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As a novel inner surface processing method, grid enhanced plasma source ion implantation method can realize uniform inner surface ion implantation of a metal tube and metal binary compound can be produced.

栅极增强等离子体源离子注入一种新的金属管件内壁处理方法,该方法能够均匀地对金属管件内壁进行离子注入,并且能够生成二元金属化合物。

Chlorophenol and 4-chlorophenol can be transformed to phenol and chloride ion and 2, 4-dichlorophenol to phenol, chloride ion and a small amount of 2-chlorophenol and 4-chlorophenol.

2-氯酚和4-氯酚被还原脱氯生成苯酚和氯离子,2,4-二氯酚被还原脱氯生成苯酚、少量的2-氯酚和4-氯酚以及氯离子。

Indices~ mP 0 and 1 were fitted, respectively, with the heat of formation,ionic hydration energy, lattice energy ,internuclear distance bond lengthof 20 kinds of alkali halides; with the lattice energy of 20 kinds of alkali-earth metal halides,with the ionic hydration heat of 51 kinds of metals, and with the ionic standard heat of formation of 80 kinds of i.

用mP的0和1阶指数分别与20种碱金属卤化物的生成焓ΔfH m、离子水化能ΔhG m、晶格能U1、气态碱金属卤化物核间距R0,20种碱土金属卤化物的晶格能U2,51种金属离子水合焓ΔhH m关联,拟合的回归方程的相关系数为m和80种离子标准生成焓ΔfH 0.9753(0.9834)、0.9761(0.9816)、0.9964(0.9986)、0.9967(0.9967)、0.9789(0.9890)、0.9901和0.9805,满足优级或良级标准。

In the aluminum solution ,the trivalence aluminum ion combi...

另一方面,在这种铝盐溶液中,三价铝离子是以铝水配合物的形态存在,配位水发生水解生成羟基配离子,其通过羟基桥联结,放出水分子,并逐级由单体配合成双核、三核以致形成多核羟基配合物。

In the aluminum solution ,the trivalence aluminum ion combines with water to form the coordination compound and then the coordination waters hydrolyze into hydroxide ions. The hydroxide ions can join up each other by the hydroxide ion bridges so that the double cores, three cores and multiple cores coordination compounds are formed.

另一方面,在这种铝盐溶液中,三价铝离子是以铝水配合物的形态存在,配位水发生水解生成羟基配离子,其通过羟基桥联结,放出水分子,并逐级由单体配合成双核、三核以致形成多核羟基配合物。

The reason may be that complex formed by rhodium and halide was difficult to produce the catalytic active species. Therefore halide ion was the poison for the rhodium catalyst in hydroformylation of olefins in ionic liquid. The effect of double long chain cationic surfactant (DCMAB, dicetyl dimethylammonium bromide) on selective hydrogenation of cinnmaldehyde catalyzed with RuCl3·x H2O/TPPTS was studied.

进一步的研究表明在使用有良好反应活性的两种催化剂HRh3 、Rh_2进行催化反应时,向体系中加入含有卤离子的化合物时将使反应活性大大降低,而且随着卤化物加入量的增加,催化剂的活性迅速下降,这是卤离子可能和金属铑作用使它难于生成催化活性物种,进一步证明卤素离子是引起催化剂活性下降的极其重要的因素。

Hydrothermal reactions makes water a Bronsted base-acid and act as an effective catalyst and the metal ions represent Lewis base character. The conversion process occurs in a very complex network of parallel, consecutive and equilibrium reactions, and the last step being the catalyzed Cannizzaro-type reaction of pyruvaldehyde to lactic acid.

nsted酸碱并具有一定的催化作用,金属离子在水热催化降解丙酮醛生成乳酸中表现出Lewis碱的特性,能与丙酮醛生成金属复合物,最终生成乳酸,此反应过程符合Cannizzaro反应特性。

The results showed that the MS2 fragmentation pathways of DASSSB were affected by the character and position of substitutes on salicylidene phenyl. The C=N cleaving to form fragmentation ion [M+H-283](superscript +) was dominant for DASSSB compounds with electron-donating group on the C4 of the salicylidene phenyl; while fragmentation ion [M+H-254] (superscript +) forming by C-C cleavage of the β-position of C=N was dominant for DASSSB compounds with electron-withdrawing group on the C5 of the salicylidene phenyl.

结果显示,这些化合物的ESI-MS/MS裂解方式与它们分子中水杨醛苯环上取代基的性质和位置有关:当水杨醛苯环上4位连接供电子取代基时,分子以CN双键断裂为主,生成[M+H-283]碎片离子;当水杨醛苯环上5位连接吸电子取代基时,分子以CN双键β位的C-C键发生断裂为主,生成[M+H-254]碎片离子。

The pH stability of enzyme was 8 and the temperature stability of enzyme was 30℃. Bap-degrading enzyme catalyzed the oxidation of veratryl alcohol to veratraldehyde without H2O2 and the oxidation of Mn2+ by H2O2 to Mn3+.

酵素在将veratryl alcohol氧化生成veratraldehyde时是不需要H2O2协助催化,然而在对Mn2+离子氧化生成Mn3+离子时若有H2O2协助催化下可以加快酵素催化的速度。

A large releases of kinetic energy for channel CH3CS++ H of least energy might result from a dissociation mechanism according to which c-C2H4S+ isomerizes to a local minimum CH3CSH+ and then dissociates through a transition state to form CH3CS++ H. On the other hand, a predicted dissociation energy 11.05 eV for c-C2H4S ?

实验中观察到环硫乙烯离子解离成CH3CS++ H的解离通道释放出大量的平均动能,并采用G3计算预测环硫乙烯离子的解离通道,推测环硫乙烯离子异构化至次稳定态CH3CSH+结构,再经过渡态结构,断裂S-H键生成C2H3S+和H,同时释放出大量的动能。

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