离子

The organoboron compounds in this paper are based on triarylboranes, boronic acids and boronic esters. The structure-property relationship and sensing mechanism are elucidated. Organoboron compounds as Lewis acid can be used as fluoride probe with high sensitivity and selectivity because they have a unique LUMO in which the π-conjugation is divergently extended through the vacant p-orbital of the boron atom. The complexation of the boron π-electron systems with fluoride ion would interrupt the π-conjugation extended through the boron atom, causing the change of photophysical properties.

介绍了基于三芳基硼化合物、硼酸和硼酸酯的有机硼化合物在氟离子检测中的应用，评述了这些化合物的结构和检测性能之间的关系，讨论了检测机理，即有机硼化合物中硼原子空的p轨道使其作为路易斯酸能够选择性地结合氟离子，硼原子与氟离子的结合破坏了硼中心与芳香取代基的p-π共轭，引起有机硼化合物光物理性质的变化，从而实现对氟离子的高选择性检测。

Both catalytic activity and selectivity of Ru(PPh_3)_3Cl_2 were improved in ionic liquid BMImPF_6/DME medium.The conversion of hexene and selectivity ofβ-adduct for the hydrosilylation reaction of 1-hexene with triethoxysilane catalyzed by Ru(PPh_3)_3Cl_2 in ionic liquid BMImPF_6DME (V/V=1/4) medium at 90℃were 100% and 89.0%,respectively.

实验结果表明，在乙二醇二甲醚/离子液体1-丁基-3-甲基咪唑六氟磷酸盐(BMImBF_6)(V/V =1/4)介质中，于90℃下，己烯与三乙氧基硅烷反应的转化率为100%，β加成物的选择性可达89.0%，而用Rh(PPh_3)_3Cl作为反应的催化剂，在纯离子液体BMImPF_6中，就可以高效催化烯烃与三乙氧基氢硅烷的加成反应，过渡金属Rh(PPh_3)_3Cl，Ru(PPh_3)_3Cl_2催化剂/离子液体BMImPF_6催化体系，不仅解决了产物与催化剂分离困难这一难题，同时，离子液体BMImPF_6的存在提高了过渡金属Rh(PPh_3)_3Cl，Ru(PPh_3)_3Cl_2催化硅氢加成反应的活性，特别是β加成物的选择性。

The nickelous chloride both may use in to galvanize, and is prepares the galvanization chemical thionamic acid nickel the important raw material, lead is affects the electronickelling quality a important attribute, in the present industry 331 ion exchange resin deleading effect still could not arrive in the electronickelling the lead content standard, used pocket weak basicity resin XSC312 after the screening experiment determination to take from the nickelous chloride solution intermediate ion exchange except the micro lead resin, inspected the material fluid pH value, the contact duration in the ionic exchange column to the ionic exchange adsorption lead influence, has determined the resin adsorption capacity and inspected the resin analysis performance.

氯化镍既可用于电镀，又是制备电镀化学品氨基磺酸镍的重要原料，其中的铅是影响电镀镍质量的一个重要因素，现行工业中的331离子交换树脂除铅效果尚不能到电镀镍中铅含量标准，经过筛选试验确定采用大孔弱碱性树脂XSC312作为从氯化镍溶液中离子交换除微量铅树脂，在离子交换柱中考察了料液pH值、接触时间对离子交换吸附铅的影响，测出了树脂的吸附容量并考察了树脂的解析性能。

Considerable attention has really been focused on ionic liquids as "green" alternatives to classical environmentally damaging organic solvents in many fields such as in organosynthesis, material, catalysis, electrochemistry, biochemistry, physicochemistry, separation and so on. However, there have been only a few examples of chiral ILs have been reported so far, and ILs possessing chirality are having been synthesized aimed at application in asymmetric catalytic reaction.

离子液体在许多领域如电化学、有机合成、催化、生物化学、物理化学、材料及分离等的绿色替代溶剂技术引起了人们的重视，然而，有关手性离子液体的合成与应用的报道比较少，含有手性片段的离子液体不断被合成出来并期望在不对称催化反应中得到应用，但是成功的例子不多，使用手性离子液体在不对称催化反应中还在初始的探索阶段。

The results showed that the interactions between Al(superscript 3+), Fe(superscript 3+), polysilicic acid, the polynuclear hydroxy complexes of Al(superscript 3+), Fe(superscript 3+) and SO(superscript 2- subscript 4) had a compositive effect of electric neutralization, adsorption and bridge on the coagulating properties.

结果表明，含硅多核无机高分子絮凝剂的混凝作用是铁离子、铝离子、聚硅酸、铝铁离子的水解聚合物以及它们和硫酸根离子相互作用的产物对废水中胶体悬浮物颗粒的电中和、吸附架桥及粘附卷扫等综合作用的结果。

Three kinds of ionic liquid were used to support the acetylacetone at the C3 position directly according to the method indicated above. These synthesized ionic liquid supported acetylacetone catalysts include imidazolium salts ionic liquid supported acetylacetone catalysts, pyridinium salts ionic liquid supported acetylacetone catalysts and ammonium salts ionic liquid supported acetylacetone catalysts. All these catalysts were characterized by ~1H-NMR,~(13)C-NMR, IR and elementary analysis.

采用设计过程中预期能够提高乙酰丙酮金属催化剂催化氧化活性的修饰方式，合成了三类离子液体支载的乙酰丙酮金属催化剂：咪唑型离子液体支载乙酰丙酮金属催化剂、吡啶型离子液体支载乙酰丙酮金属催化剂、胺型离子液体支载乙酰丙酮金属催化剂，并采用核磁共振氢谱、碳谱，红外光谱及元素分析来对这些新型的催化剂进行了表征。

Results of meausred radioluminescence spectra show that energy transfer mechanisms occurring from Gd3+ cations towards Tb3+ emssion centers as well as the cross relaxation among Tb3+ cations within the certain concentration range exert tremendous effects on the emission intensity of glasses.

Tb3+离子的掺杂浓度范围为1－5 mol %。玻璃样品的X射线激发发射光谱结果显示，发生在玻璃基质中由Gd3+离子向发光中心Tb3+离子的能量转移机制以及在一定浓度范围内Tb3+离子之间的交叉驰豫过程对玻璃的发光性能有重要影响。

Both the rarefactive and compressive waves can be determined by plasma parameters including the temperatures of dust fluid, ion and electron, as well as the non-thermal ions, and the number densities of dust particle , ion and election, etc.

而稀疏孤波和压缩孤波的存在则完全取决于尘埃等离子体参数，如：尘埃流体、离子和电子的温度，非热离子的快离子数以及尘埃颗粒、离子和电子的数密度等。

The ionic conductivity of polymer electrolytes equaled 3.56×10-4 S·cm-1 when the mass fraction of silicotungstate lithium was 8.5% in polymer film. The lithium ions transference number, which was measured by the method of combination of AC impedance with DC polarization, decreased with increase of the mass fraction of Li4SiW12O40 in the porous polymer film.

为了提高聚合物电解质的Li+离子迁移数，人们设法增大阴离子的体积[6~8]使其难以迁移而达到提高Li+离子迁移数的目的，很少应用含有多个Li+离子的锂盐做聚合物电解质的Li+离子载体。

To test the hypothesis, neontal rat cadiomyocytes Treat with heat shock(HS,42℃,2h) to induce the expression of HSP70,then teated with 0.5mmol/L H2O2. We first found H2O2 can reduced cadiomyocytes apoptosis and HSP70 only over-expression in the HS group, other two group only express HSP70 a little in the test of expression of HSP70.Then we tested the concentration of Ca2+, the [Ca2+ ] of CON was 192.224+6.654, the [Ca2+ ] of H2O2 group was 290.6918+8.922and the [Ca2+]of HS group was 214.2633+4.484.To further determine how HSP70 repaired the Ca2+ homestasis, we measured calcium transient of each group.

实验中应用MTT和流式细胞技术检测细胞的凋亡，发现损伤组的存活率明显低于其他2组，热休克组(Heat shock group，HS group)细胞存活率略低于正常组细胞；免疫组化结果表明只有在HS组才检测到阳性反应，即是HSP70的表达，其他2组均为弱阳性结果；应用离子成像技术对细胞内钙离子浓度进行测定，发现损伤组290.6918+8.922明显高于正常组192.224+6.654和HS组214.2633+4.484，HS组细胞内的钙离子浓度略高于正常组；为了进一步探讨HSP70对于ROS引起的心肌凋亡过程中钙离子的调控机制，又对各组的心肌细胞进行了钙瞬变的测定。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。