磺酸盐

A catalytic amount of Ln(OSO2CF3)3 affected the stereochemistry of-MOPMAM during radical polymerization: the polydispersities of the polymers prepared in the presence of the Lewis acid were broader than those without the Lewis acid and the absolute value of specific rotation decreased in a majority of solvents.

结果表明，在-MOPMAM的聚合反应中，加入稀土盐可观察到明显的效应：在大部分情况下，随着三氟甲磺酸稀土盐加入量的增加，聚合物分子量分布变宽，旋光度也有很大幅度的下降。

It is concluded that the main influence factors on the micro-hardness of the nickel deposit are sulphamate concentration and electrolyte temperature. The most hard nickel deposit layer was obtained with sulphamate concentration 700g/L, cathodal current density 5A/dm2, pulse current frequency 800Hz, pulse current duty cycle 0.6, electrolyte pH value 4.0, electrolyte temperature 70℃.

试验结果表明：主盐浓度和镀液温度是影响镀层硬度的显著因素；当主盐氨基磺酸镍的浓度为700g/L，阴极电流密度为5A/dm2，脉冲频率为800Hz，占空比为0.6，镀液pH值取4.0，镀液温度为70℃时，可以制得显微硬度最高的镍镀层。

The UV and IR spectroscopic studies of the monomer films showed that the photoreaction ratio of monomer (about 50%) was higher than the corresponding photosensitive polymer (about 10%, PVCi). The polarized IR spectra proved that obvious anisotropic absorption was displayed in the irradiated photosensitive film. With polarizing microscopy method, we found that these kinds of photoalignment films exhibited good alignment ability, and the stability of the photoalignment film could reach about 100℃. 2 A photosensitive self-assembled monolayer was fabricated that contained photo-cycloadditable groups, such as, coumarin and cinnamate. The reaction process were detected by contact angle method because the IR absorption of monolayer was very weak. The photosensitive self-assembled monolayer promote uniform alignment of nematic liquid crystals by LPUV, and it thermal stability could reach about 130℃. 3 A cationic bolaform amphiphiles was synthesized that had two photosensitive double bonds, and can be polymerized by ultraviolet. A layer-by-layer self-assembled deposition film was prepared in aqueous solution by using this material and poly (sodium 4-styrenesulfonate). The UV-Vis. spectra proved that the multilayers film was uniform and layer-by-layer. When LPUV irradiated the film, the photopolymerizable double bond underwent [2+2] cycloaddition, and the production of the reaction distributed along the polarized direction of incident LPUV. Polarized UV-Vis. spectra indicated that the irradiated self-assembled multiplayer film was anisotropic, and the dichromic ration is about 0.09, it is higher than the spin-coating method of photosensitive polymer or monomer. We used this anisotropic film as alignment layer of nematic liquid crystals, and obtained a uniform and stability alignment result, the static contrast ratio is about 100, which is very close to application of liquid crystal device. This thesis is an instance that the photochemical material was used in the physics region of liquid crystals, the route that was from photosensitive monomer, self-assembled monolayer film to self-assembled multiplayer film was undergone, by this logical research method photoailgnment of liquid crystal was extended and consummated.

围绕上述思路开展了如下工作：1合成了三种可进行光二聚反应的光敏小分子单体，LPUV 辐照制作了光控取向膜；用紫外-可见光谱法和红外光谱法分析了薄膜中的光化学反应，发现小分子的光反应程度可达到50%以上，至少比光敏高分子高出5倍；薄膜的偏振红外光谱证实，经过LPUV 辐照后薄膜出现了明显的各向异性；将小分子光控取向膜制成液晶器件，在偏光显微镜下观察看到均匀一致的液晶取向；并且热稳定性达到100℃左右，接近实用化要求。2制备了含肉桂酸、香豆素基团的自组装单层膜；采用接触角的方法监测自组装反应的动力学过程；紫外-可见光谱证实了自组装单层膜在石英基板表面形成；自组装单层膜经LPUV 辐照后能诱导液晶均匀取向，而且热稳定性可达130℃，热稳定性进一步提高。3合成了含有光敏双键的双季铵盐，在水溶液状态下将它和聚乙烯基苯磺酸钠沉积生成layer-by-layer 自组装多层膜，紫外-可见光谱证实这是一个逐层均匀的沉积；在LPUV 照射下，自组装膜中的光敏双键按照偏振方向发生[2+2]环加成反应，形成取向膜，用二向色性值评价的分子取向度高于高分子及小分子光控取向膜的水平；实验证明用自组装多层膜制成的液晶器件亮暗态均匀，静态对比度约为100，达到实用化器件的水平。

Carbamide reacting with H2SO4 forms aminosulfonic acid. Allantoin is prepared by oxidation of the aqueous solution of glyoxal into glyoxylic acid which is then used to synthesize allantoin.

氨基磺酸的合成是用尿素和发烟硫酸反应；尿囊素的合成是用硝酸氧化乙二醛溶液制得乙醛酸后，再加入氢氧化钙和氯化钙，使乙醛酸以钙盐形式析出，然后在盐酸介质中与尿素缩合而成。

Firstly, polyacrylamide with 26 million molecular weight was compounded in lab through establishing optimum compounding initiator proportionality of 1:1. 3 and mass concentration of 170 mgL^(-1), temperature of 10 ℃, acrylamide mass percentage of 25%, electrical conductivity of 3.6 μSm^(-1) and pH value of 6.57. The salt-resistance, thermal endurance and shear-resistance of polyacrylamide could be enhanced b introducing sulfonic acid group or styrene sulfonate group or drawing the two groups above at the same time. Secondly, chelator HEDP, bactericide isoquinoline ketone and oxygen scavenger thiourea were optimized to improve the compatibility of polyacrylamide and formation water.

在由室内试验确定了复合引发剂最佳比值1：1.3和质量浓度170 mgL^(-1)、合成最佳温度10℃、丙烯酰胺单体质量分数25%、电导率3.6μSm^(-1)和pH值6.57后，合成出相对分子质量高于2.6×10^7的聚丙烯酰胺，同时通过丙烯酰胺单体复配引入磺酸基团、苯乙烯磺酸基团或同时引入此两种基团，提高了聚合物的抗盐、抗温、抗剪切性能；后针对聚丙烯酰胺与地层水配伍性差的问题，优选出HEDP螯合剂、异噻唑烷酮杀菌剂和除氧剂硫脲，对聚合物稳定效果明显。

Myristic monoethanolamide ammonium sulfatewas synthesized from myristic acid and monoethanolamide with sulfamic acid as sulfating agent .

在芳烃类溶剂与羰基化合物催化剂存在下，以肉豆蔻酸和乙醇胺为原料，氨基磺酸作硫酸化剂，制备了肉豆蔻酸单乙醇酰胺硫酸酯铵盐。

Our company specializes in operating plating materials: sulfamic acid nickel, nickel sulphate, nickel chloride, nickel carbonate, etc.; environmentally friendly sewage treatment materials: polyacrylamide, polypropylene acid sodium, ferrous sulfate, etc.; washing cleaning materials: OP - 10, TX-10, NP-9, K-12, JFC, sodium carboxymethyl cellulose, etc.; cosmetic raw materials: Triclosan, Resorcinol, stearic acid and so on, basic chemical raw materials: Industrial salt, soda ash industrial ammonium chloride, ammonium chloride agriculture, Sodium Sulfate, Sodium Molybdate, Ammonium Molybdate, as well as chemical products such as UV-absorbers.

本公司专业经营电镀原料：氨基磺酸镍，硫酸镍，氯化镍，碳酸镍等；环保污水处理原料：聚丙烯酰胺，聚丙烯酰钠，硫酸亚铁等；洗涤清洗原料：OP-10，TX-10，NP-9，K-12，JFC，羧甲基纤维素钠等；化妆品原料：三氯生，间苯二酚，硬脂酸等，基础化工原料：工业盐，纯碱，工业氯化铵，农业氯化铵，元明粉，钼酸钠，钼酸铵等以及紫外线吸收剂等化工产品。

A kind of high speed sulphamate nickel-based electrolyte is chosen as basal electrolyte, the influences of plating process parameters on the micro-hardness of the nickel deposit have been studied by orthogonal experiments. It is concluded that the main influence factors on the micro-hardness of the nickel deposit are sulphamate concentration and electrolyte temperature, the deposition rate and quality in single-pulse mode are higher than that in DC power and double-pulse mode.

选择以氨磺酸型高速镀镍液作为基础镀液，通过正交试验研究了电镀工艺规范对镀层显微硬度的影响关系，试验结果表明：镀液主盐氨基磺酸镍浓度和镀液温度是影响镀层硬度的显著因素，单脉冲供电模式下的电镀沉积速率和镀层质量优于直流和双脉冲模式。

Pentanediol reacted with phosphorus tribromide to make it mono-bromination, under the catalytic action of PPTs it reacted with 2,3-dihydropyran to protect another hydroxy group, then to react with triphosphine, produced quarterphossal.

再以1，5-戊二醇为原料，三溴化磷使之单溴代，得到5-溴-1-戊醇，在对甲苯磺酸吡啶盐的催化下与2，3-二氢吡喃反应保护其另一端的羟基，与三苯基膦反应生成季磷盐。

The sodium dodecyl sulfate eletrophoresis pattern of proteins showed that 32Kd, 36Kd and 41Kd proteins were rich synthesized in the NaCl-tolerant cell line and the corresponding bands strengthened. Abore all, the 38Kd protein band is a specific band of the NaCl-tolerant cell line.

耐盐系和对照系可溶性蛋白质的十二烷基磺酸钠电泳图谱表明：耐盐系中32Kd，36Kd和41Kd蛋白质合成加强，并且在38Kd蛋白质处出现了所特有的带。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。