碳酸盐

The current study and C and O isotope evolution are consistent with the previous research results, which provides isotopic evidence supporting the existence of an aulacogen basin alone, and furthermore are highly concordant with the C and O isotope evolutions in Belt Supergroup in North America and MidRiphean in Ural, Russia, which suggests a response to a global paleoocean geochemical setting.

研究区与天津蓟县和北京十三陵地区的中、新元古代碳酸盐岩碳、氧同位素组成与演化表现出明显的相似性，反映了它们共同受燕山裂陷槽发育的控制；同时，与北美Belt超群和俄罗斯乌拉尔里菲期碳酸盐岩碳、氧同位素组成、演变的高度协同性，又说明了中、新元古代碳酸盐岩中碳、氧同位素组成、演化响应于全球古海洋背景和地球化学条件。

The apply of theory and technology of fluid unit in clastic rock to karsted carbonate reservoir , theoretical concept of "fracture and vug unit" is first suggested , the integrated scheme of fluid unit characteristics in karsted carbonate is performed utilize the combination of development geology ,reservoir engineering with seismic data .which provides a new way for detailed description of karsted carbonate reservoir .

运用碎屑岩储层流动单元的理论和技术，以岩溶缝洞型碳酸盐岩储层为研究对象，首次提出了"缝洞单元"的概念，提出和建立了一套缝洞型碳酸盐岩储层流动单元的开发地质、油藏工程和地震资料相结合的综合研究思路及方法，为缝洞型碳酸盐岩储层的精细描述提供了新的思路。

In order to clearly recognize the geophysical response of carbonate reservoir,based on preliminary recognition of Ordovician carbonate reservoir under the basal surface in Tahe oilfield,some regular vug models and random arranged vug models were designed and built. The variable-grid finite difference method was used to simulate the seismic wave propagation in these models. Then,the seismic records of the models were analyzed and the effect to seismic reflections caused by vug is studied. The impact rule of regular vug scale and random arranged vug density on seismic attributes was obtained.

为了研究碳酸盐岩储层的地球物理响应特征，在对塔河油田奥陶系风化面下碳酸盐岩储层初步认识的基础上，利用随机介质建模技术，设计并建立了一系列碳酸盐岩储层规则孔洞和随机孔洞模型，并应用变网格有限差分法对地震波在孔洞模型中的传播进行了正演计算，对模拟得到的地震属性进行了分析，研究了孔洞对地震反射特征的影响，获得了规则孔洞尺度以及随机排列孔洞密度对地震属性的影响规律。

The geology research of carbonate reservoirs in Ordovician of Tahe oilfield showed that many large dissolved vugs and fractures were developed. The spread of the reservoir take on a very heterogeneous state. And the typical fractured-vuggy reservoirs was formed. According to the combination of the various spaces, the formation was divided into vuggy formation, fractured-vuggy formation and fractured formation. The research showed that development of the vug is relevant to the its position on the structure, the fractures, the water surface and the weathering surface. Multi-phase charge and recharge of the oil in the reservoirs resulted in the complexity of the fluid distribution. So the"Bottle Model"was brought forward to explain the movement of the water-oil contact. The special storage space and the complex fluid distribution lead to the unstability of the production and the complexity of the water cut. In order to explain the characteristic of the fracture-vug unit was brought forward and the basic principle and method of the partition of the fracture-vug unit was formed. The classification and evaluation of the units were performed according the reserve and energy. Based on the research of geology characteristic and the fluid flow in the reservoir the comprehensive numerical simulation plan of the fractured-vuggy reservoirs were established. Through the selection of the simulation unit, fluid flow type and parameter equivalent the triple media reservoir simulation model was established. Considering the practical application the model was resolved by the DKR decomposition conjugate grads method. Based on the fine reservoir description of Dsitrict IV of the Tahe oilfield the various space type were classified and combined together. The geology model of Unit S48 was constructed. Two typical single well model was established according to the geology and the dynamic phenomena. Finally the single well model and the Unit S48 were simulated by the triple media reservoir simulator. Via the local grid refinement and coarsening in the simulation good matchs were gained. Based on the results of the simulation the reserve distribution, percent of reserve produced in various space and the natural energy were analyzed. The fluid was storaged in the fractures and vugs mostly and more than 90% the produced oil came from the systems. The energy belonged to the active one. The results of simulation accorded with the fact and showed the validity and practicability the research and the simulator.

塔河油田奥陶系碳酸盐岩油藏的地质研究表明，其储层中发育着很多大型的溶蚀洞、缝，储层的平面展布呈现出极度的非均质性，形成了典型的缝洞型碳酸盐岩油藏，根据各种孔隙介质在储层中的组合，将储层分为了溶洞型、裂缝-溶洞型和裂缝型三类；研究表明溶洞储层的发育和构造位置、裂缝的发育、潜水面和风化面的位置等因素有关；多期充注的油气成藏模式导致了流体复杂的赋存状态，由此提出了所谓的"瓶子模型"，解释生产过程中油水界面的变化；特殊的储集空间类型和流体分布特征导致油田在开发过程中表现出很大的不确定性和含水变化的复杂性，为了合理的解释油气田开发过程中的动态特征，提出了"缝洞单元"的概念，并制定了"缝洞单元"纵横向划分的基本原则和依据及划分方法，并对"缝洞单元"进行了分类和评价；基于地质特征和流体在其中流动规律的研究，提出了缝洞型碳酸盐岩油藏的数值模拟综合解决方案，通过模拟单元的选择、流动类型和参数的等效，建立了三重介质油藏三维三相数值模拟模型，采用不完全LU分解预处理共轭梯度法进行了求解；在塔河油田4区精细油藏描述的基础上，将各种类型的孔隙空间进行了归类组合，建立了S48单元的地质模型；通过对油井生产动态进行分析研究，建立了两类和油井地质、生产动态相对应的单井模型；最后应用三重介质油藏数值模拟软件对单井模型和S48单元进行了数值模拟，通过局部加密和粗化等技术模拟流体流动规律，取得了很好的拟合效果；结合数值模拟结果，分析了各种介质中的储量分布、储量产出的百分比以及地层的能量，认为塔河油田缝洞型油藏中流体绝大多数储集于缝洞系统之中，所产出流体90%以上也来自于缝洞系统，其底水能量属于较充足的类型；模拟结果和油田实际情况符合较好，说明了地质研究和油藏数值模拟研究的正确性。

The marine carbonate near the unconformity was mainly reconstructed by strong atmogenic freshwater during the Indo-China and Yanshan Movement, being better reservoir. The reconstructed records behave as following: the ratio for 87Sr/86Sr in the different carbonate minerals or structural components is higher than carbonate matrix, while the δ13C and δ18O value in mass of samples in the different carbonate minerals or structural components are lower than carbonate matrix.

在不整合面附近的海相碳酸盐岩主要受到印支、燕山再曝露期古喀斯特作用强烈的大气淡水的改造而形成良好的岩溶储层，这种改造作用的记录表现在各种洞或脉中的碳酸盐矿物的87Sr/86Sr比值显著高于基质碳酸盐，而大多数样品的δ13C和δ18O值则显著低于基质。

Three main methods with lacustrine carbonates have been used to reconstruct the lake water palaeo-temperature at present. First, the technique of isotopic geological thermometer, since being put forward to reconstruct sea-water paleo-temperature, was subsequently introduced into lacustrine carbonate sediments for constructing lake-water based upon the function relationship between lake-water temperature and the oxygen isotopic compositions of lacustrine carbonate and lake-water. Second, paleo-temperature of the lake-water can be reconstructed by determining Mg/Ca values of the lacustrine ostracode shells. And third, paleo-temperature of the lake-water can be reconstructed based upon the statistic model between the oxygen isotopic composition of lacustrine carbonate and the Lake-water temperature by testing the modem hydrogeological parameters and some relevant isotopic data of the lake basin.

目前利用湖泊碳酸盐对湖泊古水温进行重建主要有三种方式，一是运用同位素地质温度计原理，利用水温与湖泊碳酸盐氧同位素值和湖水氧同位素值三者之间的函数关系，对湖泊古水温做定量研究；二是通过测定介壳[Mg(上标 2+)]/[Ca(上标 2+)]进而重建古水温；三是通过测定湖泊流域范围内现代水文气象参数及一些相关的同位素资料直接建立起湖泊自生碳酸盐氧同位素值与温度间的统计模型。

As the ferroan sparry carbonate cements were formed later and the sandstone reservoir was on the whole not subjected to any other constructive diagenesis, the development of carbonate cements must have played an apparent controlling effect on reservoir characteristics.

由于含铁碳酸盐胶结物形成时代晚而且储层未受到其他建设性成岩作用的明显改造，晚期碳酸盐胶结物含量和面孔率呈互相补偿的关系，表明了晚期碳酸盐胶结物对储层物性的破坏作用。

The geology research of carbonate reservoirs in Ordovician of Tahe oilfield showed that many large dissolved vugs and fractures were developed. The spread of the reservoir take on a very heterogeneous state. And the typical fractured-vuggy reservoirs was formed. According to the combination of the various spaces, the formation was divided into vuggy formation, fractured-vuggy formation and fractured formation. The research showed that development of the vug is relevant to the its position on the structure, the fractures, the water surface and the weathering surface. Multi-phase charge and recharge of the oil in the reservoirs resulted in the complexity of the fluid distribution. So the"Bottle Model"was brought forward to explain the movement of the water-oil contact. The special storage space and the complex fluid distribution lead to the unstability of the production and the complexity of the water cut. In order to explain the characteristic of the fracture-vug unit was brought forward and the basic principle and method of the partition of the fracture-vug unit was formed. The classification and evaluation of the units were performed according the reserve and energy. Based on the research of geology characteristic and the fluid flow in the reservoir the comprehensive numerical simulation plan of the fractured-vuggy reservoirs were established. Through the selection of the simulation unit, fluid flow type and parameter equivalent the triple media reservoir simulation model was established. Considering the practical application the model was resolved by the DKR decomposition conjugate grads method. Based on the fine reservoir description of Dsitrict IV of the Tahe oilfield the various space type were classified and combined together. The geology model of Unit S48 was constructed. Two typical single well model was established according to the geology and the dynamic phenomena. Finally the single well model and the Unit S48 were simulated by the triple media reservoir simulator. Via the local grid refinement and coarsening in the simulation good matchs were gained. Based on the results of the simulation the reserve distribution, percent of reserve produced in various space and the natural energy were analyzed. The fluid was storaged in the fractures and vugs mostly and more than 90% the produced oil came from the systems. The energy belonged to the active one. The results of simulation accorded with the fact and showed the validity and practicability the research and the simulator.

塔河油田奥陶系碳酸盐岩油藏的地质研究表明，其储层中发育着很多大型的溶蚀洞、缝，储层的平面展布呈现出极度的非均质性，形成了典型的缝洞型碳酸盐岩油藏，根据各种孔隙介质在储层中的组合，将储层分为了溶洞型、裂缝-溶洞型和裂缝型三类；研究表明溶洞储层的发育和构造位置、裂缝的发育、潜水面和风化面的位置等因素有关；多期充注的油气成藏模式导致了流体复杂的赋存状态，由此提出了所谓的&瓶子模型&，解释生产过程中油水界面的变化；特殊的储集空间类型和流体分布特征导致油田在开发过程中表现出很大的不确定性和含水变化的复杂性，为了合理的解释油气田开发过程中的动态特征，提出了&缝洞单元&的概念，并制定了&缝洞单元&纵横向划分的基本原则和依据及划分方法，并对&缝洞单元&进行了分类和评价；基于地质特征和流体在其中流动规律的研究，提出了缝洞型碳酸盐岩油藏的数值模拟综合解决方案，通过模拟单元的选择、流动类型和参数的等效，建立了三重介质油藏三维三相数值模拟模型，采用不完全LU分解预处理共轭梯度法进行了求解；在塔河油田4区精细油藏描述的基础上，将各种类型的孔隙空间进行了归类组合，建立了S48单元的地质模型；通过对油井生产动态进行分析研究，建立了两类和油井地质、生产动态相对应的单井模型；最后应用三重介质油藏数值模拟软件对单井模型和S48单元进行了数值模拟，通过局部加密和粗化等技术模拟流体流动规律，取得了很好的拟合效果；结合数值模拟结果，分析了各种介质中的储量分布、储量产出的百分比以及地层的能量，认为塔河油田缝洞型油藏中流体绝大多数储集于缝洞系统之中，所产出流体90%以上也来自于缝洞系统，其底水能量属于较充足的类型；模拟结果和油田实际情况符合较好，说明了地质研究和油藏数值模拟研究的正确性。

The sedimentary characteristics in Xuefeng area suggested that Xuefeng experienced complex vicissitudes of uplift-depression from Sinian to Cretaceous, it can be divided into five stages, including carbonate slope-shelf basin in Early Sinian-Middle Ordovician, uplifting and denuding in Late Ordovician-Late Carboniferous, carbonate platform in Permian, carbonate shelf in Early Triassic, uplift and intermountain basin in Middle Triassic-Cretaceous.

雪峰及其周缘地区的地层沉积特征则表明，震旦纪-白垩纪雪峰地区经历了复杂的隆凹变迁历程，可概括为五大阶段，分别为早震旦世-中奥陶世的碳酸盐斜坡-陆棚-盆地阶段、晚奥陶世-晚石炭世的隆起剥蚀阶段、二叠纪的碳酸盐岩台地阶段、早三叠世的碳酸盐陆棚阶段和中三叠世-白垩纪的隆起-陆相山间盆地阶段。

The results show that 42.86% topsoil samples are polluted by Cadmium, soil synthesis pollution index is moderate, Cadmium pollution degree of topsoil correlate with the environment of sampling sites. The results also show that exchangeable Cd, carbonate-bound Cd, organic-bound Cd and residual Cd are found in all soil samples except for Fe-Mn oxide-bound Cd. Furthermore, the concentration of exchangeable Cd and carbonate-bound Cd, both which have high biological validity, is high. Humus has a certain correlation with exchangeable Cd, organic-bound Cd and residual Cd, and has no obvious correlation with other chemical speciations. Any chemical speciation of Cd has no obvious correlation with pH and total Fe of soil samples. Cadmium in topsoil can be eluviated by acid solution, the quantity of Cadmium eluviated by redistilled water is little. With the rise of pH of eluviating solution, eluviated Cadmium quantity decrease. For the same soil sample, the lower pH value of eluviating solution is, the more fast the Cadmium is eluviated, and the more thequantity of Cadmium is eluviated.

研究结果表明：成都市表生土壤样中有42.86%受镉污染，镉综合污染水平达中度污染，成都市表生土壤镉污染程度与采样点周围环境表现出一定的相关性；除铁锰氧化物结合态镉在部分土壤样中未检出外，所有土壤样均含有可交换态镉、碳酸盐结合态镉、有机结合态镉、残留态镉，且生物有效性较高的可交换态镉和碳酸盐结合态镉占总镉量比例较高；成都市表生土壤中的腐殖质与可交换态镉、有机结合态镉、残留态镉有一定相关性，与碳酸盐结合态镉、铁锰氧化物结合态镉相关性不显著；各形态镉与土壤pH值和全铁的相关性均不显著；土壤中的镉可被酸溶液淋出，重蒸馏水淋出镉量十分微小；随着淋滤液pH值的升高，土壤样的镉淋出量下降，且0～5小时时段的镉淋出量占镉总淋出量比例下降，5～30小时时段的镉淋出量占镉总淋出量的比例上升，对同一土壤样而言，酸度大的淋滤液比酸度小的淋滤液淋出镉速度更快，淋出镉量更大。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。