离子结构

In order to investigate the relationship between the open-chain ligands and metal ions, and the possibility of the metal complexes used as electroluminescent materials, a new naphthol schiff base ligand which is a open-chain crown and its four transition metal complexes, a new amide type tripodal ligand containing heterocyclic ring, two tripodal ligands (H〓L〓 and H〓L〓) containing phenol schiff bases and their rare earth complexes were synthesized and characterized.

为了进一步研究和探讨开链配体与金属离子的配位作用，以及金属配合物作为电致发光材料的可能性，我们设计合成了含萘酚环的Schiff碱开链冠醚H〓L〓及四种过渡金属(Zn、Ni、Co、Cu)配合物，两个含酚羟基的Schiff碱三足配体H〓L〓和H〓L〓及稀土配合物，一个含杂环的酰胺型三足配体L〓，培养了配体L〓的单晶，确定了其晶体结构。

The hardness improved from 0 55GPa for unimplanted Kapton to 6 7GPa,corresponding to a factor of improvement of about 12.Reciprocating sliding wear tests using a steel ball counte...

通过X 射线光电子能谱实验得出注入He+离子后的薄膜表面层中O、N原子含量降低，形成以苯环为主的三维立体网状结构

It is a original work in the world that using these ligands to coordinate with vanadyl cation to form complexes and the study of the structures along with the anti-diabetic properties, thus provide us opportunity to obtain vanadium drug with the properties of lowering blood sugar significantly and low toxicity, the research will benefit the large number of diabeticpatients, the economic and social benefit will be obvious.

上述配体与氧钒离子形成配合物及结构和抗糖尿病功能的研究在世界上属首创工作，使我们有望制备出具有显著降血糖功能且低毒性的钒类药物，为广大糖尿病患者带来福音，产生明显的经济效益和社会效益。

According to Johnson's Rule and IR spectra, their possible structures are suggested. The bonding parameters of those complexes are calculated by ESR parameters. And the crystal field parameters are calculated by using electronic spectral data. It can be seen that the vanadyl complexes in the solution are ionic complexes and that the α〓 values of those complexes decrease following the increasing of the N donor replacing the O donor of water on the equatorial plane in those complexes. This means that the covalent bonding between vanadium and ligand increases as Ser, Phen or Bipy replace water ligands. The results show the competitive coordinate law that the coordination reactivity of Phen and Bipy is much stronger than that of Ser. The simulation program of ESR is compiled by the theory of ESR in the present work.

测定了VO-丝氨酸二元体系、VO-丝氨酸-邻菲咯啉三元体系和VO-丝氨酸联吡啶三元体系在不同酸度下（pH=1.0～14.0）的乙二醇／水（V／V=1：1）溶液低温ESR谱，发现不同pH下，溶液中具有不同组成的配合物，根据不同pH下ESR谱的变化，利用Johnson的加合规则并结合红外光谱，推测了它们在溶液中的可能结构；利用波谱参数计算了配合物键参数；利用电子光谱数据计算了配合物的晶体场参数，讨沦了它们的成配特性，结果表明：VO配合物属离子型配合物，随取代水分子的配体（Ser、Phen或Bipy）数目增加，键参数减小，配合物共价性增强，同时得出这些体系中，生物配体竞争配位规律：Phen和Bipy与VO的配位能力比Ser强。

A new technique to characterize microstructure of RE complexes withcooperative vibronic spectra of RE ions is established and developed.

本文建立和发展了一种利用稀土离子的电子振动光谱来表征物质微观结构的新技术。

Two structures can be drawn that have a net charge of zero, but the predominant form of alanine at its pI is zwitterionic.

净电荷为零的结构有两种，但是主要的形式为兼性离子。

Its chemical structure ensures that the thickener does not react with cationic, anionic or zwitterionic surfactants and emulsifiers and does not require neutralization.

其化学结构确保增稠剂没有反应，阳离子，阴离子或两性离子表面活性剂和乳化剂，并且不需要失效。

It is concluded that the infrared photodissociation spectroscopy of protonated serine clusters H+n, n = 2 8, provides evidence for a size-dependent transition from neutral to zwitterionic network structures.

第四章的结论中提到由此一系列由二至八的丝胺酸团簇红外吸收光谱结果，我们观察到从二聚体的中性丝胺酸单位到八聚体的两性离子单位，中间经历了结构转换的过程。

The 3565 cm-1 band, on the other hand, progressively decreases in intensity with increasing n and it disappears completely at n = 8, suggesting that the protonated serine octamer is dominated by zwitterionic structures.Chapter four gives a conclusion.

当此团簇的丝胺酸数目渐多时，第一根吸收峰（3565 cm-1）的高度则随著渐减，直到八聚体时这根吸收峰完全消失，证明了质子化丝胺酸八聚体在气相状态下的结构是以两性离子为主。

A chemical or chemicals viewed from the perspective of their structural characteristics. Included here are concepts which can mean either a salt, an ion, or a compound (e.g.,"Bromates" and "Bromides").

根据其结构特性划分的一种或一类化学物质，包括某种盐，某种离子或某种化合物，如溴酸盐及溴化物。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。