离子结构

The structure model of ionic crosslinked PVC-TPE was proposed, in which microcrystallites, entanglements and ion pair aggregates acted as crosslinking point.

提出以微晶区、缠结点和离子对聚集区为表观交联点的离子交联PVC-TPE结构模型。

The influences of alkali concentration, temperature, polymer and additive on ionic conductivity and electrochemical stability were studied with orthogonal experiments and single factor experiments design, the relation of structure and ionic conductibility is researched by FIRT, XRD,DSC and SEM analysis ways.

结合正交设计实验和单因素实验研究了碱浓度、温度、聚合物以及增塑剂对固体电解质离子电导率、电化学稳定性的影响，用红外光谱、X衍射分析和差热分析等手段研究其结构与离子导电性能的关系，摸索出了本实验条件下的最优方案。

The main content of this paper as follows: The acidic strength, reaction temperature, reaction time of Chlorine-aluminate Ionic Liquids with different structure of cation on the activity of transalkylation of MN with TeMB and the selectivity of 2,6-DMN were studied. The optimum reaction condition was obtained: the molar fraction of AlCl_3 is 0.71, molar ratio of 2-MN and TeMB is 1, the amount of ionic liquid is 32wt%, reaction temperature is 20℃and reaction time is 8h using X-xAlCl_3 and X-xAlCl_3 as catalysts; the optimum reaction time is shortened 6h using Et_3NHCl-xAlCl_3 as catalyst.

本文主要研究了以下内容：分别考察了不同阳离子结构的氯铝酸盐类离子液体的酸强度、反应温度、反应时间等因素对MN和TeMB转移烷基化的催化反应活性和2，6-DMN选择性的影响，优化得到适宜的反应条件为：以X-xAlCl_3和X-xAlCl_3为催化剂时，AlCl_3的摩尔分数x=0.71，2-MN和TeMB摩尔比为1∶1，离子液体用量为32wt％，反应温度为20℃，反应时间为8h；以Et_3NHCl-xAlCl_3为催化剂时，反应时间缩短到6h。

The equilibrium structure of the ionic cluster is very different in geometry from that of the neutral cluster.The results also revealed the significant difference between the two kinds of fragment ions and the corresponding neutral cluster.

研究结果表明：中性团簇最稳定构型为R－HNH2－HNH2(R∶1，4-二氧六环)，离子团簇由于发生质子转移，其构型与中性团簇有较大的不同，两类碎片离子R(NH3)＋和R(NH3)H＋与中性团簇R(NH3)的结构也有所不同。

Comparing with water, the optimal heat transfer enhancement is achieved near the critical micelle concentrations of surfactants. The degree of heat transfer enhancement is different with different surfactants and is influenced by solubility characteristic, ionic nature and chemical structure of surfactants. Boiling in surfactant solutions, when compared with that in water, is observed to be more vigorous with smaller-sized, more regularly shaped and faster departure frequency bubbles, but the surfactant solutions of Triton X-100 and Triton X-114 become cloudy for the cloud point of surfactants.

和水相比，表面活性剂强化池内核态沸腾换热的最佳浓度为临界胶束浓度；不同种类表面活性剂强化换热程度不同，它们与表面活性剂的溶解特性、离子类型和化学结构有关；溶液沸腾时，沸腾汽泡的脱离直径变小，脱离频率变快和更不易聚集，但非离子表面活性Triton X-100和Triton X-114由于存在浊点其沸腾溶液变浑浊。

FT-IR spectrum showed that the new bands at 3000cm-1~2700cm-1 and 1600cm-1~1400cm-1 were assigned to the C-H telescopic vibration and the framework vibration feature of imidazole ring, besides the characteristic bands of BMMs appeared in all samples, however, all of characteristic bands for imidazolium ionic liquid disappeared in the samples when calcined at 550oC, which implied that the structure of imidazolium ionic liquid has been destroyed during calcinations.

FT-IR分析测试中3000cm-1~2700cm-1及1600cm-1~1400cm-1波数范围内的谱带被认为是饱和的C-H伸缩振动和芳环骨架振动，说明离子液体的存在，这些峰只在萃取样品中出现，可见键连的离子液体的结构在焙烧过程中被破坏。

The completely diagonalized Hamiltonian matrices of 3d2/3d8 ion configuration in the trigonal symmetry have been established by irreducible representation method. Taken into account the influence of the spin-spin coupling interactions omitted in previous publications, the spectra and the constants of crystal structure and zero-field splitting parameters of CsNiCl3 crystal and CsNiCl3: Mg2+ crystal are calculated and the influence of the doping to the spectra, the constants of crystal structure, zero-field splitting parameters and Jahn-Teller effect are studied. The results show that doping can change the structure of crystal which brings about the changes in the spectra and zero-field splitting parameters as well as Jahn-Teller effect.

应用不可约张量理论构造了三角对称晶场中3d2/3d8态离子的45阶可完全对角化的微扰哈密顿矩阵，在考虑了以前工作中被忽略的自旋-自旋耦合作用的基础上计算了CsNiCl3晶体和CsNiCl3：Mg2+晶体的基态能级、晶体结构、零场分裂参量和Jahn-Teller效应，研究了掺入Mg2+对CsNiCl3晶体的光谱、零场分裂参量及Jahn-Teller效应的影响和自旋单重态对基态能级的贡献，发现掺杂使得晶体结构产生畸变，从而改变晶体光谱的精细结构和零场分裂参量，不改变Jahn-Teller效应的分裂规律但改变分裂的大小。

We compared the spectral and its secondary structure of endostatin with and without of zinc, heparin and lanthanides. It demonstrated that the pH has strong effect on the interaction of endostatin and heparin.

研究了内皮抑素与锌离子、肝素、稀土离子作用后蛋白质的光谱学性质和二级结构的变化，首次发现偏酸性pH对肝素与内皮抑素的结合作用有特殊影响，为研究内皮抑素特异抑制肿瘤组织新生血管的生成提供了实验依据。

In this paper, after a brief introduction for the composition and structure of lignin, cellulose, hemicellulose and room-temperature ionic liquids, the recent progress in dissolution and separation of lignocellulose with ionic liquids is reviewed.

本文在介绍木质素、纤维素、半纤维素和相关室温离子液体的组成与结构的基础上，综述了室温离子液体在溶解、分离木质纤维素方面的研究进展。

The main objective of this project is to apply the gel-casting technique, a novel ceramic forming method, in the development of IT-SOFCs. The gel-casting technique was investigated, modified and optimized to synthesize strontium doped lanthanum manganate La_(0.72Sr_(0.18)MnO_3, LSM, lanthanum strontium manganese chromite (La_(0.75)Sr_(0.25)_(1-x)Cr_(0.5Mn_(0.5)O_(3-δ), LSCM, LaCoO_3-based nano powders and lanthanum silicate apatite electrolyte powders.

本论文采用优化的凝胶注模工艺合成了以下粉体：Sr~(2+)离子掺杂的锰酸镧(La_(0.8)Sr_(0.2)_(0.9)MnO_3，LSM阴极粉体、Sr~(2+)和Mn~(2+)离子共掺杂的铬酸镧(La_(0.75)Sr_(0.25)_(1-x)Cr_(0.5Mn_(0.5)O_(3-δ)，LSCM阴极／阳极粉体、LaCoO_3阴极纳米粉体和磷灰石结构硅酸镧La_(10)Si_6O_(27)电解质粉体。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。