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The hydrophobically associating interactions of the copolymer PASA with acrylamide, styrene derivative and sodium-2-acrylarnido-2-methylpropane sulphonate in aqueous solution were studied by flourescent probe.

通过荧光探针研究了丙烯酰胺-苯乙烯衍生物-2-甲基-2-丙烯酰胺基丙磺酸钠共聚物在溶液中的疏水缔合作用。

The invention discloses a method for synthesizing acetyl tributyl citrate, which uses tributyl citrate and acetic anhydride as reaction articles, uses naphthalenesulfonic acid methylal as the catalyst during the ester synthesis process, filtering the catalyst from reacted articles after reaction, water-washing, alkaline-washing, distilling the filtrate to obatin acetyl tributyl citrate.

本发明公开了一种合成乙酰柠檬酸三丁酯的方法,它以柠檬酸三丁酯、乙酸酐为反应物,在酯合成过程中用萘磺酸甲缩醛作催化剂,反应结束后,将催化剂从反应后的物料中过滤出来,滤液经水洗、碱洗、蒸馏获得乙酰柠檬酸三丁酯。

Cytotoxic effect was demonstrated with nitrogen mustard, nitromin, sarcolysin, thio-TEPA and myleran at concentrations of 7, 10, 25, 35, 100, and 100μg/ml respectively.

氮芥及氧化氮芥在7—10微克/毫升,溶肉瘤素和新恩必恨于25—35微克/毫升,三乙酰硫代磷酰胺和丁二醇二甲磺酸酯在100微克/毫升,都出現了显著的細胞毒作用,使細胞很快死亡溶解;但6-巯基嘌吟和氨基喋吟未表現作用。

The new surfactant was synthesized from the main starting materials such as lauric acid, p-cresol, chlorosulphonic acid and ethylene diamine, by 5 classic reactions which are acyl chlorination, esterification, Fries rearrangement, sulfonation and condensation, with total yield of 58%.

作者以十二酸、对甲酚、氯磺酸、乙二胺等为主要原料,共采取了酰氯化、酯化、Fries重排、磺化和缩合等5步经典的单元反应,合成了该表面活性剂,总收率为58%,并探讨了各步反应的条件对收率的影响。

At first, Polyaniline was synthesized by the improved chemical oxidation technique, then, PANI/HCl, PANI/TSA and PANI/DBSA were obtained by doping emeraldine with HCl, 4-methyl benzene sulfonic acid and dodecylbenzene sulfonate acid, separately. Leucoemeraldine was obtained in the N-dimethylformamide by using phenylhydrazine deoxidizing emeraldine in N_2 atmosphere.

本文首先通过改进合成条件的化学氧化法合成了聚苯胺,经氨水脱掺杂获得本征态聚苯胺,再经盐酸、对甲苯磺酸、和十二烷基苯磺酸掺杂,分别获得到质子酸掺杂的聚苯胺样品,然后在N,N-二甲基甲酰胺中,利用苯肼,在N_2氛围下还原本征态聚苯胺得到还原态的聚苯胺。

In order to study the mechanism of the biotype of Galium aparine resistant to tribenuron-methyl, the differences on ALS, GSTs, SOD and POD of the resistant and susceptible biotypes to tribenuron-methyl were preliminarily determined.

为探讨猪殃殃Galium aparine抗药性生物型对苯磺隆的抗性机制,测定了苯磺隆对猪殃殃抗性、敏感生物型体内靶标酶[乙酰乳酸合成酶]、代谢酶[谷胱甘肽-S-转移酶]及抗氧化酶影响的差异。

In order to test heat-resistance of the graft copolymerization of sulphonate onto LV-PAC, the optimal reaction conditions of the graft copolymerization of AMPS onto LV-PAC were studied by using Ce(superscript 4+) as initiator.

为了探讨低粘聚阴离子纤维素接枝磺酸盐共聚物的耐温性能以Ce(上标 4+)为引发剂,研究了LV-PAC水溶液与2-丙烯酰胺-2-甲基丙烷磺酸接枝共聚反应的最适宜反应条件。

A series of ABEPS were synthesized from long chain fatty acids, benzene, polyglycol and 1, 3-propane sultone by the procedure of Friedel-Crafts acylation, Huang-Minlon reduction, Williamson and sulfonation reaction, and these compounds had never been reported in the past time.

以长链羧酸、苯、多缩乙二醇和丙烷磺内酯为初始原料,依次经Friedel-Crafts酰基化反应、Huang-Minlon还原、Blank反应、Williamson成醚以及磺化反应等过程,合成了系列未见报道的ABEPS。

In this contribution novel acid-base sulfonated poly(phthalazinone ether nitrile ketone)s membranes are introduced.The membranes are composed of SPPENKs as the acidic compounds,and polyetherimide as the basic compounds,furthermore,redissolving SPPENKs and PEI in N-methylpyrrolidone then cast directly onto clean glass substrates in dust free environment at 60℃ aiming at enhancing membrane toughness and other relative properties.

以合成的一系列不同磺化度的碘化聚芳醚腈酮为acidic聚合物,以聚芳醚酰亚胺为basic聚合物,并将其溶解在 N -甲基-2-吡咯烷酮中配成质量分数为10%的成膜液,60℃下刮制成膜,制得acid-base型磺化聚芳醚腈酮质子导电了聚合物膜。

Comb-shaped copolymer of polycarboxylate containing carboxyl,sulfonic groups(-SO3M),polyethylene glycol(-OC2H4-) was synthesized by monomers of sodium 2-acrylamido-2-methylpropane sulphonate,acrylic acid,polyethylene glycol monoester acrylate under certain conditions.

本文通过2-丙烯酰胺-2甲基丙基磺酸钠与丙烯酸、聚乙二醇单丙烯酸酯在一定条件下发生聚合反应合成含有羧基、磺酸基(—SO3M)、聚氧乙烯链(—OC2H4—)等侧链的高性能减水剂PC。

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