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The glutamine synthetase produced by the engineering bacteria can specially act on NH4 and aminoglutaric acid, the durability to the high concentration ammonium ion has been distinctively improved because of the dissolution of adenosine acylation modification, the major bottleneck of glutamine with enzymatical production has been solved, and the concentration of the obtained glutamine can reach 47.6g/L.

本发明工程菌产的谷氨酰胺合成酶可专一性的作用于NH 4 和谷氨酸,且因解除了腺苷酰化修饰作用对高浓度铵离子的耐受能力显著提高,解决了酶法生产谷氨酰胺的重要瓶颈,生成的谷氨酰胺的浓度最高达到47.6g/L。

Fe-ion doped TiO2 was immobilized on solid support stubstrates-SiOa using sol-gel method. The photocatalytic efficiency of the TiO2 coating was compared with nanosize powders using the degradation of benzophenol in a aqueous solution as a standard test system, the photocatalytic efficiency was found to markedly increase.

采用溶胶凝胶法制备了硅胶附载的掺杂不同量铁离子的二氧化钛薄膜,用XRD,Raman,SEM的手段进行了表征,证明该条件下制备的二氧化钛为锐钛矿相,薄膜在硅胶表面的成膜效果较好,但有一定程度的龟裂,通过光催化实验发现催化效率与纳米粉相比有明显的提高。

The total amount of Mg and Fe ions in the equilibrium solution depends on the solubility of resulting double salts. The reaction speed is decided by the speeds of ionization of ammonia salts and brucite together.

平衡溶液中镁、铁离子的总量取决于生成复盐的溶解度,反应的速度是由铵盐电离的速度和水镁石电离的速度共同决定的。

The results show that isobutene oligomerization is fast liquid-solid reaction. Under the temperature of 80 ℃~120 ℃ and pressure of 2.0 MPa, the products of oligomerization are mainly dimers and trimers of isobutene. The yield of trimers is higher than that of dimers and the mass fraction of trimers decreases with reaction temperature increasing. The yield of tetramers is much lower than that of dimmers and trimers. The tetramers are formed by reaction of isooctenes and C8 carbonium ion.

结果表明,异丁烯齐聚反应为快速液固相催化反应,在80 ℃~120 ℃,2.0 MPa的实验条件下,反应产物主要是异丁烯的二聚物和三聚物,且三聚物的收率远高于二聚物,两者的浓度比值随反应温度的升高而下降;少量四聚物的生成主要源于碳八烯烃与碳八正碳离子的反应。

Reaction trends of catalytic desulfurization of thiophene were determined based on the reaction energy needed, which was obtained with the AM1 calculation results of thiophene and possible carbonium ions on transition state.

采用半经验AM1计算方法,利用静态理论对噻吩在分子筛催化剂上的催化裂化脱硫机理进行了量子化学计算研究,通过对噻吩分子和可能产生的中间正碳离子的量子化学计算,得到各中间反应所需的能量,从而判断噻吩催化裂化脱硫反应的趋势,证实了氢转移反应在催化裂化脱硫中所起的作用。

Experiment showed that the hydrolysis product of chloroisopentene in sodium hydroxide solution was mixture of isopentenol and methyl butenol , which indicated that displacement reaction of chloroisopentene was accompanied by isomerization reaction of carbonium ion.

在以氢氧化钠水溶液进行氯代异戊烯水解时发现,水解产物为异戊烯醇和甲基丁烯醇的混合物,这说明氯代异戊烯在进行取代反应的同时,伴有正碳离子的异构化反应,由此开发了一条全新的由氯代异戊烯生产甲基丁烯醇和异戊烯醇的新的工艺路线。

It may imply that there are close relation between the enhancement of electric field in nearby particles and dipolar interaction.

基底上正电荷所诱导的金属纳米粒子的偶极的形成减弱了从金属纳米粒子到PATP分子的电荷转移,碘离子的共吸附使得金属纳米粒子表面的电荷重新分布。

GABA is resitent to the toxicity of the excitory amino acids because it can promote the conduct of Cl-, prevent the depolarization of the postsynaptic inhibition effectively and the open of Ca2+-gated channel, reduce the metabolic rate of the ischemic nurons.

GABA可以拮抗兴奋性氨基酸的毒性作用,它主要通过促进氯离子的传导,有效的阻断突触后去极化及电压依赖性Ca2+通道的开放,降低正常灌注/缺血性神经元的代谢率和氧的消耗,从而使神经元易耐受缺血性损伤[9]。

Based on the deterioration mechanism of corrosive medium, a lot of polymer such as ternary-polymer, adding-felt addition, hydrophobe and polypropylene fiber were added to enhance the performance of anti-corrosion, anti-penetration, conglutination and anti-cracking of original cementious material. The microstrure of cementious material was changed from the simplex hydration product of cement to the superposition structure of the hydrolysate of polymer and the hydration product of cement. A lot of the corrosive ions were prevented from the interior of concrete by this stable structure. The results of tryout indicated that the mending material has the good effect at the corrosion form of corrosive medium.

根据介质腐蚀形式的劣化机理,该文以提高修补材料耐腐蚀性能、抗渗透性能、粘结性能和抗裂性能为出发点,采用添加有机硅改性三元共聚物、增粘剂、孔隙憎水剂等多种聚合物和聚丙烯纤维对原水泥基材料进行改性,使得修补材料的内部微观结构从单纯的水泥水化产物转变成聚合物和水泥水化产物叠合的空间网状结构,这种稳定的结构能有效抵抗各种介质离子的侵蚀,在实际工程上的试用也显示出新修补材料良好的使用效果。

At first it may seem rather strange to treat the chemistry of the halogens and the noble gases,two groups that represent the extremes of chemical activity and inertia ,in the same section .the superficial differences between the halogens and the noble gases are much reduced,however if we focus our attention on the comparison of halide ions(particularly F-) with the isoelectronic noble gas atoms and the noble gas compounds with halogen atoms or the halogens in their higher positive-oxdation states.

起初它可能看起来很奇怪对待的卤素化学和惰性气体,两个团体代表在同一节的化学活性和惯性的极端。与卤素和惰性气体的表面差异大大减少,但是,如果我们着眼于(特别是架F -等电子与惰性气体原子和原子与卤素或在卤素稀有气体化合物)卤离子的比较,我们的注意力较高的正- oxdation国家。

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