrangement.〓. The laser-induced micro-photoluminescence in the range of 1000～5000〓(1.34eV～1.83eV) was found for the first time in LPE MCT epilayer. The center of photoluminescence wasat 2750〓 or 1.62eV and the FWHM of luminescence was 2000〓 or 0.25eV. We assume thatthe photoluminescence is due to recombination of electron from an anion vacancy resonance levelto the top of valance. In addition, new Raman shift was observed at 750〓 in LPE MCTepitaxial film.〓. The laser-induced micro-photoluminescence with quasi-periodic structure was observed forthe first time at room temperature in one of MOVPE MCT epitaxial film samples. The range offluorescence was from 1.46eV to 2.21eV, i.e., 1.73eV above the conduction band edge.

2首次在LPE生长的碲镉汞外延薄膜的显微Raman谱中，在1000～5000〓范围发现了激光激发显微荧光，该荧光的发光范围换算为电子伏特标度为1.34eV～1.83eV，荧光的发光中心大约位于2750〓，即1.62eV，发光的半峰高宽约为2000〓或0.25eV；指出该显微荧光来源于碲镉汞薄膜中的阴性离子空位共振能级的激光激发发光；观察到了碲镉汞外延薄膜中一个新的Raman散射峰，位于750〓位置； 3首次在一块用MOVPE方法生长的〓Te外延薄膜的显微Raman谱中，发现了1.46eV至2.21eV范围并伴随有周期结构的显微荧光峰，该发光峰对应的能带中心位于〓Te材料导带底上方1.73eV，通过研究得出样品在1.46eV至2.21eV范围的显微荧光峰是由于改进 MOCVD 生长工艺，提高了碲镉汞外延薄膜的结构质量所致；通过分析指出该显微荧光来源于外延层中的阴性离子空位的共振能级发光。

Sensing ability of PSS/PANI self-assembled film with different doping/dedoping structure to DMMP and CEES was investigated. Results demonstrate that the gas sensitivity of PSS/PANI self-assembled film is affected by the size of dopant counterions. Gas sensitivity of self-assembled film increases with increasing size of dopant counterions. It is found that sensing ability of PSS/PANI self-assembled film to DMMP increases significantly by redoping/dedoping EB-PSS/PANI film with sarin acid that has similar structure with DMMP.

首次考察了不同掺杂/脱掺杂结构的PSS/PANI自组装膜对化学战剂模拟剂DMMP和CEES的敏感性能，研究表明，掺杂酸对离子的尺寸大小对PSS/PANI自组装膜的气敏性有很大影响，较大的对离子尺寸有利于提高自组装膜的气敏性；并且发现采用与DMMP结构类似的沙林酸对EB-PSS/PANI自组装膜进行再掺杂-脱掺杂，能显著提高PSS/PANI自组装膜对DMMP的敏感性能。

The 1%-Ni-doped TiO_2 calcined at 400℃has the best photocatalic ability.An indigo carmine solution of 10 mg/L was completely photodegraded in 50 minutes in the presence of as-obtained photocatalyst under visible light.A series of structure analysis,such as XPS,TEM,are employed to investigate the structure of the Ni/TiO_2 composite in details.The results indicate that at the lower temperature,instead of the simple interface compounding reported by some references,the Ni ions could be inserted into the crystal lattice of TiO_2,and form the innovative material.

通过XPS、TEM等多种表征手段对镍掺杂纳米二氧化钛的结构与光(来源：6414A41BC论文网www.abclunwen.com)催化性能进行了深入分析研究，发现在较低温度下煅烧可以获得镍离子晶格掺杂而不是表面复合的新型材料，通过镍离子缺陷能级的引入改变了二氧化钛的能级结构，提高了材料可见光下的光催化氧化的效率。

The main works included atomic structures and properties of the superheavy element Hs(Z=108)and Uub(Z=112)as well as hyperfine structures of Be-like ions.

主要工作分为两部分，1研究了Hs(Z=108)和Uub(Z=112)原子的能级结构及激发态、离子态性质，2研究了高离化态类铍离子的超精细结构。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。