磺酰基

Some new α,β-unsaturated sulfones were prepared by condensation of 4-nitrophenylsulfonylacetates with aromatic aldehydes in cyclohexane/CH_3CH_2OH in the presence of catalytic amounts of piperidine.

不饱和砜是以对硝基苯磺酰基乙酸酯为原料与芳香醛在六氢吡啶醋酸盐催化下发生缩合反应制得的。

We introduced the sulfonyl group to P-amino alcohols derived from amino acids to prepare β-sulfonamide alcohols.

由于磺酰基的强吸电子作用，磺酰氨基不是作为给电子基团出现，而是和金属钛共同作为Lewis酸对反应起作用的。

In the second part,we alternated amines to sulfonamides under the same reaction system and found that N-sulfonyl aldimine was formed.

在同样的条件下，使用磺酰胺替代普通胺，反应会生成N-磺酰基亚胺。

New sulfonyloxadiazolones have the formula, in which A stands for hydrogen, sulphur,-SO-,-SO2- or a group, in which R stands for hydrogen or alkyl; R stands for optionally substituted cycloalkyl, cycloalkenyl or aryl; and R stands for optionally substituted alkyl, alkenyl, dialkylamino or aryl.

本发明涉及式新的磺酰基__二唑酮，其中，A代表氧、硫、－SO－、－SO 2 －或基团，其中R 3 代表氢或烷基；R 1 代表任选被取代的环烷基，任选被取代的环烯基或任选被取代的芳基；和R 2 代表任选被取代的烷基，链烯基，二烷基氨基或芳基。

The present invention relates to sulphonyloxazolamines of general formula, wherein R, R represent independently from each other H, A,-(CH2)n-Ar or alkenyl with 2-6 C atoms, R and R together also represent a mononuclear saturated heterocycle with 1-2 N, O and/or S atoms, Z is H, A, CF3, NO2, Hal, OH, OA, NH2, NHA or NA2, A represents alkyl with 1-6 C atoms, Ar is Z-monosubstituted or Z-disubstituted phenyl, halogen is F, Cl, Br or I, n is 1 or 2 or the physiologically acceptable salts or solvates thereof.

本发明涉及式磺酰基∴唑胺或其生理上可接受的盐或溶剂化物，其中R 1 ，R 2 每一个相互独立为H、A、－(CH 2 )n－Ar或具有2到6个C原子的链烯基，R 1 和R 2 也一起为具有1到2个N、O和/或S原子的单核饱和杂环，Z为H、A、CF 3 、NO 2 、卤素、OH、OA、NH 2 。NHA或NA 2 ，A为具有1到6个C原子的烷基，Ar为被Z取代的或Z二－取代的苯基，卤素为F、Cl、Br或I，n为1或2。

M-Chlorosulfonylbenzoyl chloride were prepared by the reaction of benzotrichloride with chlorosulfonic acid .

三氯甲苯和氯磺酸反应制备了间氯磺酰基苯甲酰氯。

By the nucleophilic substitution reaction of 6-O-tosyl-l,2:3,4-di-O- isopropylidene-a-Z-galactopyranose (3) with some substituted 1, 2,4- triazole-3-thiols (4a ~ 4c) or 1, 2, 3,4-tetrazole-5-thiols (5a~5f), nine 6-S-(substituted triazolyl or tetrazolyl)-l,2 : 3,4-di-O- isopropylidene-a-D-galactopyranoses (6a ~ 6i) were prepared in high yields. Their structures and configurations were analyzed and established by elemental analysis, IR, NMR, MS spectra.

报道了6－O－对甲苯磺酰基－1，2：3，4－二－O－异亚丙基－α-D吡喃型半乳糖（3）与取代的3－巯基三唑或5－巯基四唑4a-4c或5a-5f的亲核取代反应，合成了9个6－S－－1，2：3，4－二－O－异亚丙基－α- D吡喃型半乳糖（6a-6i），通过元素分析，IR，NMR和MS确证了上述化合物的结构，并经分子模型计算进行了其构象分析。

According to the results of the examination, the stronger the electron-withdrawing protective group of imines, the better the cis-selectivity of the reaction, 68% yield, trans:cis is 99:1 diastereoselectivity could be leaded by Ts-imines (4-methyl-N-methylene-benzenesulfonaides) with a substituent [2,4-(CH3O)2C6H3], Substrate scope investigation revealed that a wide variety of ketenes and imines could react smoothly to afford corresponding,β-lactams.

实验结果表明，亚胺的保护基团吸电子能力越强，越有利于顺式产物的生成。对甲苯磺酰基保护的取代基为2，4-二甲氧苯基的亚胺参与的该反应可得到68%的产率，反式：顺式=99：1的非对映选择性。底物拓展过程中发现Staudinger反应适用于多种不同的亚胺与烯酮。

Preferably, at least one member selected from among heterocyclic compounds having any of hydroxyl, carbonyl, carboxyl, amino, amido and sulfinyl and containing at least either a nitrogen or a sulfur atom is contained in the polishing solution.

优选其中包含杂环化合物，所述杂环化合物含有羟基、羰基、羧基、氨基、酰胺基和亚磺酰基中的任1种，且含有氮和硫原子中的至少1种。

The Sm or Yb complexes were tested to be used as a catalyst for the Diels-Alder reaction of cyclopentadiene with methyl acrylate.

用α-亚磺酰基-N，N-二取代乙酰胺同三氯化钐和三氯化镱反应得到了相应的稀土配合物，用元素分析、红外光谱进行了结构表征。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。