碳酸化

The synthetic method for nickel borate acylate, a kind of rubber-steel c ord adhesion promoter, through nickelous carbonate borate and mixed carboxylic a cids was studied, and many factors influencing the synthesis of NBA were investi gate d systematically.

研究了以碳酸镍、硼酸酯和混合羧酸合成新的金属橡胶粘合促进剂硼酰化镍的新方法。系统地考察了各种因素对合成硼酰化镍的影响。

Teflubenzuron was synthesized from 2,4-difluoronitrobenzene and 2,6-dichlobenil as starting reagent through six-step reaction with the yield of 75.3%.3,5-Dichloro-2,4-difluoroaniline was synthesized by chlorination,reduction reaction from 2,4-difluoronitrobenzene,the yield was 84.5%;2,6-difluorobenzamide with the yield of 87.7% was synthesized by fluoridation and hydrolysis from 2,6-dichlobenil.

以2，4-二氟硝基苯和2，6-二氯苯腈为起始原料，经过6步反应合成伏虫隆，总收率为75.3%。以2，4-二氟硝基苯为原料，经过氯化、还原反应合成3，5-二氯-2，4-二氟苯胺，产率为84.5%；以2，6-二氯苯腈为原料，经过氟化和水解，制得2，6-二氟苯甲酰胺，产率为87.7%；将Ⅱ与二碳酸酯酰化，合成2，6-二氟苯甲酰异氰酸酯，产率为91.3%；Ⅲ与Ⅰ加成，得到杀虫剂伏虫隆，产率为95%。

The reaction of condensation-cyclization of the two prepared compounds at 100 ℃ in the presence of anhydrous potassium carbonate gave 1,4,7,10-tetrakis(p-toluenesulfonyl)-1,4,7,10-tetraazacyclododecane,with a yield of 71%.

在无水碳酸钾存在下，100℃加热使所得两种磺酰化产物缩合环化得到1，4，7，10-四-1，4，7，10-四氮杂环十二烷，产率71.0%。

Rare elements and REE are mainly enriched in gray-black trachyte and less in other rocks. In addition, schistosity, pyritization, silicification and carbonation in gray-black trachyte are contributed to enrich rare element and REE. It is suggested that alkaline rocks in Hongyang area have the characteristics of subvocanics, and alkaline rocks in Hongyang and Miaoya areas all came from upper mantle and mixed with some substances of crust. Intrusion of alkaline rocks is related to the occurrence, development and evolvement of the deep rupture zone in the areas.

稀土、稀有元素主要富集于灰黑色粗面岩中，而在其他岩石类型中相对较少，同时岩石的片理化、黄铁矿化、硅化和碳酸盐化对稀土、稀有元素有进一步的富集作用；提出了本区的碱性岩组合具有次火山岩相的特征，讨论了本区碱性岩的成因，认为其与湖北庙垭地区的碱性岩可能均来自上地幔，并不同程度地混染了大陆壳的物质成分，其形成时代与断裂构造带的发生、发展和演化基本同步。

Calculation of loss and gain of components in parentage and altered rocks during metasomatism, reveals that, in rubification and afforestation belts, the components brought in were K〓, CO〓, H〓O, and the components brought out were SiO〓, Ca〓 and Na〓, implying that the early ore-bearing hydrothermal fluids were rich in CO〓 and H〓O. SiO〓 brought out from potassic and chlorite alteration zones could serve as the main source for SiO〓 necessary in the formation of quartz veins, of silicification and of bericitization at shallow depth.

说明早期成矿流体为富含CO〓、H〓O等的碱性流体，其中钾化、绿化带中带出的SiO〓等是浅部石英脉、硅化、绢英岩化中硅质的主要来源，带出的Ca〓与成矿流体中的CO〓结合形成碳酸盐化，带出的Na〓则在浅部形成钠长石脉。

Nitro-4-methylsulfonylbenzoic acid was prepared from 4-toluene sulfonyl chloride by the reaction of Alkylation (in the condition of sodium sulfite and baking soda), Nitrification (in the condition of nitric acid and vitriol) and Oxidation reaction (in the condition of nitric acid and catalyzer).

研究了以对甲苯磺酰氯为起始原料，首先通过亚硫酸钠和碳酸氢钠的水溶液进行烷基化、其次在浓硝酸和浓硫酸加热回流的条件下峭化、最后在浓硝酸和催化剂的条件下进行氧化，3步反应合成了玉米田高效除草剂甲基磺草酮的重要中间体2-硝基－4-甲磺酰基苯甲酸。

I was founded in 2005, is a professional Chemical Industry Co., Ltd, Main BF3 acetonitrile complex, boron trifluoride diethyl ether complex, boron trifluoride DMC complex and Inorganic chemical raw materials, pharmaceutical intermediates.

我公司成立于2005年，是一家专业的化工实业有限公司，主营三氟化硼乙睛络合物、三氟化硼乙醚络合物、三氟化硼碳酸二甲酯络合物及无机化工原料、医药中间体。

Through the analysis of szaibelyite ,the manufacture method of boric acid and magnesium carbonate from szaibelyite by sulfuric acid,CO_2 and ammonia water is determined.

对硼镁矿成分进行分析，从而确定了采用硼镁矿制取硼酸联产碳酸镁工艺路线———用硫酸分解硼镁矿制取硼酸，硼酸母液经处理后加入碳化氨水制取碳酸镁。

Dimethyl carbonate was used as the methylating reagent, o-vanillin as the material and K2CO3 as the catalyzer to synthesize oV. The effect of material ratio, reaction time, reaction temperature and catalyzer dosage on its synthesis reaction was investigated.

方法］采用碳酸二甲酯作为甲基化试剂，以邻位香兰素为原料，无水碳酸钾为催化剂，合成邻藜芦醛，研究物料配比、反应时间、反应温度和催化剂量对反应的影响。

And precipitation rate of vanadium was higher than 98.5%. Five vanadium catalysts were made withγ-Al_2O_3 and the mesoporous molecular sieve MCM-41 as carrier, and were made by dipping method, intermingle process and functionalizing method respectively. The characterization of their pore size, crystal structure, specific surface area and V_2O_5 load of catalysts were studied by XRD, the adsorption /desorption of N_2 technique, Raman spectroscopy and XRF. The activities of the catalysts estimated by the synthesis of DPC with DMC and phenol.

钒催化剂的制备与表征及活性评价：是分别以γ-Al_2O_3和介孔分子筛为载体，采用浸渍法，掺杂法及官能化法制备了5种钒催化剂；分别对其进行了XRD分析、N_2吸附-脱附分析、红外光谱分析和荧光分析，对其孔径、晶型结构、比表面积和V_2O_5负载量进行了表征；以碳酸二甲酯和苯酚的酯交换合成碳酸二苯酯的典型反应为依据，对钒催化剂进行了活性评价。

Plunder melds and run with this jewel!

掠夺melds和运行与此宝石！

My dream is to be a crazy growing tree and extend at the edge between the city and the forest.

此刻，也许正是在通往天国的路上，我体验着这白色的晕旋。