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The impact of reaction conditions, such as acid/oil ratio, reaction temperature and reaction time on the product yield was studied.

在磺化反应过程中主要考察了反应温度、反应时间和酸油体积比对石油磺酸收率的影响。

At first,the intermediate of sodium 3-chloro-2-hydroxy propanesulfate was synthesized from epichlorohydrin and sodium bisulfite;And then,using NaOH as a catalyst,the title compound has been synthesized from intermediate and allyl alcohol to reach the yield of about 70%.

先由环氧氯丙烷和亚硫酸氢钠合成中间体3-氯-2-羟基丙磺酸钠,然后中间体再与丙烯醇在氢氧化钠催化下生成目标产物2-羟基-3-烯丙氧基丙磺酸钠。

However,aryl arenesulfonates and mesylates are attracting more interesting.

近年来,芳基磺酸酯和甲磺酸酯参与的交叉偶联反应日益受到关注。

Students should grasp the classification of the nitration reactions and its industrial application, the main nitration reagents and the nitration method, the classification of the sulfonation reactions, the function of sulfo group and its in the industrial application, sulfonating agents and its industrial application, the separation method for the sulfonated compounds, the widespread applicationof diazonium and the coupled reactions and its in the industry specially employed in the dyes and the pigments synthesis

掌握硝化反应的分类及其在工业上的应用。掌握主要的硝化试剂和硝化方法。掌握磺化反应得分类、磺酸基的作用及其在工业上的应用。掌握磺化剂其在工业上的应用。了解磺化物得分离方法。掌握重氮化及偶合反应及其在工业上特别是在染料和颜料合成中的广泛应用。

A series of 2-oxocyclododecyl sulfonylurea s have been synthesized from 2-oxocyclododecylsulfonamide via acylation of phenyl chloroformate and amination.

以环十二酮为起始原料,经磺化反应制备得到2-氧代环十二烷基磺酸盐B,B经过氯化和胺解反应制备得到2-氧代环十二烷基磺酰胺C,C经过苯氧酰化与胺解反应后合成了10个新的2-氧代环十二烷基磺酰脲类化合物D,它们的结构通过了1HNMR和IR的确证。

The stable or unstable state of the montmorillonite-water dispersion is mainly effected by the properties of montmorillonite, water, and stabilizers as well as their interactions, while the type, the structure, the properties and the concentration of the stabilizer play dominate roles. Based on the molecular designing clues, this research selected three sulfonated copolymers as the stabilizers, i.e. the sodium 2-acrylamido-2-methyl-1propane sulfonate /acrylamide /disodium itaconate terpolymer, the AMPS/AM/N-vinyl pyrrolidone terpolymer and the sodium styrenesulfonate /IA copolymer. The preparation and characterization of the sulfonated copolymers were discussed, the high-temperature stability of the montmorillonitewater dispersion was characterized with the rheology, the filtration, the particle size distribution, the electrostatic properties, and the adorption of the sulfonated copolymers onto montmorillonite particles. At the same time, a systematic mechanism of the hightemperature stabilization of the dispersion was presented.

本文构筑了分子设计的思路,选取AMPS(2-丙烯酰胺基-2-甲基丙磺酸钠)/AM/IA三元共聚物、AMPS/AM/NVP三元共聚物和SSA/IA二元共聚物等三种磺化共聚物作为蒙脱土-水分散体系的高温稳定剂,进行了磺化共聚物稳定剂的制备与表征;从流变学、滤失性能、粒度分布、电性质以及磺化共聚物在蒙脱土上的吸附作用等方面,对蒙脱土-水分散体系的高温稳定性进行了研究,考察了蒙脱土-水分散体系的高温稳定性能,同时提出了高温稳定机理。

The superplasticizer CS-SP1 is completely different from traditional formaldehyde or lignosulphonate based water-reducing admixtures. CS-SP1 is a new kind of high performance polycarboxylate water-reducing admixture without any formaldehyde.

超塑化剂CS-SP1与传统的由甲醛、萘磺酸缩聚而成的萘系和木质素磺酸盐减水剂是完全不同的,是一种新的完全不含甲醛的高性能聚羧酸系高效减水剂。

The superplasticizer CS-SX1 is completely different from traditional formaldehyde or lignosulphonate based water-reducing admixtures. CS-SX1 is a new kind of high performance polycarboxylate water-reducing admixture without any formaldehyde.

超塑化剂CS-SX1与传统的由甲醛、萘磺酸缩聚而成的萘系和木质素磺酸盐减水剂是完全不同的,是一种新的完全不含甲醛的高性能聚羧酸系高效减水剂。

The company specializes in products four series of 30 species, including : a new generation of products mainly polycarboxylic acid salt water reducer, Sulphamate superplasticizer, aliphatic sulfonates superplasticizer, composite efficient, retarding and bleed air, Gao Qiang superplasticizers and pumping agent series of concrete products superplasticizer series.

公司主要产品有四大系列三┼余种,其中:产品主要有新─代聚羧酸盐减水剂、氨基磺酸盐减水剂、脂肪族磺酸盐减水剂、复合高效、缓凝、引气、高强减水剂和泵送剂系列产品为主的混凝土减水剂系列。

The adsorption behaviour of chemically different superplasticizers, such as melamine formaldehyde sulphite polycondensate,β-naphthalene sulfonate formaldehyde polycondensate and polycarboxylate, on early hydrating cement phases was studied. For this purpose, pure ettringite AF(subscript t, monosulfate AF(subscript m and syngenite were prepared. The adsorbed amount and zeta potential of early hydration products were measured.

制备了钙矾石AF(下标 t、单硫型硫铝酸钙AF(下标 m和钾长石类单矿物,并研究了三聚氰胺磺酸盐甲醛缩聚物、β-萘磺酸盐甲醛缩合物及聚发酸盐等几种化学成分不同的超塑化剂在其早期水化颗粒表面上的吸附行为。

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