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The mechanism,thermodynamics and kinetics of ion-exchange reactions between alkali,alkaline-earth and transition metal ions and zirconium phosphate and its derivatives ar...

本文综述了碱金属、碱土金属、过渡金属离子等与磷酸锆及其衍生物的离子交换反应机理、热力学和动力学特性,另外也讨论了发光金属配合物与磷酸锆的离子交换反应研究进展。

The mechanism, thermodynamics and kinetics of ion-exchange reactions between alkali, alkaline-earth and transition metal ions and zirconium phosphate and its derivatives are reviewed, progress in ion-exchange reaction between luminescent metal complex and zirconium phosphate is also discussed.

本文综述了碱金属、碱土金属、过渡金属离子等与磷酸锆及其衍生物的离子交换反应机理、热力学和动力学特性,另外也讨论了发光金属配合物与磷酸锆的离子交换反应研究进展。

A new cataphoresis He-Ca+ laser was designed and made, and the stable output power of a hundred mW at 373.7nm recombination laser was obtained for a long operation time.

本文结合国家自然科学基金项目的研究内容,对高重复率脉冲放电钙离子激光动力学机制、工作特性和电泳效应进行了深入研究,设计制作了新型电泳式He-Ca+激光器,获得了百毫瓦功率钙离子373nm复合激光的稳定输出,为解决传统钙离子复合激光存在寿命短和放电不稳定等缺点提供了新途径。

The effects of temperature, pH, ionic strength and ionic variety on the nitrogen solubility of chickpea protein isolate were investigated, and those of pH and ionic strength on emulsifying capacity and emulsion stability were also studied.

研究各种外部条件如温度、pH、离子强度、离子种类对鹰嘴豆分离蛋白质溶解性的影响以及pH、离子强度对乳化能力及乳化稳定性的影响。

This study has hypothesized that high concentration of nitrate, acetic and chorine ions in the scrubbing water lowers the water vapor pressure which in turn reduces the relative humidity of the scrubber outlet from 90~100% to below 80%. As a result, nitric acid can't absorb water to grow into visible white smoke particles.

本研究推论白烟消失的原因是因为含有高浓度硝酸根离子、醋酸根离子及氯离子之洗涤水蒸气压变低,使得洗涤塔出口的相对湿度由90~100%降低至80%以下,因而使得硝酸无法反应及成长成可见之白烟微粒。

In this review, we describe nuclear magnetic resonance techniques which are widely used to investigate inter-molecular interactions between proteins and diamagnetic/paramagnetic metal ions.

本文简要介绍目前国际上用NMR方法研究抗磁金属离子和顺磁金属离子与蛋白质相互作用的进展,并具体介绍了NMR方法在钙调蛋白、锌指蛋白、朊病毒蛋白等金属离子蛋白研究上的应用。

The nickelous chloride both may use in to galvanize, and is prepares the galvanization chemical thionamic acid nickel the important raw material, lead is affects the electronickelling quality a important attribute, in the present industry 331 ion exchange resin deleading effect still could not arrive in the electronickelling the lead content standard, used pocket weak basicity resin XSC312 after the screening experiment determination to take from the nickelous chloride solution intermediate ion exchange except the micro lead resin, inspected the material fluid pH value, the contact duration in the ionic exchange column to the ionic exchange adsorption lead influence, has determined the resin adsorption capacity and inspected the resin analysis performance.

氯化镍既可用于电镀,又是制备电镀化学品氨基磺酸镍的重要原料,其中的铅是影响电镀镍质量的一个重要因素,现行工业中的331离子交换树脂除铅效果尚不能到电镀镍中铅含量标准,经过筛选试验确定采用大孔弱碱性树脂XSC312作为从氯化镍溶液中离子交换除微量铅树脂,在离子交换柱中考察了料液pH值、接触时间对离子交换吸附铅的影响,测出了树脂的吸附容量并考察了树脂的解析性能。

Considerable attention has really been focused on ionic liquids as "green" alternatives to classical environmentally damaging organic solvents in many fields such as in organosynthesis, material, catalysis, electrochemistry, biochemistry, physicochemistry, separation and so on. However, there have been only a few examples of chiral ILs have been reported so far, and ILs possessing chirality are having been synthesized aimed at application in asymmetric catalytic reaction.

离子液体在许多领域如电化学、有机合成、催化、生物化学、物理化学、材料及分离等的绿色替代溶剂技术引起了人们的重视,然而,有关手性离子液体的合成与应用的报道比较少,含有手性片段的离子液体不断被合成出来并期望在不对称催化反应中得到应用,但是成功的例子不多,使用手性离子液体在不对称催化反应中还在初始的探索阶段。

The ion concentrations were studied in both four snow pits on Hami Miaoergou FlatTopped Glacier and one snow pit on Haxilegen Glacier No.51 of Kuitun river in eastern Tianshan Mountain, and both snow pits were retrieved in 2004. The results show that the Ca2+, NO-3 and SO2-4, particularly Ca2+, are major ions in the snow of snow pits in both ablation and accumulation area and also in the ice of snow pits in accumulation area on Hami Miaoergou FlatTopped Glacier, where the relationships among major cation concentrations in snow of snow pits can be revealed by ion concentrations in the ice of snow pits, but the correlation between ion concentrations in the snow of snow pits and elevation is not obvious, which probably can be attributed to the narrow span of elevation and sparse snow pits on glacier. However, the good correlation between ion concentrations in the ice of snow pits and elevation indicates that the elution process weakened gradually with the elevation rise and temperature decrease.

对2004年获取的天山奎屯河哈希勒根51号冰川1个雪坑和哈密庙尔沟平顶冰川4个雪坑的离子浓度特征进行了研究,结果表明:Ca2+、NO-3和SO42-是哈密庙尔沟平顶冰川雪坑雪层和积累区雪坑底部冰中的主要离子(尤其是Ca2+),其雪层中的主要阳离子关系可在底部冰中得以较好的反映,但雪层中各离子浓度与海拔的相关性不明显,可能与海拔的跨度较小和挖取的雪坑较疏有关;雪坑底部冰中的离子浓度与海拔间明显的相关性说明淋融作用随着海拔升高、气温降低而逐渐减弱。

In the second part of this thesis, the physical model, which used to describe the evolution of highly charged ions in the EBIT and provided by Penetrate, are discussed in detail. Based on this model, we have some modifications. The modified physical model takes the effect of the geometry of drift tube, the cumulation of space charge, and ionization heating into account.

在论文第二部分,我们详细讨论了Penetrate所提出的用来描述高价态离子在电子束离子阱中演化的物理模型,并在Penetrate所提出的物理模型基础上做了部分修正,修正后的物理模型考虑了漂移管的几何位形、电离加热以及电子束的空间电荷累积的影直流电弧等离子体发生器的数值模拟及电子束离子阱物理研究响,利用修正后的物理模型,对高价态离子在EBI下中演化过程进行详细地数值模拟。

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