离子

By using density functional theory B3LYP/6-311G++method, the geometric configuration was optimized for tetrahydrofuran、butylene oxide、 secondary oxonium ion and tertiary oxonium ion. And parameters about the electronic structure, bondlength, energy of frontier orbital of these species were determined.

采用DFT中的B3LYP/6-311G++方法对四氢呋喃和环氧丁烷单体、仲氧鎓离子以及叔氧鎓离子进行了几何构型的全优化，确定了各个构型的电子结构、键长和前线轨道能量等参数，并运用前线轨道理论从微观层次上分析了四氢呋喃和环氧丁烷的阳离子均聚反应机理。

In this paper, transparent Er(superscript 2+) ions doped oxyfluoride glass-ceramics was prepared by high temperature melting and thermal treatment technology. The changes of micro-crystals structure, UV-VIS absorption spectra and NIR emitting spectra occurred with the variety of Er(superscript 3+) concentrations were studied.

采用高温熔融及热处理工艺，制备了透明度良好的Er(上标 3+)离子掺杂的氟氧化物玻璃陶瓷，并研究了不同Er(上标 3+)离子掺杂浓度下，玻璃陶瓷微晶结构、紫外－可见波段吸收光谱、近红外发射光谱的变化。

We found out one kind of new orange-red long afterglow material La2O2S: Eu3+, Mg, Zr.2 In the phosphor Gd2O2S, Mg, Ti which was prepared by high-temperature solid-state method, the orange afterglow phenomenon can be seen after illuminated with UV light.3 Using the high-temperature solid-state method, Gadolinium oxysulfide phosphors doped with rare earth ions were synthesized. We can observe the red or orange phosphorescence in Gd2O2S doped with Eu3+, Sm3+, Tm3+, Yb3+, Dy3+, Er3+, Nd3+or Ho3+. This is a new result of the long afterglow phosphors research.4 Using the microwave radiation method, the new Sm3+ doped gadolinium oxysulfide phosphor, which has the orange-red long afterglow emission after illuminated with UV light or visible light, was synthesized for the first time.5 In fluorescent materials YOX doped with europium ions, the long afterglow phenomenon wasnt observed but the blue luminescence of Eu2+ and red luminescence of Eu3+ are simultaneously examined. This is a new result of the valence stability and change of Eu2+ in yttrium oxyhalide .We systematically studied the effects of the host, addition agents and reaction atmosphere on the valence change and fluorescence property of europium ions.

经过系统的研究总结得到以下的结论与成果： 1采用高温固相反应法合成了一系列稀土离子掺杂的硫氧化镧发光粉，发现了该体系中Eu~(3+)的长余辉发光，从而得到一种迄今未见文献报道的红色长余辉发光材料：La_2O_2S：Eu~(3+)，Mg，Zr； 2在Gd_2O_2S，Mg，Ti磷光粉中观察到橙色的长余辉发光现象； 3采用高温固相反应法合成了一系列稀土离子掺杂的硫氧化钆磷光粉，在掺杂Eu~(3+)、Sm~(3+)、Tm~(3+)、Yb~(3+)、Dy~(3+)、Er~(3+)、Nd~(3+)、Ho~(3+)的Gd_2O_2S中观察到红色和橙色长余辉发光； 4首次采用微波法合成了Gd_2O_2S：Sm~(3+)，Mg，Ti磷光粉，该磷光粉经紫外或可见光激发后呈现明显的橙红色长余辉发光； 5在YOX中同时观察到Eu~(2+)和Eu~(3+)的发射，系统研究了基质、添加剂及反应气氛对Eu价态和发光的影响。

Recently, it was reported that PANI could interact with many heavy metal ions and rare-earth cations.

研究表明：聚苯胺可以和许多金属离子和稀土离子相互作用。

A23187 and OA could parthenogenetically activate Urechis unicinctus oocytes and activate MAPK, indicating that the effect of fertilization on GVBD and activation of MAPK was mediated by rising in intracellular free calcium, and phosphorylation of some proteins was enough to activate the oocytes.

钙离子载体A23187和OA可以孤雌活化单环刺螠卵母细胞并激活MAPK。说明：①受精是通过钙离子的内流来激活卵母细胞并使MAPK活化的。②某些蛋白质的磷酸化状态对减数分裂是必要而且在一定程度上是充分的。

Chitosan had been modified by polyacrylate sodium, glularaldehyde, and NaBH4, respectively, which afforded three kinds modified chitosan: polyacrylate sodium modified chitosan (CIS- PA4) chitosan bead and pentamethylene diamido crosslinked chitosan bead (CTSB- G- Hy). The adsorption properties of CTS-CTSB and CTSB-G-Hy were studied by L25(56) orthogonal experimental design. They show high adsorption activities for Pb2+ in solution. The highest removal efficiency of Pb2+ for CTS-PA4, CTSB and CTSB-G-Hy is 94%, 96% and 93%, respectively. The results showed the adsorption property of CTSB is the highest. The CTSB- G- Hy has good mechanical property, acid-resistance and alkali-resistance.

第二部分壳聚糖的改性及其对水溶液中铅离子的吸附性能研究以壳聚糖为原料制备了三种改性吸附剂——聚丙烯酸钠改性壳聚糖(CTS——PA_4)、珠状壳聚糖凝胶树脂和戊二氨交联珠状壳聚糖凝胶树脂，着重考察了CTSB—G—Hy的制备条件，并考察了三种吸附剂吸附6.3mg/L铅离子水溶液中铅的最佳使用条件，结果表明对CTS—PA_4而言当pb~(2+)溶液的pH在4～6.5之间，吸附剂用量为5g/L，吸附时间为1h时pb~(2+)去除率高于94％，CTS—PA_4可在酸性条件下使用，在碱性条件下依然有效但处理效果较差；CTSB对pb~(2+)具有很好的吸附能力吸附剂用量为5g/L，吸附时间为1h时处理效果极佳，pb~(2+)去除率高于96％；CTSB—G—Hy对pb~(2+)具有一定的吸附能力，吸附剂用量为3g/L，吸附时间为1.5h时处理效果最佳，Pb~(2+)去除率高于93％，而且CTSB—G—Hy的机械强度高，耐酸碱性强，可在较宽的pH范围内使用。

The possible reason is that doped Zr〓 ion enters the interstitial sites for its small ionic radius and no dipole complexes were formed. Monovalent ion F〓 has been reported to improve the scintillating performance greatly. Our results show that Agrand diagrams of F〓: PWO crystals obey an modified Cole-Cole equation. The crystals present similar dielectric relaxation phenomena to but have much higher activation energy than that of RE〓: PWO crystals, which originate from the 〓 dipole complexes. The co-doping of trivalent Y〓 and pentavalent ion Nb〓 does not always show a better scintillation performance than that of solely doped samples, which could be attributed to the existence of the 〓 dipole complexes, which counteract the solely doping effect.

而Zr〓由于离子半径太小，可能进入间隙位置，不形成类似的偶极缺陷；一价负离子F〓的掺入提高了晶体闪烁性能，阻抗谱测试结果表明F〓：PWO晶体Argand图符合修正的Cole—Cole方程，晶体同样表现出介电弛豫现象，并具有比RE〓：PWO晶体中高得多的弛豫激活能，可能起源于形成的〓偶极缺陷；Y〓和Nb〓双掺的PWO晶体并没有显示出两种离子单掺优点的叠加，阻抗谱测量结果表明，在双掺晶体中可能形成〓偶极缺陷，使两者掺杂作用相互抵消。

The results are: 1 the stricture of the capillaries of stria vascularis was observed in most cochleae of rickety rats and, segmental deletions of the outer hair cells on the first turn of cochlea were found in a small number of rickety rats; 2 the perilymphatic ionized calcium concentration significantly re- duced and the threshold of CAP (Compound Action Poten- tials of the eighth nerve) significantly rose in rickety rats in comparison with those of normal control; 3 gentamicin results in an increase of the perilymphatic ionized calcium concentra- tion in rickety rats; 4 the cochleae of the rickety rats appeared to be less vulnerable to the ototoxicity of gentamicin than the normal one.

研究包括两个方面，其一是&佝偻病的感觉神经性耳聋及其对庆大霉素耳毒性作用的耐受性&，系用大白鼠建立维生素D缺乏性佝偻病动物模型，发现：（1）佝偻病大白鼠耳蜗血管纹毛细血管狭窄，少数动物耳蜗底回外毛细胞有节段性缺失；（2）佝偻病大白鼠的耳蜗鼓阶外淋巴钙离子浓度降低，CAP（听神经复合动作电位，以下简称CAP）听阈提高；（3）庆大霉素可使佝偻病大白鼠耳蜗外淋巴钙离子浓度上升；（4）佝偻病大白鼠耳蜗在功能和形态上都比正常者更能耐受庆大霉素的耳毒性损害。

After enter to environment and occur complicated chemistry process, heavy metal may become many kinds of pollutions which be in different shape and different struction. For example, in soil, heavy metal can be differentiated five shapes generally, namely, dissolved, permutable by feeble permutoid, permutable by strong permutoid, original mineral, secondary mineral.

重金属排入环境后，有复杂的化学过程，形成多样化的形态或结构的污染物，如土壤中的重金属离子或类金属离子可分为五种形态：①水溶态的；②弱代换剂可代换的；③强代换剂提取的；④次生矿物中的；⑤原生矿物中的。

Animal venoms are among the richest sources of toxins and pharmacologically active compounds that act on ion channels .

就离子通道和动物离子通道毒素的来源，种类，特性及其对新药开发的意义进行了综述。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。