离子结构

Bond breaking and the formation of alkyne end groups and free radicals were observed.

采用多种手段研究了35MeV/u的Ar离子辐照聚酯膜产生的微观结构变化。

In their structures, polyanions are bridged by Ln ions via the coordination of the bridging oxygen atoms and terminal oxygen atoms, forming a W–Ot′–Ln–Ob–W linkage; and through the W–Ot′–Ln–Ob–W linkage a one-dimension infinite linear chain with alternating cations and anions is formed.

在相似的合成条件下，我们向原有体系内加入顺丁烯二酸作为有机配体，合成了化合物7，其7的基本结构和化合物1-6很相似，但有一个顺丁烯二酸阴离子取代了一个NO3-离子的位置。

Inthe compound, Pr~(3+) cations are eight-coordinated with oxygen atomsfrom six DMSO molecules, two polyanions. The crystal structureindicates that the compound forms a one-dimensional zigzag chain builtfrom the alternating polyanions and cationic units throughW-O_d-Pr-O_d-W links.

结构分析结果表明，化合物中Pr~(3+)离子为八配位，配位氧原子分别来自6个NMP分子和二个杂多阴离子的端氧原子，金属配阳离子与杂多阴离子骨架通过W-O_d-Pr-O_d-W相连。

The crystallization thermodynamic data, such as solubility, metastable zone and other basic data of 6APA were measured based on experiments, which demonstrated that as an ampholyte 6APA can exist in solution as a combination of anionic, zwitterionic and cationic species.

实验数据证明6APA是一种两性化合物，其结构以及溶液行为类似于普通氨基酸，在溶液中以两性离子、正离子以及负离子的形式共存，通过改变溶液的pH值，可以极大地改变6APA的溶解度，这就是6APA等电点沉淀的原理。

By using the OP-10/JFC/ amyl alcohol non-ionic compound emulsifier as stabilizer, about 12% organosilicon was appended after the pre-polymerzation of MA, n-BMA, and MAA acrylate monomer was performed and the temperature was decreased to 62℃, and then the pH value was controlled in 7~8 after the polymerization.

结果表明，以OP-10聚醚渗透剂JFC/戊醇非离子复合乳化剂为稳定剂，在MA、n-BMA、MAA丙烯酸酯单体形成预聚体后降温至62℃，加入12%左右的有机硅单体，反应结束后控制pH值7~8，微乳液具有良好的稳定性，乳胶粒具有翻转型的核－壳结构。

Systematic investigations were made on relationship between nuclear magnetic resonance of chemical shifts of 291 phosphines and their molecular structure parameters of phosphorus atoms, such as ionicity index and stereoscopic effect parameters ε(subscript i.

采用离子性指数、立体效应参数ε(下标 i对291个膦化合物中磷原子进行结构表征，并与其核磁共振磷谱(31P NMR)建立定量结构波谱关系模型。

The precursor was prepared with ammonium zinc phosphate and lithium carbonate as materials via solid state reaction at room temperature.The target product was got after baking the non crystals precursor of the compound.

人们从对有层状结构的磷酸盐性质的研究中获知，大量具有层状结构的磷酸盐化合物能够承受离子交换而且还具有良好的催化性能。

Chloride permeability of concretes, which is determined through rapid chloride permeability test, is an important indicator of the ability of chloride ion penetration in concrete.

单位时间内通过混凝土结构的总电荷量是反映混凝土结构氯离子渗透能力的一个重要指标。

Based on the durability characteristics of prestressed concrete structures,the durability limit states of carbonation and chloride ion attack are defined,respectively.Durability predicting models on the basis of reliability mathematics and stochastic processes are constructed,and the pure theoretical formulae of failure probability of prestressed concrete structures are analyzed.

根据预应力混凝土结构的耐久性特点，分别定义了结构构件在碳化环境和氯离子侵蚀环境下的耐久性极限状态，建立了以可靠性数学和随机过程为理论基础的数学模型，并对耐久性失效概率进行了理论分析。

Therefore, the EL spectra of (Znq_2)_4 is wider than that of Znq_2. 4._2 was synthesized. The analysis of molecular spatial structure and the characterization of material performance of_2 and Liq showed that two Liq molecules and two Naq molecules were connected by Na-O-Na bond bridges to form_2. Compared with Liq,_2 exhibits stronger rigidity in planar molecular structure, larger steric hindrance and intermolecular distance, and much smaller molecular polarity, thus resulting in much longer fluorescence lifetime, much higher fluorescence quantum efficiency, wider energy bandgap and better film formability. When used as light-emitting layer in OLED,_2 shows lower formation probability of excited dimmer and exciplex formation than Liq, thus emits bluer light with higher current efficiency than Liq. When_2 ultrathin film is used as electron injection layer in OLED, it exhibits higher current density, higher luminance, lower turn-on voltage and higher current efficiency than Liq ultrathin film for the existence of sodium ions in_2 ultrathin film. 5. The summarization the relationship between molecular spatial structure and material performance of Alq_3,(Znq_2) and Liq, lead the conclusion that the molecular spatial structure of Mq_n affects its material performance in such aspects as the rigidity of planar molecular structure, intermolecular interaction, molecule stacking mode and intermolecular distance.

制备了_2，通过对_2和Liq的分子空间结构与性能进行分析与讨论，发现_2是通过两个Na-O-Na键桥将两个Liq和两个Naq连接构成的，其分子平面结构的刚性程度强于Liq，空间位阻大于Liq，分子之间的距离大于Liq，分子极性远远小于Liq；_2的荧光寿命长于Liq，荧光量子效率高于Liq，成膜性优于Liq；_2的禁带宽度比Liq大，光致发光光谱中_2的最大发射峰较Liq发生蓝移；当_2在OLED中作为发光层时，激发二聚体与激基复合物的生成几率远远小于Liq，发的光比Liq更蓝，电流效率大于Liq；_2超薄膜中有Na离子的存在，与Liq超薄膜相比，当其在OLED中作为电子注入层时，具有更大的电流密度，更高的发光强度，更低的阈值电压和更高的电流效率 5、对上述Alq_3、Znq_2和Liq的分子空间结构与材料性能之间的关系进行了归纳总结，认为Mq_n的分子空间结构主要在分子平面结构的刚性程度，相邻分子之间的相互作用，分子堆叠的方式和分子之间的距离这四个方面影响其性能。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。