离子结构

In this paper, after taking over coupling effect between electronic spin and orbital angular momentum, to revise the formula of electronic angular momentum in Bohr's theory, and electronic speed formula is obtained in a single-electron system, and to correct the energy level formula of atomic orbit in Schr? dinger's method by relativistic effect, the theoretical improving formula is built for spectrum fine splitting calculation, the calculated values are in good agreement with experimental ones, and reflect changing law of spectrum fine splitting values.

本文在考虑了电子的自旋角动量与轨道角动量的耦合作用后，通过对Bohr理论中的电子运动角动量的修改，推导出单电子体系的电子速度公式，结合对Schrdinger的原子轨道能级表达式相对论效应修正，从而得出本文的氢及类氢离子光谱精细结构值的理论计算公式，应用此改进公式，所得的计算值与实验观测值符合得很好，计算结果也反映了氢及类氢离子光谱精细结构数据变化的规律性。

The relationship between the crystal structure and their point of zero charge, the floatability of some silicate minerals with and without metal ions as activator, using sodium oleate as collector, the adsorption behavior of the metal ions on the silicate minerals, are investigated by analysis the crystal structure of the silicate minerals.

通过分析硅酸盐矿物晶体结构，研究硅酸盐矿物零电点与晶体结构的关系，硅酸盐矿物在油酸钠体系中的浮游特性，硅酸盐矿物对金属离子的吸附规律，金属离子活化的矿物可浮性规

Mixture microcrystal deposit obtained in high concentration of tungsten and current density.

当镀液中钨离子含量低，电流密度低时，镀层为晶态结构；当镀液中钨离子含量高，电流密度大时，镀层呈非晶态或混合微晶态结构。

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist"s attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What"s more, PILM was mainly studied as a catalyst in oil refining process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有"三明治"结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点，但是目前国内外大量报道的PILM制备大多采用离子交换法，生产周期很长，影响因素很多，并且产物热稳定性不够高，特别是水热稳定性较差，这是其不能在实际中大规模生产和应用的主要障碍，因此制备一种高稳定性的PILM意义非常；文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物，传统的离子交换法必须将钙基蒙脱石钠化改型，其成本相当高，而自然界中大量存在的却是钙基蒙脱石，直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义，但目前这方面的报道却很少见；另外，迄今为止，PILM作为催化剂的研究领域主要在石油的炼制中应用，而在煤炭的液化中却鲜有报道，如果能在煤炭转化领域应用这一成果，其影响也将是相当大的。

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist's attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What's more, PILM was mainly studied as a catalyst in oil refinin g process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有"三明治"结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点，但是目前国内外大量报道的PILM制备大多采用离子交换法，生产周期很长，影响因素很多，并且产物热稳定性不够高，特别是水热稳定性较差，这是其不能在实际中大规模生产和应用的主要障碍，因此制备一种高稳定性的PILM意义非常；文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物，传统的离子交换法必须将钙基蒙脱石钠化改型，其成本相当高，而自然界中大量存在的却是钙基蒙脱石，直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义，但目前这方面的报道却很少见；另外，迄今为止，PILM作为催化剂的研究领域主要在石油的炼制中应用，而在煤炭的液化中却鲜有报道，如果能在煤炭转化领域应用这一成果，其影响也将是相当大的。

From the point of ion exchange and chelating ,the high adsorption selectivity was investigated by the peculary structure of amidoxime fiber(combined with crosslinking structure and the maximal conversion of cyano) and Au ion.

从离子交换和螯合吸附的角度，根据偕胺肟基纤维本身的交联结构和最大氰基转化特点以及金离子本身的结构特点对其高选择吸附性能进行了解析。

Crystal structure of melilite is limited by MgO content of glazes, also restricted by O/Si ratio. Because of differences of ionic radius and ionic polarization capacity between Ca〓 and Mg〓, suitable O/Si ratio for melilite is influenced by content of CaO and MgO to a certain extent.

结晶釉中黄长石结构的出现，除了和MgO含量相关外，还受O/Si比值的限制；而Ca〓和Mg〓离子半径和离子间的极化能力的差异，使钙镁含量对形成黄长石结构的O/Si比值具有一定的影响。

Applying the Large-scale multi-configuration Dirac-Fock wave functions, we calculated the parameters such as wavelength, oscillator strengths and excited energy for the transitions related to lightning spectra. The most important effects of relativity, correlation, and relaxation are included in the computational model. Comparison of the calculated results with experimental spectra shows that the spectra in plateau area have a distinctive characteristic. Beside the lines of lower excited state with n=3 in NII ions, transitions of NI and OI are increased, their excited energy is around 13~14eV, and there are rarely lines from OII ion.

将原子结构的理论应用於闪电光谱的研究，用多组态Dirac-Fock方法，计算了有关光谱线的波长、振子强度以及相应的激发态能量等参数，理论与试验观测资料进行比较分析后发现，高原地区闪电首次回击光谱的结构及跃迁特性与其他地区有明显的区别，除NII离子n=3的低激发态产生的跃迁谱线外，激发能量为13~14eV左右的中性NI和OI的跃迁增多，但很难观测到OII离子的跃迁谱线。

A pplying the Largescale multiconfiguration DiracFock wave functions, we cal culated the paramete rs such as wavelength, oscillator strengths and excited energy for the transitio ns related to lightning spectra. The most important effects of relativity, corre lation, and relaxation are included in the computational model. Comparison of th e calculated results with experimental spectra shows that the spectra in plateau area have a distinctive characteristic. Beside the lines of lower excited state with n=3 in NII ions, transitions of NI and OI are increased,their excited energy is around 13～14eV, and there are rarely lines from OII ion.

将原子结构的理论应用于闪电光谱的研究，用多组态DiracFock方法，计算了有关光谱线的波长、振子强度以及相应的激发态能量等参数，理论与试验观测资料进行比较分析后发现，高原地区闪电首次回击光谱的结构及跃迁特性与其他地区有明显的区别，除NII离子n=3 的低激发态产生的跃迁谱线外，激发能量为13～14eV左右的中性NI和OI的跃迁增多，但很难观测到OII离子的跃迁谱线。

Harbin Institute of Technology, Harbin 150001, China）Abstract: The modified layers by O2-PBII technology on Ti6Al4V alloy surface were studied using X-ray photoelectron spectroscopy. The negative pulse voltage of 10, 20, 30 kV was applied to the sample, which was mounted on an oil-cooled sample holder. The results show that the thickness of the oxide layer increases with increasing implanted ion energy.

摘 要：采用等离子体基离子注氧技术（O2-PBII）对Ti6Al4V合金进行了表面改性处理，实验过程中改变注入离子能量的工艺参数，负脉冲偏压分别为10、 20、 30 kV，离子注入过程中样品台通油冷却以实现低温注入；用XPS对离子注氧层的深度、成分及化学结构进行了系统的分析。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。