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离子交换

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The changes of the ion exchange percentage E of the interaction of both in the presence of the glycine have been presented.The results are that the effects of the transform sand and untransform sand on the adsorption are different,which agree with the reality and the theory inferrer.

结果表明:当沉积物分别为转化沙和未转化沙时,其对重金属的吸附作用的影响是不同的,且实验结果与理论推测和实际是一致的;甘氨酸的存在对不同金属离子分别与转化沙和未转化沙相互作用的离子交换率E-pH曲线的影响各不相同。

A selective and mild PS-DIB/ionic-liquid immobilized 2, 2, 6, 6-tetramethyl-piperidin-4-ol-N-oxyl catalytic oxidation procedure of alcohols to the corresponding aldehydes and ketones in ionic liquid BF4 at room temperature was developed. The oxidant PS-DIB was prepared via the iodation and acetylation of polystyrene resin. For the preparation of the ionic-liquid immobilized TeMPO catalyst, 4-(2, 2, 6, 6-Tetramethyl-1-oxyl-4-piperidoxyl)butyl bromide was first synthesized from TeMPO and 1, 4-dibromobutane.

将聚苯乙烯树脂先碘化再乙酰基化,制得了负载型二乙酰氧碘苯作为氧化剂。2, 2, 6, 6-四甲基-N-氧自由基哌啶醇与1, 4-二溴丁烷反应生成4-溴丁氧基-2, 2, 6, 6-四甲基-哌啶-1-氧化物,再与N-甲基咪唑发生季铵化反应,生成的溴化季铵盐与四氟硼酸钠进行离子交换制得氟硼酸型2, 2, 6, 6-四甲基-N-氧自由基哌啶负载离子液体。

A selective and mild PS-DIB/ionic-liquid immobilized TEMPO catalytic oxidation procedure of alcohols to the corresponding aldehydes and ketones in ionic liquid BF4 at room temperature was developed. The oxidant PS-DIB was prepared via Iodation and acetylation of polystyrene resin. For the preparation of the ionic-liquid immobilized TEMPO catalyst, 4-(2,2,6,6-Tetramethyl-1-oxyl-4-piperidoxyl)butyl bromide was first synthesized from 2,2,6,6-tetramethyl-piperidin-4-ol-N-oxyl and 1,4-dibromobutane.

将聚苯乙烯树脂先碘化再乙酰基化,制得了负载型二乙酰氧碘苯(diacetoxyiodo polystyrene,PS-DIB)作为氧化剂。2,2,6,6-四甲基-N-氧自由基哌啶醇(2,2,6,6-tetramethyl-piperidin-4-ol-N-oxyl,TEMPO)与1,4-二溴丁烷反应生成4-溴丁氧基-2,2,6,6-四甲基-哌啶-1-氧化物,再与N-甲基咪唑发生季铵化反应,生成的溴化季铵盐与四氟硼酸钠进行离子交换制得氟硼酸型2,2,6,6-四甲基-N-氧自由基哌啶负载离子液体TEMPO-IL。

The monovalent permeselectivity of ion exchange membrane may be improved by treating its surface.

经表面处理的离子交换膜可提高一价离子的选择透过性。

The mathematical models of the dynamics of the mass transfer based on the Nernst-Planck equation were established from which it is found that the different characteristics of the water decomposition between the cation and the anion exchange membranes or resins, is owing to the different potential gradient on the two kind of ion-exchange interfaces, which is further because of the difference between the structure and performance of the different membranes or resins, and is also because of the difference between transfer numbers of cation and anion ions.

根据所建立的传质数学模型方程获知在阴阳膜/树脂表面与水接触的界面层中发生的水解离的差异性,是在于离子交换界面电势梯度的差异,而这种差异又与膜与树脂的结构、性能以及阴阳离子在水溶液中的迁移数的差异有关。

Contaminant cations such as calcium,magnesium,barium,strontium,and radium and anions such as fluoride ,nitrate,fulvates,humates,arsenate,selenate,chromate ,and anioic complexs of uranium can be removed from water by using ion exchange or adsoption onto activiated alumina.

具有污染能力的像Ca,Mg,Ba,Sr,Ra的阳离子,和像氟化物,硝化物,黄酸物,腐质酸物,砷酸盐,硒酸盐和铬酸盐的负离子以及像铀一样的负离子复合物可以通过离子交换和离子吸附从水中排除。

In the first part, two novel methods were proposed for the determination of three kinds of organogermanium compounds βcarboxyethylgermanium sesquioxide,β- carboxyethylgermanium sesquioxide and di-(β-carboxyethyl) germanium hydroxide by using high performance ion-exchange and ion-exclusion chromatography.

第一部分采用高效离子交换和离子排斥色谱法,建立了两种测定三种有机锗化合物β-羧乙基锗倍半氧化物、β-羧乙基锗倍半氧化物、二-锗氢氧化物的新方法。

Chelate fiber with amidoxime group,which is obtained from chemical modification of PAN fiber,is treated with mercury nitrate to prepare anion-exchange fiber.

离子交换纤维的比表面大,对金属离子具有吸附选择性高、应用形式多样等特点,是近年来发展迅速的新型吸附材料[1~5]。

From the point of ion exchange and chelating ,the high adsorption selectivity was investigated by the peculary structure of amidoxime fiber(combined with crosslinking structure and the maximal conversion of cyano) and Au ion.

离子交换和螯合吸附的角度,根据偕胺肟基纤维本身的交联结构和最大氰基转化特点以及金离子本身的结构特点对其高选择吸附性能进行了解析。

The BAW detector combined with ion exclusion chromatography is used to determine short-carbon-chain organic acids in beehoney and beverages. NA and NAD in foods is also determined by IC-BAW.

本文以离子排斥色谱分离结合BAW检测,对峰蜜和饮料中的低分子有机酸进行了测定;也用离子交换色谱-BAW测定了常用食品中烟酸、烟酸胺的含量,实现质量监控。

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