磷化氢

This article mainly reviewed the discovery and the research course of natural phosphine ,namely,how phosphine coming into being,and whether phosphine being universal existed gas in natural environment such as in aerosphere,biosphere,hydrosphere.

磷化氢是剧毒的、十分活泼的无色气体，具有强的还原性，在光照、空气等作用下，极易转化为磷的其它形态。

The phosphine and arsine absorb the ultraviolet light much more strongly than does silane, causing them to be deposited out on the walls of the container.

磷化氢和砷化三氢对紫外光的吸收比硅烷强烈得多，因此，它们就沉积在容器的器壁上。

The results indicated that the magnitude of the activity of catalase in red flour beetle has positive correlation with the resistance level to phosphine, and the resistance to phosphine of the insect may be associated with the activity increase of catalase.

结果表明赤拟谷盗虫体内过氧氢酶的活性大小与其对磷化氢的抗性水平高低呈正相关，害虫对磷化氢的抗性可能与过氧化氢酶的活性增加有关。

The specific activity of catalase in resistant and susceptible strains of red flour beetle, Tribolium castaneum, was mensurated, wherein distinct difference in the resistance to phosphine existed among the four strains.

比较研究了3个对磷化氢抗性有明显差异的赤拟谷盗Tribolium castaneum品系与敏感品系虫体内过氧氢酶的比活力。

Phosphine(PH3)is an important electronic specific gas which is mainly used in fields of N-type semiconductor doping,ion implement and chemical vapor deposition etc.

磷化氢在电子工业中主要用作外延硅半导体的一种n型掺杂剂，在化学气相沉积和离子注入中被用作一种磷源，在发光二极管用磷砷化镓膜的生产中也占有重要地位。

So, eutrophication lake water may be one source of phosphine taking part in phosphorus circulation.

结果表明：富营养湖泊水体是磷化氢参与磷的生物地球化学循环的一个汇。

Therefore, it is of great significance to make thorough study on its distribution characters in marine sediments and the transforming mechanism of phosphine so that evidences would be provided for its function in the phosphorus biogeochemical recycle.

开展磷化氢在海洋沉积物中的分布特征、磷化氢与其他形态磷化物之间的转化机制的研究，对于弄清磷化氢在磷的生物地球化学循环中的作用和地位具有重要的科学意义。

The experts also simulated the phenomenon of natural fire in Luo Maozai's home: the phosphoreted mineral was decomposed into the gas of phosphoreted hydrogen under the condition of bacteria. The gas of phosphoreted hydrogen burns spontaneously under given conditions of moist air and then ignites the methane in the air which comes from the mouse holes.

专家组成功地模拟了罗家的&自燃&现象：含磷的矿物质在有细菌和具备还原性条件下分解成磷化氢气体，而磷化氢气体在一定潮湿的空气环境下自燃，继而引发空气中通过老鼠洞挥发出来的甲烷体燃烧。

Work 工作:(1) feasible process development for high-pure tetraalkyphosphonium salt as catalysts for polymerizations, potential sale 2-4 million us$;(2) simple and feasible preparation process for phosphonium salt as ionic liquids, biocides and phase transfer catalysts;(3) new and industrially feasible processes for highly sterically hindered alkylphosphines as catalyst ligands, these include tricyclohexyl-phosphine, phosphorinanes and dsmphos2,3- bis(9-phosphabicyclononylbutane;(4) sterically hindered dialkylphosphinic acid as new generation of co/ni extractant;(5) alkylphosphonium wittig reagents and the wittig reactions with them;(6) exploration of the application of borane chemistry in the synthesis of highly sterocally hindered organophosphines;(7) customer preparation of samples of a variety of organophosphorus compounds for customers all over the world.

用作高分子聚合反应催化剂的高纯度四烷基瞵盐的实用生产流程。产品销售前景 2-4 百万美元；(2)用作离子化液体，杀菌剂和相转移催化剂的烷基瞵盐的简单实用合成方法；(3)高位阻烷基磷化氢催化剂配体的工业实用合成路线的研究，这包括，三环己烷基磷， phosphorinanes 和 dsmphos 2，3-bis(9-phosphabicyclononylbutane ；(4)高位阻二烷基膦酸金属萃取剂的工业实用合成路线的研究；(5)烷基膦 wittig 反应试剂的研究；(6)硼化学在高位阻烷基磷化氢合成中的应用；(7)为世界各地提供顾客合成服务。

At the same the fumigating residue with large amount of phosphor is difficult to deal with and endangers people so it must be embedded under earth. It not only pollutes the earth and water, but also wastes lots of aluminas.

本论文根据磷化氢水解反应和粮食储备库环流熏蒸的特点，在已有磷化氢高效发生技术的基础之上，系统研究了磷化氢发生反应的最佳工艺条件。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。