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The energy of excited state depended on the nature of different cations. 3. 4-(4-tolyl)-6-phenyl-2, 2'-bipyridine platinum acetylide complex containing a monoazazcrown moiety in the acetylide ligand could signal Mg〓 specifically and displayed large changes both in color and in luminescence intensity upon complexation with Mg〓. The most striking result was that it could signal Mg〓 specifically even in the presence of alkali and alkaline earth metal ions in high concentrations.

对位带有氮杂-15-冠-5冠醚的苯乙炔为辅助配体的4-(4-甲基苯基)-6-苯基-2,2'-联吡啶Pt络合物AC,不仅在碱金属和碱土金属的存在下吸收光谱明显改变,更有意义的是,它只有在Mg〓离子存在时能够发光,因此可以通过发射光谱选择性的识别Mg〓,尤其可以在高浓度的其它金属离子存在下选择性的检出Mg〓离子。

The effect of the initial concentration and the addition order of arsenate and chromate on their uptake by hydroxy-Fe-montmorillonite complex was investigated.

在模拟氧化及酸性土壤条件下,用制备的低聚合羟基铁-蒙脱石复合体进行了砷酸根、铬酸根离子的竞争吸附实验,研究了砷酸根离子和铬酸根离子不同用量及不同添加顺序对竞争吸附的影响,并与蒙脱石和含水氧化铁进行了对比。

Simplier and more efficient ion extraction methods for atomic vapor laser isotope separation AVLIS were evaluated using a 2-D electron-equilibrium model to compute and compare three electrostatic methods the parallel electrode method, the Π type electrode method, and the improved M type electrode method.

为探索用于原子蒸气激光同位素分离AVLIS的简单有效的离子引出方法,用二维流体理论电子平衡模型计算比较了3种静电场方法平行板电场法,Π型电极法,改进M型电极法计算发现,二维流体理论电子平衡模型并不能很好地描述Π型电极法对另外两种静电场方法,计算了不同外加电压、不同的初始原子密度和不同的目标同位素丰度等条件下的离子引出情况从计算结果可以看出,改进M型电极法不论是从离子引出时间还是从碰撞损失率,都要比平行板电极法好得多当外加电压较高或初始原子密度较高时,这种好处就更加明显因此,改进M型电极法是一种可供实际采用的比较好的静电场方法

Benzoin condensation using imidazolium based ionic liquids as solvent for the first time has been successfully achieved. The reaction conditions have been studied in detail. When under 65 and with 0.5 equiv. NaOH in ionic liquid l-butyl-3-methyl-imidazolium tetraborate, benzoin was obtained in excellent yield of 91%. Recycling of ionic liquid has been available.

首次探索并成功实现了在咪唑鎓盐离子液体中进行苯偶姻缩合反应,详细探讨了反应条件,当反应在65℃下和0.5当量NaOH存在下以及在离子液体4-丁基-1-甲基咪唑鎓四氟硼酸盐中进行时,苯偶姻产率可达91%;并对离子液体进行了有效回收再利用。

A new cataphoresis He-Ca+ laser was designed and made, and the stable output power of a hundred mW at 373.7nm recombination laser was obtained for a long operation time.

本文结合国家自然科学基金项目的研究内容,对高重复率脉冲放电钙离子激光动力学机制、工作特性和电泳效应进行了深入研究,设计制作了新型电泳式He-Ca+激光器,获得了百毫瓦功率钙离子373nm复合激光的稳定输出,为解决传统钙离子复合激光存在寿命短和放电不稳定等缺点提供了新途径。

With abroad congener technology photograph is compared, the compound function colophony of new research and development is measured to the adsorption of organic matter in liquid waste of printing and dyeing raise 1 times above, and fight contaminative ability to increase greatly.

与国外同类技术相比,新研发的复合功能树脂一般也称离子交换树脂(用化学法将高分子共聚物制成的有机单体颗粒的离子交换剂对印染废水中有机物的吸附(物质表面吸住周围介质中的分子或离子现象)量提高1倍以上,且抗污染能力大大增强。

For salt lake brines, ED exhibits very low efficiencies for removal of trace divalent ions or extraction of trace univalent ions.

对盐湖卤水的分离而言,ED对卤水中痕量的二价离子的脱除效率很低,对卤水中痕量的一价离子的提取效率也很低。

Mass spectrometry results revealed that the pair of eluents respresented a pair of ternary copper complexes with mixed ligands, providing the first experimental evidence. These complexes are diastereoisomer in nature. The optimized configuration of the diastereoisomer was predicted by theoretical calculation.

质谱实验结果表明,拆分组分是一对铜混合配体复合物离子,其中的一个配体是提供手性环境的流动相添加物,另一配体是待拆分物质的某一构型对映体,这对铜混合配体复合物离子本质上属于非对映异构体。

The adsorption of NH〓 in the 〓CO〓 solution and the adsorption of NH〓-N in the waste water from the Coking plant,Capital Iron and Steel Coripo ration by bentonite were investigated. The results show that the amount of 〓 adsorbed by particulate betonite (〓1. 68mm) and -200 mesh bentonite are 26. 39 and 8. 87mg/g, respectively; and the amount of NH〓-N in the waste water from the coking plant adsoybed by particulate bentonite, acid activated bentonite and -200 mesh bentonite are 32. 00, 21. 85 and 15. 62mg/g, respectively.

对膨润土吸附溶液中的 NH〓离子和从首钢公司焦化厂焦化废水中去除氨氮进行的试验研究结果表明,该膨润土对碳酸铵溶液中 HN〓离子的饱和吸附量是颗粒膨润土26.39mg/g、粉状膨润土8.87mg/g;对焦化废水中氨氮的饱和吸附量是颗粒膨润土32.00mg/g、活性膨润土21.85mg/g和粉状膨润土15.62mg/g。

In our research, through derivatization of stable calix[4]pyrroles, active substituting units were jointed on the calixpyrrolic skelecton. After acylamide and free radical transfer reaction, the preparation of new calix[4]pyrrole-bonded stationary phases were fulfilled. the separation abilities of them to inorganic and organic anions and medicines were exploited and new analytical methods were established. The separation mechanisms were discussed. At the same time, through using calix[4]pyrroles as additives in CZE to influence the electrophoresis of inorganic anions, the recognition mechanisms and influencing factors in supramolecular chemistry were also studied.

本项目以新型杯吡咯大环化合物分子识别化学研究为基础,设计合成了含活泼取代基的官能化杯[4]吡咯化合物,通过酰胺化反应和原位自由基链转移反应制备了新型的杯[4]吡咯色谱固定相,系统研究了具有阴离子识别功能的杯[4]吡咯大环化合物作为离子色谱的分离介质对无机、有机离子型化合物和药物分子的色谱分离性能,建立了新的分析方法,对分离机理进行了探索和验证;同时将杯[4]吡咯化合物用作毛细管电泳流动相添加剂,利用其对无机阴离子电泳行为的影响探讨超分子化学中分子识别的机理和影响因素。

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Lugalbanda was a god and shepherd king of Uruk where he was worshipped for over a thousand years.

Lugalbanda 是神和被崇拜了一千年多 Uruk古埃及喜克索王朝国王。

I am coming just now,' and went on perfuming himself with Hunut, then he came and sat.

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