离子对

From the angle of engineering application, this article analysed the corrosion characteristics and damage causes of the current structural used concrete in the region of Hangzhou gulf, on the basis of on-site survey of all the Marine concrete projects in that area. Taking HPC used in Marine as research objective, this article put great emphasis on the influence of the composition cementing material system to concrete performance, and make a preliminary probe into the action mechanism of the composite effects of various mineral materials in improving the performance of concrete by laser measuring size machine and EMPA. Through experiments, the article discussed how chloride ingression in concrete will be effected by such factors as exposure time, chloride binding, environment temperature, stress and cracks conditions; and also analysed the symptoms of these factors in the model of concrete service life prediction by conference to all related research reports both home and aboard. On the foundation of abovementioned research, this paper brought up an engineering model of service life prediction of marine concrete, which is based on chloride-induced corrosion.

本文从工程应用的角度，在对杭州湾地区既有海工混凝土工程作实地调研的基础上，研究分析杭州湾地区既有海工混凝土结构的腐蚀特点和破坏原因；以海工高性能混凝土为研究对象，着重研究复合胶凝材料体系对混凝土性能的影响，并应用激光粒度仪、EMPA等分析手段，就复合胶凝材料的作用机理进行初步探讨；试验研究混凝土暴露时间、胶凝材料对氯离子的吸附、环境温度、应力和裂缝状态等因素对混凝土中氯离子迁移运动的影响，并结合国内外相关研究报导，探讨这些因素在混凝土使用寿命预测模型中的表征；在上述研究基础上，提出以氯离子侵蚀为基础的海工混凝土使用寿命预测的工程应用模型。

First of all, this study will be multi-walled carbon nanotubes by chemical oxidation process purified so it can be modified to deal with than the purification of purity before the modified 5 wt%, more than 1.89 times the surface area to increase the surface potential decrease of about 10 ~ 20 mV and the surface functional base (-COOH and-OH) to increase 1.45 times, and then the control technology of electroless preparation parameters include: analysis of plating time, plating analysis of temperature, metal ions in solution than the (Fe2+/ Ni2+), bath pH and the added value of dispersion Agent and other research towards Fe-Ni particles to increase the iron content and Fe-Ni particles spread in the MWCNT upper fixed targets,the results found that when the parameters for the preparation of 50 ℃, pH10, do not add dispersant, metal ions than the solution (Fe2 +/ Ni2 +) 7, the highest iron content can be Fe = 40.55 at%(flat iron content 111.17 mg / g) of nanocomposites Fe-Ni/CNT, then for a series of the nature of its analysis, the final evaluation Fe-Ni/CNT nanocomposites were processed on the effectiveness of the application of mixed pollutants, the results showed that in 120 minutes at the same time when Adsorption of heavy metal ions lead nitrate 10 ppm, selenium heavy metal ion degradation of 1 ppm and orange azo dye AO7 50 ppm standard of effluents, and after a total Fe-Ni nano-particles to SEM / EDS analysis of more than 50% still remaining.

本研究首先将多壁奈米碳管以化学氧化法做纯化改质处理能使其纯度较纯化改质前提高5 wt％、比表面积提高1.89倍、表面电位下降约10~20 mV以及表面官能基提高1.45倍，再控制无电镀技术之制备参数包括：析镀时间、析镀温度，镀液中金属离子比(Fe2+/Ni2+)、镀液pH值及是否添加分散剂等，研究朝提高Fe-Ni粒子的含铁量与Fe-Ni粒子散布固定在MWCNT上等目标进行，研究结果发现当制备参数为50 ℃、pH10、不添加分散剂、镀液金属离子比(Fe2+/Ni2+)7时，可得到最高铁含量Fe = 40.55 at％(单位铁含量111.17 mg/g)之奈米复合材料Fe-Ni/CNT，接著对其作一系列性质分析，最后评估奈米复合材料Fe-Ni/CNT对共处理混合污染物之应用效益，结果显示其在120分钟时能够同时吸附重金属硝酸铅离子10 ppm、重金属硒酸根离子1 ppm及降解偶氮橘色染料AO7 50 ppm达放流水标准，且共处理后奈米Fe-Ni粒子以SEM/EDS分析仍剩余50 %以上。

Result showed that tetrasubstituted calix [4] arenes in lower rim were stronger complex abilities than bisubstituted calix [4] arene with transition metal, heavy metal and rare earth ions. But when introducing the aminephenolicalcohols in the 1, 3-bisubstituted calix [4] arenes, the complex abilities were improved.

结果表明：在Lower rim上四取代的杯[4]芳烃配体比1，3-二取代的杯[4]芳烃配体对过渡金属离子，重金属离子及稀土离子有更好的配位能力，但当1，3-二取代的取代基上引入醇胺链型配体时，对金属离子也有很好的配位能力。

By means of UV-vis spectrophotometer, the complex abilities of calix [4] arene ligands with metal ions were researched, and the effect of solvent systems was discussed.

使用紫外-可见分光光度法研究了杯[4]芳烃配体与金属离子的络合性质，并考虑了溶剂对配体与金属离子配位的影响，评价了杯[4]芳烃的不同取代基对过渡金属离子及稀土离子的配位作用。

X6 3?,large specific surface area and adsorbent capacity However,most molecules and hydrated ions can not enter the aperture pass because of their size over the aperture diameter of palygorslote except less simple ones Furthermore,Palygorskite adsorbs water molecule choosingly In most cases the absorbing of palygorskite is by its outside surface that works in the form of colloid and ion exchange other than i...

但是由于凹凸棒石孔道直径小于大多数分子及水合离子的直径，除少数简单分子和离子外，多数分子和离子都不能进入凹凸棒石孔道，而且凹凸棒石选择性吸附水分子，因而在多数情况下，凹凸棒石对吸附质的吸附不是内表面吸附，而是外表面吸附。并且外表面吸附是胶体和离子交换吸附。本文阐述了凹凸棒石的孔道直径、吸附选择性、体系pH 值及凹凸棒石和蒙脱石胶体颗粒的互相作用对凹凸棒石吸附性能应用的制约。

Based on the dynamic equation, the transport and acceleration of out-flowing ionospheric ions in the magnetosphere are studied by means of finding the ion distribution function. They include two parts: the study of static ion distribution with analysis and numerical compute; the study of ion acceleration by induced electric feild in the period of dipolarization of taillike geomagnetic lines in the substorm expansion phase with the numerical simulation of the ion distribution function.

本文在磁层中上行离子的加速与传输理论研究领域中，采用动力论方程，用求解离子分布函数的方法来研究问题：(1)用解析求解和数值计算的方法，对上行离子在不同Kp指数条件下磁场位形中的定态分布进行了研究；(2)用数值模拟计算分布函数的方法，对上行离子在亚暴膨胀相磁场向偶极形驰豫过程中受磁尾的感应电场加速进行了研究。

To test the hypothesis, neontal rat cadiomyocytes Treat with heat shock(HS,42℃,2h) to induce the expression of HSP70,then teated with 0.5mmol/L H2O2. We first found H2O2 can reduced cadiomyocytes apoptosis and HSP70 only over-expression in the HS group, other two group only express HSP70 a little in the test of expression of HSP70.Then we tested the concentration of Ca2+, the [Ca2+ ] of CON was 192.224+6.654, the [Ca2+ ] of H2O2 group was 290.6918+8.922and the [Ca2+]of HS group was 214.2633+4.484.To further determine how HSP70 repaired the Ca2+ homestasis, we measured calcium transient of each group.

实验中应用MTT和流式细胞技术检测细胞的凋亡，发现损伤组的存活率明显低于其他2组，热休克组(Heat shock group，HS group)细胞存活率略低于正常组细胞；免疫组化结果表明只有在HS组才检测到阳性反应，即是HSP70的表达，其他2组均为弱阳性结果；应用离子成像技术对细胞内钙离子浓度进行测定，发现损伤组290.6918+8.922明显高于正常组192.224+6.654和HS组214.2633+4.484，HS组细胞内的钙离子浓度略高于正常组；为了进一步探讨HSP70对于ROS引起的心肌凋亡过程中钙离子的调控机制，又对各组的心肌细胞进行了钙瞬变的测定。

79Cm and 3. 78cm from M,, M2 to M3 respectively which cannot reach 1/3 height of the control averagely. The seedlings irradiated by 80 X1015 NYcmgave birth to some flower buds without floral shoots and their seed setting rate was lower than that of control obviously. Some M3 plants irradiated by 60X1015 NVcm2grow into bunches which did not appear in M, and M2. Moreover, some phenotypic variations could be inherited stably in subsequent generations. For instance, the dwarf character in the plants treated with the dose of 80 X1015 was stable in inheritance in consecutive three generations.

再次，对不同剂量的低能N~+处理的拟南芥的M_2代试管苗的叶片外植体愈伤组织的诱导和耐盐性进行了比较和分析，发现经不同剂量的低能离子处理的M_2代试管苗的叶片外植体，离子处理影响其出愈率，高剂量处理会抑制愈伤的诱导，但低剂量离子注入对愈伤组织的增殖有一定的促进作用；愈伤组织的耐盐性也与剂量相关，低剂量的耐盐能力比对照的低，但是高剂量处理反而提高愈伤的耐盐性，这间接表明低能离子引起了拟南芥的生理状态的变化，产生了生理效应。

Harbin Institute of Technology, Harbin 150001, China）Abstract: The modified layers by O2-PBII technology on Ti6Al4V alloy surface were studied using X-ray photoelectron spectroscopy. The negative pulse voltage of 10, 20, 30 kV was applied to the sample, which was mounted on an oil-cooled sample holder. The results show that the thickness of the oxide layer increases with increasing implanted ion energy.

摘 要：采用等离子体基离子注氧技术（O2-PBII）对Ti6Al4V合金进行了表面改性处理，实验过程中改变注入离子能量的工艺参数，负脉冲偏压分别为10、 20、 30 kV，离子注入过程中样品台通油冷却以实现低温注入；用XPS对离子注氧层的深度、成分及化学结构进行了系统的分析。

An evaluation on adsorption removal of chromium, arsenic, and copper from wood preservative CCA by hydrous ferric oxides, associated with effects of humic acid, was studied in this paper. Results showed that removal percentage of single chromium and arsenic by HFO increased with pH of solutions, while that of single copper by HFO decreased.

以木材防腐剂CCA中的重金属离子铬、砷、铜为研究对象，讨论了3种重金属离子在水合铁氧化物上的相互作用机理，评价了该铁氧化物对3种重金属离子的吸附去除效果，并探讨了腐殖酸对铁氧化物去除3种重金属离子的影响。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐