磺酸盐

Linear alkyl benzenes and linear alkyl dimethyl benzenes, prepared by the alkylate reaction of linear alpha olefin with benzene or dimethyl benzene which were sulfonated by chlorosulfonic acid and then neutralized to produce linear alkyl benzene sulfonates and linear alkyl dimethyl benzene sulfonates.

本文以一定链长的直链α-烯烃分别与苯和混合二甲苯为原料制备了直链烷基苯和烷基二甲苯，经氯磺酸磺化，中和可得到具有一定链长的直链烷基苯磺酸盐和直链烷基二甲苯磺酸盐。

A series of long chain alkyl methylnaphthalene sulfonates, including hexyl methylnaphthalene sulfonate, octyl methylnaphthalene sulfonate, decyl methylnaphthalene sulfonate, dodecyl methylnaphthalene sulfonate, and tetradecyl methylnaphthalene sulfonate, was characterized by high performance liquid chromatography and electrospray ionization mass spectrometry. Through a great deal of testing, the analytical conditions were optimized.

采用反相离子对高效液相色谱和电喷雾离子化质谱对系列长链烷基甲基萘磺酸盐，包括己基甲基萘磺酸盐、辛基甲基萘磺酸盐、癸基甲基萘磺酸盐、十二烷基甲基萘磺酸盐、十四烷基甲基萘磺酸盐进行分析，通过液相色谱分离条件的优化，找到了最佳分析条件。

The partial substitution of α-olefine sulfonate instead of alkylbenzene sulfonate and the production technology of α-olefine sulfonate were also described.

介绍近几年来大型磺化反应器和磺化装置的国产化及原有磺化装置的技术改造，α-烯基磺酸盐部分取代烷基苯磺酸盐及AOS生产技术，并概述了脂肪酸甲酯磺酸盐的产品开发、磺化产品的活性物干燥，以及其他磺化产品的开发等。

In part one, the reactions of some active fluorine-containing compounds such as 2, 2-dihydropolyfluoroalkanoic acids and ethyl 2-hydropolyfluoroalkenoates were studied and various fluorine-containing heterocyclic compounds were synthesized. Using 2, 2-dihydropolyfluoroalkanoic acids as the starting material, 4-fluoroalkyl quinolin-2-ols, 2- [ -1-hydropolyfluoro-1-alkenyl] -4H-3, 1-benzoxazin-4-ones, 1-aryl -4, 9-dihydro-3-fluoro-alkyl-1H-pyrazo [3, 4-b] quinolin-4-ones, 5-fluoroalkyl-12H-quin olino [2, 1-b] quinazolin-12-ones, 4-fluoroalkyl-1, 3-dihydro-1, 5-benzodiazepin-2-ones and 4-fluoroalkyl-2H-pyrido [1, 2-a] pyrimidin-2-ones were synthesized through its condensation reaction with anilines, anthranilic acid, N'-aryl-o-aminobenzamides, o-nitro aniline, o-amino pyridine and their derivatives and the subsequent transformations. 5-Fluoroalkyl isoxazolidines, 3-fluoro-3-fluoroalkylisoxazolidino [4, 3-c] quinolin-4-ones, 3-fluoroalkylisoxazolino [4, 3-c] quinolin-4-ones and 2-aryl-3per fluoroacylindoles were synthesized by inter-and intramolecular 1, 3-dipolar cycloaddition of fluorine-containing olefins and nitrones.

第二部分，我们研究了α，α-二氟苄基卤类化合物的亚磺化脱卤反应、产物的转化及全氟烷基亚磺酸盐与芳环化合物的全氟烷基化反应，发现全氟苄基碘或溴及α，α一二氟苄基溴在保险粉等亚磺化脱卤试剂引发下可生成相应的亚磺酸盐；全氟苄基亚磺酸盐与氯气或溴反应可生成全氟苄基磺酰氯或磺酰溴；在烯烃存在下，全氟苄基碘则与烯烃发生加成反应，生成相应的1：1加成产物；在三价醋酸锰的作用下，部分芳香化合物如茴香醚，二甲氧基苯，吡啶，喹啉等可以和过量的全氟烷基亚磺酸盐发生双全氟烷基化反应，反应表现出一定的区域选择性，产率良好。

For TRO there are a little surfacatants whose effect are not good.In this paper,content of sulfonates and composition of alkyl are decided through right design ;under control reaction conditions different alkylbenzene sulfonates are synthesized;Polyreaction catalyst is developed .non-straight high carbon olefine are made through C9-C12 Polyreaction technolgy;clear composition alkylkenzene is sulfanated in falling-film reactor by SO,product can be adjusted,recipe of the surfacate can be used for super-low interfacialtension with Daqing oil -10-3-10-4mN/m,and stablity is good too.According to method issued by Daqing Develop and Explore Research institute,EOR is over 20% in natural core .

本文研究通过烷基苯磺酸盐组成的正确设计，确定了磺酸盐的当量范围和烷基碳数组成和分布；通过对烷基化条件控制，设计合成了不同碳数的直链和支链烷基苯及烷基二甲苯，并用于制备了相应的烷基苯磺酸盐；研制出了新型的烯烃叠合络合催化剂，采用C_9、C_(12)支链烯烃叠合工艺合成了更高碳数的支链烯烃，并进一步合成出相应的烷基苯和烷基二甲苯；以SO_3为磺化剂，通过对磺化条件的选择和控制，采用已知组成的烷基苯混合物进行膜式磺化反应，使合成工艺得以简化；所得磺酸盐组成确定并且可控，最终配方可与大庆原油形成超低界面张力，达10~3～10~(-4)mN/m数量级，且稳定性良好；以合成的烷基苯磺酸盐为主体形成了三元复合驱配方，室内驱油模拟实验表明，按照大庆研究院对复合驱体系活性剂的评价方法，在天然岩芯上的驱油效率在20％以上。

The results show: in a specific concentration range, the solubility in neutral solution of SOL, as well as the surfactivity, the ability to reduce ITF and the wettability on the condition of non- alkali are better than the lignosulfonate in market.While using as sacrifice agent, the modified lignosulfonate can reduce 60% of the mahogany sulfonate and 50% of the α-alkene sulphonate which both are adsorbed on the oil sand surface.

结果表明在一定浓度范围内，SOL在中性溶液条件下的溶解性、在无碱条件下的表面活性、降界面张力能力、对岩石的润湿性效果优于市场木质素磺酸盐产品；作为牺牲剂使用时，改性磺化木质素能减少石油磺酸盐在油砂表面吸附的60%，减少α-烯烃磺酸盐在油砂表面上吸附的50%。

Aggregation Behavior and the Hard Water Resistant Ability of Linear Alkylbenzene Sulphonate :MesoDyn Simulation and Quantum Calculation Study The quantum calculation and MesoDyn simulation were combined in this paper, the Critical Micella Concentration difference of LAS and AS was studied by the simulation, and aggregation morphology as well as aggregation behavior of linear alkylbenze sulfonate in aqueous solution was investigated by MesoDyn simulation in the presence and absence of shear.

水溶液中直链烷基苯磺酸盐的介观模拟及其抗硬水能力的量子化学计算将介观模拟和量子化学计算方法相结合，通过模拟的方法从介观角度研究了十二烷基苯磺酸盐和十二烷基磺酸盐临界聚集浓度的差异，考察了LAS水溶液体系的聚集形貌以及微相分离时发生的复杂行为。

The industrialized situation, problems and solving ways of heavy alkylbenzene sulfonate and petroleum sulfonate were mainly, such introduced, and the research developments and industrialized prospect of arylalkyl sulfonate, alkylated diphenyl ether sulfonate and fatty alcohol ether sulfonate were discussed at the same time.

介绍了重烷基苯磺酸盐和石油磺酸盐工业化生产的现状、存在的问题以及解决的途径，并探讨了芳基烷基磺酸盐、烷基二苯醚磺酸盐和脂肪醇醚磺酸盐的研究现状与工业化前景。

But, at present, the production of a soil displacement agent from heavy alkylbenzene sulfonate and petroleum sulfonate as oil displacement agent, there were still some problems as the instable quality, produce scale. It is necessary to develop a feasible production process of arylalkyl sulfonate, alkylated diphenyl ether sulfonate and fatty alcohol ether sulfonate as they can be used as oil displacement assistant in some special oil reservoir. In which Because their abundant raw material, big changeability of structure, high electrolyte tolerance, especial strong calcium tolerance, fatty alcohol ether sulfonate has huge industrialized value.

指出重烷基苯磺酸盐和石油磺酸盐作为三次采油的主表面活性剂，目前在工业化生产中仍存在一些问题，产品质量不太稳定，需进一步改进生产工艺技术，提高产品质量，扩大生产规模；芳基烷基磺酸盐和烷基二苯醚磺酸盐可作为助表面活性剂用于特殊的油藏条件，有必要尽快开发可行的工业化生产工艺；脂肪醇醚磺酸盐类表面活性剂的原料来源丰富，分子结构可变性强，耐电解质能力强，尤其是耐钙能力强，应用领域广，极具工业化价值。

The change of the position of the benzene ring has little effect on γ cmc-The interfacial tension behavior of this series of alkylbenzenesulfonates with carbon number 14,16,18 was investigated in alkane/aqueous system, it is found that alkylbenzenesulfonates of 16 total alkyl carbon number is the best.

通过对单烷基苯磺酸盐和二烷基苯磺酸盐的降低界面张力能力的比较，结果表明附加基团在一定程度上可以改善烷基苯磺酸盐降低界面张力的能力，而且使达到最低界面张力所需的最佳碱度要小。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。