离子结合

Structures of Na~+-AD ion-complexes with 1 or 2 H2O molecules were obtained. It was found that H2O can bond with Na~+ in the structure of Na~+-AD to form Na-O van der Waals bond. H2O molecule can also bond with N or O atoms in AD moiety to form H-bonds as N-H…Ow or O…Hw-Ow. The former process takes place more easily. The most stable structures of Na~+-AD ion-complexes with 1 and 2 H2O molecules are W-C7AB and 2W-C7AB, respectively.αB conformer of Na~+-AD can not exist in the presence of 2 H2O molecules.

研究发现水分子可以结合在Na~+-AD络合离子中的Na~+附近形成Na-OW范德华键，也可以与Na~+-AD络合离子骨架结构中电负性较强的N或O原子结合形成N-H…OW或O…HW-OW氢键，相对而言，水分子更容易结合在Na~+-AD络合离子中的Na~+位置，Na~+-AD最稳定的带1个或2个水分子的结构分别为W-C7AB和2W-C7AB，Na~+-AD络合离子的αB构象在2分子水存在的情况下完全消失。

In the titration experiment of NMR and IR spectroscopy, we can understand how sensors binding with metal ions: the two carbonyl group and crown ether group cooperated in binding with metal ions. Furthermore, by altering the "oxygen" atoms of crown ether to "sulfur", we can change the binding affinity to the soft metal: cupper. It shows 60-fold enhancement of fluorescence.

在化合物2中，我们引进了硫原子在冠状醚中，则应对电子密度较低之金属有较好的结合能力，实验结果显示了此分子对铜离子有相当好的选择性和结合能力，萤光增加可达60倍；同时由红外光吸收光谱和核磁共振光谱滴定实验可确知，香豆素衍生物上的两个羰基对金属离子的选择性及结合上扮演相当重要的角色。

The purity of SAM product was higher than 95％, and the overall recovery of SAM sulfate and SAM double salt of sulfate and p-tosylate were 60％ and 50％, respectively.

通过筛选，获得了对SAM有较好选择性离子交换能力、较易洗脱和再生的争光D113弱酸型阳离子树脂，研究了温度、pH等对SAM离子交换的影响，根据SAM在弱酸阳离子树脂D113上的等温交换平衡行为表现出较强的可逆性，考虑到交换基的弱电解质性质以及结合Donan膜平衡理论，建立了考虑pH影响的可逆离子交换平衡模型，该模型可以较好地描述SAM平衡浓度、pH对离子交换平衡的影响；通过对动态离子交换过程的研究，得到了SAM在D113树脂内的有效扩散系数的数量级为1.0E-9cm〓/s～1.0E-8cm〓/s。

Binding states between modified flax fabrics and anion dyes have been investigated by infrared spectrometry, X-diffraction, peeling of color and experiments on water proofing of modified flax fabric with taking reactive red X-3B, direct Chinese red 6B and acid yellow G for examples. The results show that binding force between modified flax and acid dye is coulomb's force, and besides hydrogen bond and gravitation among molecule, electrovalent bond has been formed among direct dye and modified flax.

以直接枣红6B、活性红X—3B、酸性金黄G为例，采用X光衍射法、红外光谱法、剥色实验及织物表面防水实验，研究了改性亚麻织物与阴离子染料之间的结合状态，结果表明改性亚麻与酸性染料之间主要靠离子间的库仑力结合，与直接染料之间在形成氢键和范德华力的基础上，还形成了离子键结合。

Titanium ions were implanted into quartz and quartz coated with Ti film by MEVVA ion source implanter. The dose was 3×10^16 ions/cm^2 and 5×10^16 ions/cm^2. The ion energy and depth distribution were analyzed using simulation method.

为提高石英玻璃表面金属化膜层与基底的结合强度，利用金属蒸发真空弧离子源引出的Ti离子对石英玻璃及镀Ti膜石英玻璃进行离子注入，剂量选择3×l0^16 ions/平方公方，5×10^16 ion/平方公分，模拟分析了注入离子能量的分布。

The results suggest that CHBr3 is likely to intercalate into ctDNA and such intercalations mainly depend on the relative binding affinity of a metal ion to the bases and to the phosphate groups in DNA.

据此推断，CHBr3可能主要是通过嵌插作用与ctDNA碱基结合，金属离子对CHBr3与ctDNA结合的影响主要取决于金属离子与DNA的碱基和磷酸基团间结合的相对亲和比。

The organoboron compounds in this paper are based on triarylboranes, boronic acids and boronic esters. The structure-property relationship and sensing mechanism are elucidated. Organoboron compounds as Lewis acid can be used as fluoride probe with high sensitivity and selectivity because they have a unique LUMO in which the π-conjugation is divergently extended through the vacant p-orbital of the boron atom. The complexation of the boron π-electron systems with fluoride ion would interrupt the π-conjugation extended through the boron atom, causing the change of photophysical properties.

介绍了基于三芳基硼化合物、硼酸和硼酸酯的有机硼化合物在氟离子检测中的应用，评述了这些化合物的结构和检测性能之间的关系，讨论了检测机理，即有机硼化合物中硼原子空的p轨道使其作为路易斯酸能够选择性地结合氟离子，硼原子与氟离子的结合破坏了硼中心与芳香取代基的p-π共轭，引起有机硼化合物光物理性质的变化，从而实现对氟离子的高选择性检测。

Studies of the binding of metal to calmodulin and the subsequent binding of metal-calmodulin complexes to the target protein/peptide revealed that the La-content calmodulin complexes to its target exhibit similar affinity with the Ca-calmodulin complexes.However, there were substle differences in protein conformation as well as the kinetical properties between the two kinds of metal-calmodulin complexes, suggesting Ln could produce cellular effects via the Ca/calmodulin signaling systems.

稀土离子和钙调蛋白的结合以及后续和靶酶的结合，在热力学上与钙离子激活蛋白具有相同的亲合力，但在动力学性质上以及细微构象上明显不同，显示稀土离子可通过细胞钙相关信号系统产生特别的生物效应。

It was found that La〓 does not affect the binding affinity between calmodulin and Polistes Mastoparan, a known calmodulin binding peptide, neither the conformation of the ternary complex. Excessive amount of La〓 result in the decrease of the binding constant and the disrupted conformation. The binding affinity of La〓 to calmodulin increased in the ternary complex (La〓-CaM-Mas/Mas X), which suggested the coordination between the two global domains. The binding priority between the two global domains is also changed: La〓 more is likely to bind to the C-terminal of calmodulin than to N-terminal, thus facilitates the binding of Mas/Mas X to the C-terminal of calmodulin as the first step of the Mas/Mas X binding.

在以钙调蛋白结合肽—Polistes Mastoparan和Mastoparan X为对象的研究中，我们发现，除非过量，否则La〓的存在不影响钙调蛋白与Mas间的结合常数以及构象；过量的La〓（La〓/CaM摩尔比＞4）将引起钙调蛋白结合功能的下降，同时明显改变金属-钙调蛋白-Mas三元复合物的构象；La〓对Ca〓CaM-Mas的N末端表现高度选择性，显示了在三元复合物中两种离子间的协同效应；在三元体系中，La〓与钙调蛋白的亲和力明显上升，而且亲和力上升的程度因钙调蛋白结合肽的不同而有明显差异，显示了作用的选择性；Mas和MasX的存在改变了La〓在钙调蛋白上的结合顺序，La〓很可能优先与C末端结合，从而使Mas/Mas X首先与C末端结合，该顺序与钙离子相同；La〓的参与使三元复合物在动力学上更加稳定。

Together with the salt solution concentration in the room into H + ions and OH - for water.

与溶液中的盐一起进入浓缩室中的H+和OH-离子结合为水。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。