磷化

Chloro-5,12-naphthacenequinone was synthesized from 2-(1-hydroxy-2-naphthyl)carbonylbenzoic acid by chlorination reaction using a mixture of phosphorus pentachloride and phosphorus oxychloride as a chlorating agent and then by ring-closing reaction using sulfuric acid as a dehydrating agent.

以2-[(1-羟基-2-萘基)羰基]苯甲酸为原料、五氯化磷/三氯氧磷为氯化剂进行氯化反应，然后用浓硫酸脱水环化，合成了6-氯-5，12-萘并萘醌，优化了反应条件，总收率达68.2%。

A process of preparing phosphorus pentafluoride was put forward: first, mesneproduct was prepared from phosphorus pentoxide and anhydrous hydrogen fluoride; second, phosphorus pentafluoride was acquired after dealing with the hexafluorophosphoric acid.

本文以五氧化二磷和无水氟化氢为原料，首先制备中间产物六氟磷酸，再通过对六氟磷酸进行处理以生产五氟化磷。

Mainly engaged in sodium azide, barium azide, three phosphorus nitride Friday, phenyl isothiocyanate, 1 - phenyl -5 - mercapto-tetrazole, 4 - dimethylamino-pyridine, 2 - mercapto--5 -- methyl-1,3,4 thiadiazole, N-hydroxy phthalimide, anhydrous betaine and betaine hydrochloride, such as fine chemical raw materials and medicine, pesticide intermediates of the development, production and sales.

主要从事叠氮化钠，叠氮化钡，五氮化三磷，异硫氰酸苯酯，1-苯基-5-巯基四氮唑，4-二甲氨基吡啶，2-巯基-5-甲基-1，3，4噻二唑，N-羟基邻苯二甲酰亚胺，无水甜菜碱及甜菜碱盐酸盐等精细化工原料及医药、农药中间体的开发、生产和销售。

The bromo-polyethylenegylcol-monomethacrylate was synthesized by two steps. Firstly, methylacrylic acid was esterified with polyethylene glycol (PEG, M=200, 400) to give polyethyleneglycol-monomethacrylate Secondly, treatment of PEG-MA with phosphorus tribromide gave the aim product.

以聚乙二醉（M分别为200，400）和甲基丙烯酸进行单酯化反应，所得单酯再与三溴化磷进行溴化反应合成了一种新的两端具有功能团的不饱和溴化物，即溴代甲基丙烯酸单聚乙二醇酯。

Pentanediol reacted with phosphorus tribromide to make it mono-bromination, under the catalytic action of PPTs it reacted with 2,3-dihydropyran to protect another hydroxy group, then to react with triphosphine, produced quarterphossal.

再以1，5-戊二醇为原料，三溴化磷使之单溴代，得到5-溴-1-戊醇，在对甲苯磺酸吡啶盐的催化下与2，3-二氢吡喃反应保护其另一端的羟基，与三苯基膦反应生成季磷盐。

The phosphorus oxychloride or phosphorus tribromide N, N-dimethylformamide mix and react to form the Vilsmeier reagent used in the reaction. The newly prepared Vilsmeier reagent is added into the reaction bottle provided with the return condenser and the blender; a reaction raw material N, N-dimethylformamide solution expressed in the reaction formula is added into the system; the temperature is risen; the corresponding multi substituting pyridine-2 (1 H)-ketone compound can be made after the column chromatography of the silica gel; the production rate is between 60 and 95 percent according to different reactions.

由三氯氧磷或三溴化磷N，N-二甲基甲酰胺混合获得反应中所用Vilsmeier试剂；将新配制的Vilsmeier试剂加入装有回流冷凝管、搅拌器的反应瓶中，向体系中加入反应通式中表示的一种反应原料的N，N-二甲基甲酰胺溶液，升温，经硅胶柱层析分离得相应的多取代吡啶-2(1H)-酮类化合物，产率视不同反应在60~95％之间。

The compound 3, 9-bis (2＇, 4＇, 6＇-tribromophoxy)-2, 4, 8, 10-traoxa -3, 9-dip- hosphospiro [5.5] undecane -3, 9-dioxide (HFR-1) was prepared with pentaeryth- ritol, phosphorus oxychloride and 2, 4, 6-tribromophenoxy soldium by esterifica- tion and condensation reaction.

以三溴苯酚钠、三氯氧磷、季戊四醇为原料，通过酯化和缩合两步反应合成了阻燃剂3，9-双(2'，4'，6'三溴苯氧基)-2，4，8，10-四氧代-3，9-二磷螺环-3，9-二氧[5.5]十一烷。

This is believed to be conneeted with the depletion of Mo, a scavenger of P, in matrix due to the Mo tithed carbides formation during preaging. Therefore, more P is released and segregated to grain boundaries. Carbide coarsening perhaps contributed to the increment in transition temperature too.

Mo可抑制磷的偏析，但因时效过程中富Mo碳化物的生成和长大，使基体中Mo的含量降低，因此，磷从Mo的&束缚&下&解放&出来并偏析到晶界，使脆性转变温度升高，此外，碳化物的粗化也可能导致脆性转变温度升高。

It is well known that the gettering dwell time of rapid thermal phosphorous gettering is too shorter to dissolved impurities and precipitate of transitional metals in the silicon matrix and diffused to the gettering sites.

恒温磷扩散对于在中、低温(低于900℃以下)时铁的沾污有明显的吸杂作用，可以很好的恢复和提高材料的电学性能，特别在磷扩散吸杂后再结合进行氢钝化处理可大大的改善材料性能。

The paper introduces one kind of new chemical removing phosphorus technology named fixed active lanthanum oxide chemical-adsorption phosphorus based on the above summary.

在此基础上，提出了一种新的化学除磷技术—固定化活性氧化镧的化学—吸附除磷技术。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新