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But the concentration of Li2CO3 remains nearly consistent and a new component, CH3OLi, is found in SEI. It can be concluded from these results that anisole reacts with the reduction product of EC and DEC, RCO3Li, in the first process of Li+ intercalating into the carbon electrode. The obtained CH3OLi is helpful in building up a more effective and stable SEI of the carbon electrode, reducing the cointercalation of solvent molecular. All these contribute to the improvement of the cycle performance of lithium-ion battery.

根据以上分析结果,提出了苯甲醚对锂离子电池循环性能的影响机理:在Li+嵌入石墨电极的初次过程中,苯甲醚和EC、DEC的还原分解产物RCO3Li发生基团交换反应,生成CH3OLi,该产物能有效提高石墨电极表面SEI的稳定性,减少锂离子嵌入石墨过程中引起的溶剂分子共嵌入,从而改善电池的循环性能。

Two approaches are employed to prepare thiocyanuric acid derivatized gold nanoparticles, including the direct reduction of gold ions by potassium bitartrate and NaBH〓 and then through ligand exchange reaction.

用两种不同方法合成了三聚硫氰酸衍生的金纳米粒子,包括由酒石酸氢钾直接还原金离子及NaBH〓还原金离子后经配体交换反应。

The antiferromag-netic interaction between the Fe and Mn ions will be dominated if the amount of Feis increased.

继续加大替代量后(x=0.10),Fe离子和Mn离子之间的反铁磁交换耦合就显得更为突出一些。

All the experiments affirmed that doping copper ions could help in improving absorbent properties and the Cu-doped manganate ion-sieves were applicable absorbent in lithium extraction in brine.

实验证明掺杂铜元素能够有效提高锰酸盐型锂离子筛的交换性能,掺杂铜元素的锰酸盐型锂离子筛是一种有希望能从盐湖卤水中提取锂资源的吸附剂。

Exchanging characters of methylamine including equilibrium and kinetics were studied, which shows similarity with ammonia.

实验表明甲胺的平衡交换量和交换速率都略低于铵离子,交换性质类似,因此对废水脱除氨氮过程无不利影响。

This paper is a generalization and summation of some new progress in marine chemistry in the recent decade. The principal contents consist of seven parts:1. Oceanological survey. The oceanological survey covered the China Seas, the Pacific Ocean and the Antarctic Ocean.2. Interaction of minor elements and suspended matter in seawater and the theory of in-terfacial stepwise ion/coordination partical exchange.3. Effect of organic matters on the liquid-solid interfacial exchange and the rule of left-righ...

本文对近十年来海洋化学的若干新进展作了总结,主要包括下述7方面:(1)海洋调查,包括中国近海、太平洋和南极等;(2)海水中微量元素-固体粒子的相互作用和界面分级离子/配位子交换理论;(3)有机物对液-固界面交换的影响和S-型曲线左右移动规律;(4)海水化学模型发展的三个新趋势;(5)海水中金属的络合容量和金属-天然有机配位体络合物的条件稳定常数;(6)海洋有机化学和海洋生物化学;(7)结论,对海洋化学发展的四个特点作了分析和讨论。

335 Alkalescent ion exchange resin was used in the exchange adsorption of high concentration of copper ion in wastewater from phthalocyanine green production.

采用335弱碱性阴离子交换树脂交换吸附酞菁绿废水中高含量的铜离子。

Keywords amidoxime fiber;anion-exchange fiber;thiocyanate ion;exchange property

偕胺肟纤维;阴离子交换纤维;硫氰酸根离子;交换性能

The Ca2+ salt solution as a new regenerant was presented in this paper. The influences of the calcium salt proportioning, temperature, dosage and flow rate on anion exchange fiber regeneration were studied. High regeneration can be obtained with 0.5 mol/L CaCl2+8 g/L CaO+6.5 °Bx sucrose solution at 70~80 ℃, the dosage of the Ca2+ salt solution was about half of the raw decoloring syrup, the regenerant flow rate should be lower than that of the raw decoloring syrup. It was shown that stable decolorization rate and lower decline in exchange capacity could be achieved with the new regenerant. It performed more effectively than the traditional sodium salt regenerant with less discharge of waste water.

选用二价钙离子蔗糖溶液为再生剂,再生蔗糖脱色后的强碱性阴离子交换纤维,研究了再生液的配比、再生温度、再生液用量、再生液流速等因素对再生效果的影响,结果表明配比为0.5 mol/L CaCl2+8 g/L CaO+6.5 °Bx蔗糖的再生液在70~80℃温度下,再生剂的用量约为脱色糖汁的一半,流速应低于脱色时的流速时,再生效果优于传统的钠盐再生剂的再生效果,重复再生后的纤维脱色率能保持稳定,交换容量下降少,且再生液能回收利用,废水排放量小,是一种环保型再生液。

The Ca(superscript 2+) salt solution as a new regenerant was presented in this paper. The influences of the calcium salt proportioning, temperature, dosage and flow rate on anion exchange fiber regeneration were studied. High regeneration can be obtained with 0.5mol/L CaCl2+8g/L CaO+6.5 °Bx sucrose solution at 70~80℃, the dosage of the Ca(superscript 2+) salt solution was about half of the raw decoloring syrup, the regenerant flow rate should be lower than that of the raw decoloring syrup. It was shown that stable decolorization rate and lower decline in exchange capacity could be achieved with the new regenerant. It performed more effectively than the traditional sodium salt regenerant with less discharge of waste water.

选用二价钙离子蔗糖溶液为再生剂,再生蔗糖脱色后的强碱性阴离子交换纤维,研究了再生液的配比、再生温度、再生液用量、再生液流速等因素对再生效果的影响,结果表明配比为0.5mol/L CaCl2+8g/L CaO+6.5 °Bx蔗糖的再生液在70~80℃温度下,再生剂的用量约为脱色糖汁的一半,流速应低于脱色时的流速时,再生效果优于传统的钠盐再生剂的再生效果,重复再生后的纤维脱色率能保持稳定,交换容量下降少,且再生液能回收利用,废水排放量小,是一种环保型再生液。

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