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The cis novel bisoxazoline ligands L1-L4 have been synthesized through the treatment of new cis dihydroxy diamide with p-toluenesulfonyl chloride in the presence of catalytic quantity of 4--pyridine, and the cis dihydroxy diamide could be achieved from the condensation of the amino alcohols and cis cyclopropane dicarbonyl chloride prepared via oxidation and halogenation from cis-2,2-dimethyl-3-formylcyclopropanecarboxylate with DCC.

我们以蒈醛酸内酯为起始原料,经过氧化反应、酰氯化反应得到顺式环丙烷二酰氯,然后在二环己基碳二亚胺的催化下与相应的氨基醇反应合成了顺式二羟基酰胺,再用对甲苯磺酰氯将羟基活化,最后在二甲氨基吡啶的催化下关环合成顺式双噁唑啉配体L1~L4。

After the diazotization ,2-aminophenol-4-(2-'carboxy)sulfanil phenylamine was coupled with acetoacetanilide,2-naphthol,1-phenyl-3-methyl-5-pyrazolone,1-naphthol-4-sulfonic acid,separately to get the different diazotized compounds,then complexed with potassium chromium sulfate or cobaltous chloride to obtain the yellow,orange,red,purple,blue and other colour dyestuffs.

2-氨基苯酚-4-(2'-羧基)磺酰苯胺重氮化,分别与乙酰乙酰苯胺、2—萘酚、1-苯基-3-甲基-5-吡唑啉酮、尼文酸、1-乙酰氨基-7-萘酚等偶合,得到不同的偶氮化合物,然后分别与硫酸铬或氯化钴进行络合反应,得到黄、橙、红、紫、蓝多种颜色染料,并进行了毛织品的染色实验。

With an aim to find out the difference between in vitro inhibition and in vivo inhibition of sulfonylureas, 27 compounds were selected to measure their herbicidal activities using rape root length method.

通过比较,发现磺酰脲类化合物在体内外活性有良好的相关性,进一步肯定了对靶酶AHAS的抑制是磺酰脲类除草活性的主要因素。

A mild and convenient method for the synthesis of 4(3)-substituted 3(4)-nitro-1H-pyrroles and 3-substituted 4-methyl-2-tosyl-1H-pyrroles from nitroolefins and tosylmethyl isocyanide in ionic liquid 1-butyl-3- methylimidazolium bromide was developed.

本文以离子液体-溴化1-丁基-3-甲基咪唑为溶剂,采用对甲苯磺酰基甲基异腈与硝基烯反应生成4(3)-取代-3(4)-硝基-1-氢吡咯或3-取代-4-甲基-2-对甲苯磺酰基-1-氢吡咯。

Starting from tetrafuran, 2_(4_Aminosulfonylphenyl)_4H_1,2_thiazine_1_dioxide, an antiepileptic drug with special structure, was obtained via esterification, sulphonation, chloridization, condensation and cyclization.

以四氢呋喃为原料,经酯化、磺化、酰氯化、缩合、环化等步骤,合成了化学名为 4_(四氢_2H_1,2_噻嗪基_2 )苯磺酰胺_S_S_二氧化物的抗癫痫药舒噻嗪,通过IR、1HNMR和元素分析对其结构进行了表

Synthesis of the antiepileptic tiagabine hydrochloride;2. Starting from tetrafuran, 2_(4_Aminosulfonylphenyl)_4H_1,2_thiazine_1_dioxide, an antiepileptic drug with special structure, was obtained via esterification, sulphonation, chloridization, condensation and cyclization.

以四氢呋喃为原料,经酯化、磺化、酰氯化、缩合、环化等步骤,合成了化学名为 4_(四氢_2H_1,2_噻嗪基_2 )苯磺酰胺_S_S_二氧化物的抗癫痫药舒噻嗪,通过IR、1HNMR和元素分析对其结构进行了表

Comparable experiments employing p-toluenesulfonyl azide demonstrated thereaction specialty of fluoroalkamesulfonyl azides.

在同其碳氢类似物如对甲苯磺酰叠氮的对比实验中,还进一步证明了氟烷基磺酰叠氮的反应特殊性。

The application of perfluoroalkanesulfinyl chlorides and chiral perfluoroalkanesulfinamines in organic synthesis was studied in this dissertation.

中文摘要本论文对全氟烷基亚磺酰氯在含氟化合物合成中的应用进行了研究,并对它的衍生物手性全氟烷基亚磺酰胺的制备和应用进行了初步探索。

Resolution of-1,-2,-3 and-1,-2,-3 were performed via their corresponding camphorsulfonates of the racemates.

得到这些双山黄皮咔唑后,我们用D--樟脑磺酰酯为拆分手性源,成功将各消旋体的樟脑磺酰酯在硅胶柱上进行了手性分离,首次获得手性的双山黄皮咔唑-1,-1,-2,-2,-3,-3。

The Research about the Synthesis of Phenylsulfonyl α,β-unsaturated Ketones and Their Applications in Asymmetric Diels-Alder Reaction Catalyzed by Lewis Acid and Chiral Titanium Reagents.

磺酰基取代的α,β-不饱和酮的合成及其在不对称催化Diels-Alder反应中的研究中文名称:苯磺酰基取代的α,β-不饱和酮的合成及其在不对称催化Diels-Alder反应中的研究

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推荐网络例句

They weren't aggressive, but I yelled and threw a rock in their direction to get them off the trail and away from me, just in case.

他们没有侵略性,但我大喊,并在他们的方向扔石头让他们过的线索,远离我,以防万一。

In slot 2 in your bag put wrapping paper, quantity does not matter in this case.

在你的书包里槽2把包装纸、数量无关紧要。

Store this product in a sealed, lightproof, dry and cool place.

密封,遮光,置阴凉干燥处。