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The peroxy bond of dihydroartemisininis essential for it\'s antimalarial and antitumor activity. In order to understand the mechanism of antimalarial and antitumor, electrochemical method were used to study the interaction between DHA with Cu ion and Bi ion.

双氢青蒿素中的过氧键是抗疟、抗肿瘤的关键活性部位,为了探讨金属离子对DHA中过氧键的影响,本文采用电化学方法研究了Cu、Bi对DHA的作用,并探讨了其作用机理。

The ultrasonic-assisted solvent extraction and quantitative analysis of the oxine-copper residues in soil with ion pair of antiphase HPLC was established. This methods mainly uses XBridge C5 column and UV detector by using waters phase of phosphatic buffered solution/acetonitrile (60:40, by vol) as mobile phase with 0.8 mL/min flow ratio and UV detection at 245 nm. The residue time was 4.72 minute. The linear correlation of this method was 0.9987. The recovery rate was 76.2 to 108.7%. Comparatively standard deviation was 0.6 to 3.37%. The detection limits of method was 0.05 mg/kg.

建立了土壤中喹啉铜的超声波辅助溶剂提取-反相离子对高效液相色谱法的残留分析方法,该方法使用XBridge C18色谱柱和可变波长紫外检测器,并以水相磷酸盐缓冲体系-乙腈(体积比60:40)作流动相;流速为0.8mL/min;检测波长为245nm;保留时间为4.72min;线性相关系数为0.9987,回收率在76.2%~108.7%之间,相对标准偏差在0.6%~3.37%之间,对土壤的最低检出限为0.05mg/kg。

In addition, the ability of the copolymer to detect different metal cations in aqueous solution was investigated.

研究了常见金属离子对聚合物荧光强度的影响,其中以Fe~(3+)对聚合物的荧光淬灭程度最大。

The analysis of the experimental data indicates that membrane lipids play a leading role in the interaction of divalent metal ions with membrane lipids.

对实验数据的分析表明,在二价金属离子对膜脂的影响中,膜脂起了主导作用。

OBJECTIVE To determine the stability of PCS by means of ion-pair chromatography.

目的 :用离子对色谱法对磷酸肌酸钠的稳定性进行测定。

An ion-pair chromatographic method for the determination of Cr has been developed using a silica-based monolithic column and a conductivity detector.

研究了基于硅胶整体柱的离子对色谱快速测定Cr的方法,讨论了淋洗液浓度、乙腈浓度、流速、温度和pH等因素对分离的影响。

A series of long chain alkyl methylnaphthalene sulfonates, including hexyl methylnaphthalene sulfonate, octyl methylnaphthalene sulfonate, decyl methylnaphthalene sulfonate, dodecyl methylnaphthalene sulfonate, and tetradecyl methylnaphthalene sulfonate, was characterized by high performance liquid chromatography and electrospray ionization mass spectrometry. Through a great deal of testing, the analytical conditions were optimized.

采用反相离子对高效液相色谱和电喷雾离子化质谱对系列长链烷基甲基萘磺酸盐,包括己基甲基萘磺酸盐、辛基甲基萘磺酸盐、癸基甲基萘磺酸盐、十二烷基甲基萘磺酸盐、十四烷基甲基萘磺酸盐进行分析,通过液相色谱分离条件的优化,找到了最佳分析条件。

This paper proposes a method for the determination of 4-hydroxy-3-nitro-benzenearsonic acid and arsanilic acid in the nitration reaction product of arsanilic acid by ion-pair chromatography.

本文提出一种用于测定对氨基苯胂酸硝化反应产物中4-羟基-3-硝基苯胂酸及对氨基苯胂酸含量的离子对色谱法,选择甲醇:水=25:75作为流动相,0。

By imitating different concentration of Cd2+ Cu2+ Cr3+ Cr6+and Zn2+polluted water environment,we mainly studied their toxic effects on aquatic piants by means of measurement of physiologicai indexes and electron microscopy observation as well as the relieving to Cu2+ injury of antioxidase enzyme system in Lemna minor L. and Vallisneria asiatica Miki in this paper by throwing Ce.the experimental results showed that Cd2+ Cu2+ Cr3+ Cr6+ and Zn2+ might injure photosynthetic systems, protective enzyme system, substance metabolism systems and cell ultrastructure of the plant.

本文通过模拟不同浓度梯度的重金属Cd~(2+)、Cu~(2+)、Cr~(3+)、Cr~(6+)和Zn~(2+)污染环境,利用生理生化测定、扫描电镜、透射电镜、气相色谱及激光共聚焦等实验手段,研究了四种金属离子对不同生态型的水生植物的毒害影响,初步探索了Ce对浮萍Cu害的缓解效应和La、Zn及其交互作用对浮萍活性氧清除系统影响。

The dechlorination of the chlorinated hydrocarbon by electrolytic iron is based on the laws of redox reactions,the adsorption of the pollutants by tiny granular activated carbon among the iron filings ,the catalytic process of the tiny granular carbon,the destruction of the oxidational membrane on the iron surface by the active chloride ion and the effect of the tiny electric fields.

简述了氯代烃的主要物理性质和用途,认为铁屑腐蚀电池处理氯代烃污水是基于氧化还原反应、铁屑中活性炭微粒对氯代烃的吸附与对反应的催化、氯离子对氧化膜的破坏和微电池的电场效应等原理;简要总结了迄今利用铁屑去除氯代烃的室内实验和利用原位铁屑反应墙处理地下水中的氯代烃污染研究所取得的成果,认为这种反应墙是一种效果好、成本低、维护方便、有望投入商业运行的最佳方法,并指出了其存在的问

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