离子结构

The first part is to synthesize 5-formyl -8- quinolinol from 8-uinolinol and chloroform , using ethanol as a solvent. Then analysizing the 5-formyl-8-quinolinol by IR. The second part is , according to ideas of molecule designing, to synthesize the new self-assembly Inorganic-Organic coordination polymers Co(u2-bpyV2O6,(C4H4N2)Ni2(H2O)2-V4Ol2,(Cl2Hl2N2)Co-V2O6 using Cu, Ni, and Co as templating, 4-cyano-pyridine(4-CNPy), 4,4-bipyridine,pyrazine, l,2-bis(4-pyridyl)ethane, 5-formyl -8- quinolinol as building blocks and Ammonium Metavanadate (NH4VO3) as subordinate building blocks by Hydrothermal , analysizing their content of element determining their structures by X-Ray diffraction.

本课题实验分为两部分：一是配体的合成，以8-羟基喹啉、三氯甲烷为原料，以乙醇为溶剂，合成了5—甲醛基—8羟基喹啉并且对其进行了IR的分析测定；二是配位聚合物的合成，通过分子设计，采用溶剂热法以Cu、Ni、Co为中心离子，以5—甲醛基—8羟基喹啉、4，4-联吡啶、吡嗪、1，2-二吡啶基乙烷为配体，以偏钒酸根(VO_3~-)为辅助配体，通过水热法自组装合成了新的3-D网状结构配位聚合物Co(μ_2-bpy)V_2O_6，(C_4H_4N_2)Ni_2(H_2O)_2·V_4O_(12)，C_(12H_(12)N_2Co·V_2O_6，并对其进行了元素分析和晶体结构的测定。

Firstly, the piezoelectric properties of Na_(1-xK_xNbO_3 based ceramics around morphotropic phase boundary were studied.

首先，研究了Li_xNa__(0.52-xK_(0.48)NbO_3系列陶瓷样品在准同型相界附近的压电性能，Li离子的加入并不改变陶瓷的物相结构，体系陶瓷仍为纯的钙钛矿结构。

In the second part of this work, a computor program is developed to calcalate〓L〓energy levels, reduced matrix elements, crystal field energy levels, oscillator strengths of f-f transition and theoretical f-f absorption spectra of f-ions. The calculation results of the f-f absorption spectra of Nd in water coordination sphere and H di (2-ethylhexyl phosphinic acid coordination sphere with different symmetric structure are shown and compared with observed spectra.

在第二部分中，编制了计算f离子的〓L，能级、约化矩阵元、晶体场中Stark能级分裂、f-f跃迁振子强度及f-f理论吸收光谱的计算机程序，以此程序分别计算了Nd在不同结构对称的水配位层及烷基磷酸配位层中的f-f吸收光谱，通过与实验谱比较，识别了可能的配位层结构，并讨论了f-f跃迁的强度机理。

The effect of metal salts on the physical structure of CaCO_3 was studied by using sodium carbonate as the additive and PoreMaster-60 mercury porosimeter.

利用添加剂调制改性的方法，考察了以碳酸钠为代表的金属盐对石灰石微观结构的影响，得出调制改性优化了石灰石的物理结构，并在离子比γ为15∶1的加入量效果最佳。

X-ray single crystal diffraction study reveals that the Zn atom is five-coordinated, Furthermore, a 2D superamolecular network is constructed via the tetracarboxylate bridged binuclear of Zinc SBU ,and the amino substituent results in the formation of hydrophilic 2D structure of the title complex.

该配合物中，锌离子为5配位，2个Zn原子和4个羧基形成的双核锌结构单元，进而形成二维方格式平面结构，氨基取代基导致配合物具有亲水性。

Active hydrogen atom and oxygen ion form Hydroperoxy radicals which surround the positively charged biological contaminants, and then react with three hydrogen elements of its protein structure, destroying and detoxicating the biological contaminants nature.

活性氢和氧离子(O2-)形成的氢过氧自由基，会包围着带正电荷的生物污染物，每一枚黏附在污染物表层的氢过氧自由基，会与其蛋白质结构中三个氢元素产生反应，完全破坏其结构，变成无毒状态。

A series of emulsion fuel oil were designed with Triton X 100 as principal emulsifying agent,whose molecular formula is C 8H 17 ——O(CH 2CH 2O) 10 H.One of other kinds of surfactant is used as the auxiliary emulsifying agent.The emulsion structures were determined by micrography,and the combustion heat was determined by a bomb calorimeter.

以具有聚氧乙烯为亲水基团的非离子表面活性剂为主要乳化剂，其它表面活性剂每种类型各取一个与之复配，进行替换对比，从而以最少的表面活性剂种类，得到尽可能全面的乳液结构类型，以便找出乳液结构与乳化燃油燃烧热之间的关系。

The ampholytes generally exhibited higher membrane affinity than expected from their hydrophobicity, which stemmed from attractive polar extra-interactions with phospholipid membrane, behavior similar to bases.

这强调了药物设计中的一个重要思路：在离子型药物的化学结构中引入一定的结构区域或功能团，以达到增强药物的膜亲和性而保持低的药物疏水性。

The atomic properties of the superheavy element Hs(Z=108)and Uub(Z=112)have been studied theoretically in conjunction with the effects of electron correlations and relativistic effects.

在超重元素原子结构的研究中，通过细致考虑电子关联效应和Breit相互作用，计算了Hs(Z=108)和Uub(Z=112)原子的激发态结构、共振吸收振子强度及其一价和二价离子的基态等相关性质。

Systematic investigations were made on relationship between 31P nuclear magnetic resonance of chemical shifts of 291 phosphines and their molecular structure parameters of phosphorus atoms, such as ionicity index and stereoscopic effect parameters.

摘 要 采用离子性指数、立体效应参数对291个膦化合物中磷原子进行结构表征，并与其核磁共振磷谱(31P NMR)建立定量结构波谱关系模型。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。