离子结构

It was proved by IR spectroscopy that Zn(superscript 2+) and hydrolyzed ion were chelated with polysilicic acid to produce the polymer of zinc-silicon. The reaction was not the simple physical blending, but the chemical reaction forming the inorganic polymer with special structure. The better flocculating efficiency was resulted mainly from the chemical and physico-chemical factors among the components.

红外光谱证实了PZSS中Zn(上标 2+)及水解Zn(上标 2+)离子可与共存的聚硅酸起螯合反应生成锌硅聚合物，聚硅酸与Zn(上标 2+)反应并不是单纯的物理混合加成作用，而是形成了具有特殊结构的无机高分子的化学反应，这种新型絮凝剂所具有的优良絮凝特性是由各物质间以化学作用为主的物理化学因素共同作用的结果。

The results from ultraviolet spectroscopy and photo -luminescence spectroscopy revealed that:(1) Europium complexes based on neutral ligands, such as azaphenanthroline 2-aryl-5-(α-pyridyl)-1,3,4-ozadiazole had a strong UV absorbance at the wavelength of 290-350 nm and the characteristic PL spectrum of europium ion at 613 nm respectively;(2) The structures of ligands had a critical role influence on PL intensity of europium complexes.

紫外光谱和光致发光光谱研究表明：(1)以氮杂邻菲罗啉、2-芳基-5--1，3，4-噁二唑为中性配体的铕配合物在290～350nm左右都有强烈的紫外吸收，且在紫外光的激发下都能产生铕离子的特征光谱(613nm)；(2)配体的结构是影响铕配合物发光强度的关键因素之一。

It has been successfully applied in the fields of high-performance carbon fiber, needle coke used for ultrahigh power electrode, anode of rechargeable lithium-ion batteries, activated carbon with super-high surface area, catalyst supports and carbon foams、 In this paper, the effects of raw materials and pyrolysis conditions including heat-treatment temperature, pressure and time on the formation and development of carbonaceous mesophase were discussed in detail Since complex constitutes of raw material, various reactions and phases are involved in the process of mesophase evolution, we suggest that a given carbonaceous mesophase product should be manufactured by selecting raw materials and setting pyrocondensation conditions according to the specific requirement of the product, so that products with the best structure and performance could be obtained.

它在高性能炭纤维、超高功率电极用针状焦、锉离子二次电池负极、超高比表面积活性炭及催化剂载体、泡沫炭等领域得到了较好的应用。综述了原料和热缩聚条件对炭质中间相形成和发展的影响，这些影响因素包括原料的种类、热缩聚温度、反应压力和保温时间等。通过讨论指出，由于炭质中间相涉及的原料种类多样，热缩聚制备过程中涉及的反应、物相复杂，因此，在制备特定性能的产品时，应针对产品的特定性能要求来选择原料、设定热缩聚条件，以制得具有最佳结构和性能的产品。

As a solvent, it was mixed with various quantity of pigskin collagen powder. During the dissolution, three kinds of heating methods were applied. The one was be heated in water bath directly, the second one was be heated in water by microwave radialization and the third one was be heated by microwave radialization directly.

通过普通水浴加热，微波辐射水浴加热和微波直接辐射加热三种方式研究了离子液体对胶原蛋白的溶解能力，对不同质量浓度的溶液进行傅里叶变换红外测定，分析溶液中的胶原蛋白结构的变化，最后，对溶液进行再生得到皮胶原蛋白膜，并进行红外分析。

L-aspartic acid s are intercalated into magnesium aluminum layered double hydroxidesby using the methods of reprecipitation and coprecipitation.

以镁铝水滑石为插层主体、L-天冬酸离子为插层客体，分别用返混沉淀法和共沉淀法制备了 L-天冬酸根插层镁铝水滑石手性层柱材料，并用 FT-IR、XRD 和 DTA 对其结构进行了表征。

With increase of the doping amount of CuO, the system was transformed from the tetragonal to the rhombohedral.

Cu离子由于d〓构型也会发生姜—泰勒效应(Jahn-Teller effect)而引起体系的晶格畸变，随CuO含量的增加，体系的相结构由四方相向三方相过渡。

The XRD and Raman analysis show that LSGM1020 possesses rhombohedral structure, and its condu...

XRD和Raman分析表明LSGM1020电解质具有菱方钙钛矿结构，800oC时测量得到的氧离子电导率达到0.12Scm-1。

Our model is obviously superior to Rinker'smodel. because Rinker's model potential is a combination of Thomas-Fermi-Dirac potential and Hartree-Fock-Slater potential for the isolated ion.

我们的模型明显优越于Rinker的模型在于： Rinker的模型采用的是Thomas-Fermi-Dirac势和自由原子的Hartree-Fock-Slater势的迭加形式，而我们的模型中除离子的结构因子外，电子散射势、化学势及电离度等量都是通过自洽迭代方法计算的。

Background and Objective: The basic structure of salicylaldehyde amino acid Schiff base compounds includes a C=N chemical bond.

背景与目的：水杨醛氨基酸Schiff碱基本结构中含C＝N键，当基与金属离子配位后生物活性增强，表现出一定的抗癌、抑菌等活性。

The reactions of pyridine-2-carbaldehyde semicarbazone with transition metal Ni(II,Cosalts afford two pyridine-2-carbaldehyde semicarbazone transition metal compounds.

配合物[CoL2]·(ClO4)2·H2O(3)，分子式C14H18Cl2CoN8O11，Mr=604.19，属三斜晶系，空间群P-1，晶胞参数：a=9.984(3) A， b=11.082(4) A， c=12.196(5) A ，Dc=1.769Mg/m3，α=112.954(4)°，β=110.050(4)°，γ=94.017(3)°，V=1134.4(7) A3， Z=2，μ=1.067mm-1， F(000)=614，结构偏离因子R=0.0501 和ωR=0.1028，配合物(3)的中心金属离子采取六配位的变形八面体。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。