离子

The novel complex (1) in which both benzylic nitrogens and heteroaromatic ones to the same metal ion with the rigid ligand imposed by the large heteroaromatic moiety first time was synthesized; a 2: 1 (ligand: metal ions) type complex which has steric resistance and strong thermochemical driving force was obtained. The crystal structures of characteristic ligand (LA4) and complexes (4, 7, 10), in which one cell includes two moieties: there exist minute difference in coordinated bonds and angles despite the same metal ions with the same ligand, were obtained. It shows that several stable conformation in one complex cell.

首次合成了含邻菲罗啉的具有较大刚性的四氮配体中四个氮原子全部与同一金属离子配位的配合物的晶体结构；得到了一个在空间上存在位阻作用的配体与金属离子2：1结构的晶体；解析了具有特色的一个配体（LA4）和三个配合物（4、7和10）的晶体结构，其中的配体与金属离子的配位作用显示出细微的差异，表明在同一金属配合物的晶胞中，可以同时存在着多个稳定的构象。

In this thesis, a S~(2-) modified B-Z oscillating system has been successfully used to determine some heavy metal ions and through examining the influence of S~(2-) and benzylpenicillin sodium on B-Z chemical oscillating reaction highly sensitive detection methods of them have been developed.

本文主要研究了利用硫离子修饰的B-Z化学振荡体系对一些重金属离子的测定；同时利用经典的B-Z化学振荡体系对非金属硫离子进行了测定，并考察了药物青霉素G钠盐对该体系的动力学扰动行为。

The metal ions of the dinuclear copper complex of [Cu_2_2Cl_4] are linked by two N~1,N~2 1,2,4-triazole bridges,and the central Cu ions have distorted trigonal bipyramid geometries. The central Cu ion of [CuL22]·H2O has a centrosymmetric and distorted tetragonal-octahedral geometry. The metal ions of the dinuclear manganese complex of [Mn_2L_2_2Cl_2(H_2O)_2] are bridged by two chlorine atoms, and the central Mn ions have distorted tetragonal-octahedral geometries. Part III.

配合物[Cu_2_2Cl_4]是通过配体L的1，2，4-三唑环上两个氮原子(N~1，N~2)桥联形成的双桥双核配合物，每个中心铜离子都具有畸变的三角双锥构型；配合物[CuL22]·H_2O的中心铜离子具有中心对称的畸变八面体构型；配合物[Mn2L2_2Cl_2(H_2O)2]是通过两个氯原子桥联形成的双桥双核配合物，每个中心锰离子都具有畸变的八面体构型。

In part three oxidation of bromide with an ion-supportedbenzene in ionic liquids afforded a clean path for bromination of alkenes. It was found that this reaction is highly stereoselective.

在离子液体中使用离子支持的二乙酸碘苯氧化溴离子，提供了一条清洁的烯烃加溴途径，发现反应具有高的立体选择性。4。

The system can endure the change of chloric ion concentration by increasing from 8 500 mg/L to 12 500 mg/L or decreasing from 8 500 mg/L to 4 500 mg/L, and it is more tolerant to the sudden increase than that of the sudden decrease of chloric ion concentration.

系统能够忍受氯离子浓度从8 500 mg/L直接升到12 500 mg/L和从8 500 mg/L直接降低到4 500 mg/L的变化，且抗氯离子浓度突然升高的能力比抗氯离子浓度突然降低的能力要强。

Synthesis of isopropyl chloroacetate catalyzed by acidic ionic liquids was studied,including influences of different ionic liquids,reaction temperature,reaction time and quantity of ionic liquid.

研究了功能化酸性离子液体催化合成氯乙酸异丙酯的反应，考察了不同离子液体、反应温度、反应时间和离子液体与反应物物质的量比等对反应的影响。

These experiments suggest that this dihydropyridinesensitive isoform of the mbC α1 subunit is functional in the transfected chromaffin cells and that the number of calcium channels is a limiting component in the secretion from chromaffin cells in culture.

这些实验结果推论这个小鼠脑中的对双氢吡啶敏感的mbC钙离子通道是L-型钙离子通道，并在转化的肾上腺嗜铬细胞中具有功能活性，而且说明钙离子通道的数目对培养的肾上腺嗜铬细胞的分泌是个限制因素。

However, collisional scattering of product ions in CID results in decrease in intensity of the primary product ion.

但胜肽利用碰撞引致裂解方法碎裂之后，母离子会平均碎裂成子离子，因而大幅减低子离子强度。

Non-fluoride ionic number of Nd-F in dilute LiF-NdF3 melts and Nd-O-F species in dilute LiF-NdF3-Li2CO3 melts was researched by cryoscopic method,respectively.

采用冰点降低法分别研究了以LiF为溶剂的稀LiF-NdF3熔盐中Nd-F离子团及LiF-NdF3-Li2CO3熔盐中Nd-O-F离子团的非氟离子的个数。

Cytophaga sp was selected for heparinase production because it was more productive. Three heparinases, named HⅠ, HⅡ and H Ⅲ were purified from the crude cell extract by means of batch DEAE-Cellulose negative adsorption, Hydroxylaptide adsorption and releasing, SP-Sepharose cation exchange chromatography, Source 30S cation exchange chromatography, Poros 20HS cation exchange perfusion chromatography and Sephacryl S200HR gel permeation chromatography.

利用超声破碎、DEAE-纤维素反吸附去杂、羟基磷灰石批处理吸附层析、SP-Sepharose离子交换层析、Source 30S离子交换层析、Porous20HS离子交换灌注层析及Sephacryl S200HR凝胶排阻层析，从噬纤维菌中纯化出三种新的肝素酶。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐