磷酰胺

In this thesis, a convenient and efficient synthesis of highly functionalizeddihydropyrido[2,3-d]pyrimidines via a double [5 + 1] annulation strategy startingfrom easily available α-alkenoyl-α-carbamoyl ketene--acetals 1 and cheapreagents (NH4OAc, DMF, and POCl3) has been developed.

本论文探索了一种简便有效的合成高度官能化的二氢吡啶并[2，3-d]嘧啶的方法，此方法由易得的α-乙酰基-α-氨基乙酰基二硫缩烯酮1和便宜的试剂(醋酸铵，二甲基甲酰胺和三氯氧磷)通过两步[5 + 1]加成而实现。

Results show that, by using thionyl chloride and N,N-dimethyl formamide as chlorinating reagent and dichloromethane as solvent and taking -15℃ as reaction temperature, Z-iomer crystals with pale white color and stable to temperature can be obtained with an overall yield of 70%.

以2-（2-氨基噻唑－4-基）－2-甲氧亚氨基乙酸为原料，经盐酸化、氯代等反应合成了Z-2-（2-氨基噻唑－4-基）－2-甲氧亚氨基乙酰氯盐酸盐；氯代时以用亚硫酰氯和N，N-二甲基甲酰胺的混合物代替五氯化磷作氯化剂，并考察了温度和溶剂对氯代产物中Z-异构体和E-异构体收率的影响。

In order to further understand combining characteristic of cyclohexyl methylphosphonofluoridate and isopropyl methylphosphonofluoridate and contribute more scientific data for its medical protection, the potency of inhibition of acetylcholinesterase activity induced by GF, GF+GB and the effects of reactivation by oximes pyramidoxime monohydrate(HI-6) and pyridine-2-aldoxime methylchloride(2-PAM-Cl) in rat brain were investigated with DTNB microanalysis in this study.

为进一步了解甲氟膦酸环己酯与甲氟膦酸异丙酯的联合特性，为制订医学防护措施提供更多的理论依据，用微量DTNB法对GF，GB和GF与GB混合对大鼠脑乙酰胆碱酯酶的抑制及肟类重活化剂酰胺磷定（HI-6）和氯磷定（2-PAM-Cl）的重活化作用进行了研究。

The effects and performances of dephosphorization of the common coagulant and the flocculants: the calcium salt, the molysite and the aluminum salt and polyacrylic amide were studied on the post-positioned precipitation of municipal sewage which was processed through biological treatment.

本实验以常用混凝剂及絮凝剂：钙盐、铁盐和铝盐及聚丙烯酰胺为研究对象，研究它们对经生物处理后的城市生活污水出水，进行后置沉淀除磷的性能及除磷效果。

A flame retarding and smoke suppressing agent polyphosphoric cyanamine urea was prepared with phosphoric acid,melamine and urea as the raw materials.

以磷酸、三聚氰胺、尿素为原料制备阻燃抑烟剂聚磷酰氰胺脲，然后将其应用于TDE-85#环氧树脂中，以顺丁烯二酸酐为固化剂制备了阻燃抑烟环氧树脂。

Base on the analysis, organophosphate inducible system has been established by treatment of the swimming seedling and drenching roots with organophosphate solution. This inducible system consists of model plant Arabidopsis thaliana and methamidophos, folimat or methyl parathion which are the representative types of highly toxical OPs. Meanwhile, the responses of the esterase isozymes and the total soluble proteins to OPs in Arabidopsis thaliana have been detected by Native-PAGE and SDS-PAGE.

在此基础上，采用模式植物拟南芥和甲胺磷、氧化乐果和甲基对硫磷三种极具代表性的高毒高残留有机磷农药，通过水培和灌根的方法，建立了有机磷诱导系统，并应用变性与非变性聚丙烯酰胺凝胶电泳技术，研究了拟南芥酯酶同功酶和可溶性总蛋白对有机磷胁迫的响应。

In a pot experiment with spring wheat and buckwheat as test crops and with thiophosphric triamide and dicyandiamide as test inhibitors, the transformation, regulation and residual effect of 〓N-labelled urea were studied.

采用〓N标记的尿素，以N-丁基硫代磷酰三胺和双氰胺为供试抑制剂，春小麦和荞麦分别为供试作物进行尿素N转化的调节及其残效盆栽试验。

The products include antioxidants,blowing agents,organic solvents, intermediates for pesticides,drugs and dyestuffs,perfumes,water glass,silicates,molybdenum compounds,graphite series,activated carbon,plasticizers,flame retardant,heat stabilizers,food additives and chemical reagents,etc.

注册商标有&鹿牌&合成樟脑，&桃浦&牌合成樟脑副产物和其他化工产品，&金牛&牌抗氧剂，发泡剂，水合肼，二甲基乙酰胺，二甲基乙醇胺，&海球&牌硅胶系列，&飞铃&牌磷氯，双乙烯酮衍生物，磷酸酯，乙烯利等，&泉字&牌，&水晶&牌各类泡化碱系列，&上胶&牌钼类化合物，石墨类产品系列。

The effect of phosphoric amide herbicide amiprophose-methyl, which was used wildly in agriculture, on chromosome structure and protein composition of root meristems of wheat were studied by exposure to concentrations of 1-4 μmol/L. The results indicated that, as the concentration of APM increased the frequency of chromosomal structure variation increased.

利用农业上广泛使用的酰胺类除草剂甲基胺草磷，在1~4μmol/L浓度下，对野二燕1号小麦根尖分生组织细胞染色体结构变异及蛋白质组分变化进行了研究，结果发现，随着浓度升高，染色体结构变异率呈上升趋势。

With the aid of 〓P NMR examination for the process and ESI-MS/MS analysis of the derivatized products from the reaction intermediate, it is found that the corresponding phosphoryl chloride is generated after mixing the hydrogen phosphonate derivative with chlorodiisopropylamine, and they react with amino acid, amino acid methyl ester, dipeptide methyl ester or N-methyl imidazole carboxyl alkyl diamine respectively to form the desired products.

利用〓P NMR对反应过程监测以及对反应中间体衍生化后产物的ESI-MS／MS检测分析发现，氢亚磷酸二酯与氯代二异丙胺反应首先生成了磷酰氯中间产物，它继续与氨基酸、氨基酸甲酯、二肽甲酯、1-甲基咪唑-2-酰基烷基二胺等反应生成了目标产物。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。