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碳酸化

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A photoresist composition including a polymer is disclosed, wherein the polymer includes at least one monomer having the formula: wherein, R1 is selected from H, linear, branched or circular alkyl with 1-20 carton atoms, linear, branched or circular alkyl with 1-20 C atom, which is perfluorinated or semi-perfluorinated; and CN; R2 is alicyclic group with 5 or more carbon atoms; X is selected from methylene, aether, ester, amide and the connecting part of the carbonate; R3 is linear or branched alkylene with one or more carbon atoms or perfluorinated or semi-perfluorinated linear or branched alkylene; R4 is selected from H, CH3, CF3, CHF2, CH2F and perfluorinated or semi-perfluorinated aliphatic group; R5 is selected from the CF3, CHF2, CH2F and perfluorinated or semi-perfluorinated substituted and unsubstituted aliphatic group; n is 1 or higher integer; OR12 is OH or at least an acid unstable group selected from the tert-alkyl carbonate, tert-alkyl ester, tert-alkyl aether, acetal and ketal.

本发明公开了一种包含一种聚合物的光刻胶组合物,该聚合物包括至少一种具有下列结构的单体:其中,R 1 选自氢、具有1~20个碳原子的线形、支化或环状烷基、半氟化或全氟化的具有1~20个碳原子的线形、支化或环状烷基、以及CN;R 2 为具有5个或更多个碳原子的脂环基团;X为选自亚甲基、醚、酯、酰胺和碳酸酯的连接部分;R 3 为具有1个或多个碳原子的线形或支化亚烷基或者半氟化或全氟化的线形或支化亚烷基;R 4 选自氢、甲基(CH 3 )、三氟甲基(CF 3 )、二氟甲基(CHF 2 )、氟代甲基(CH 2 F)、以及半氟化或全氟化的脂族基团;R 5 选自三氟甲基(CF 3 )、二氟甲基(CHF 2 )、氟代甲基(CH 2 F)、以及半氟化或全氟化的取代或未取代的脂族基团;n为1或更大的整数;OR 12 为OH或者选自叔烷基碳酸酯、叔烷基酯、叔烷基醚、缩醛和缩酮的至少一种酸不稳定基团。

Field obserbation and laboratory study indicate the main type of rock alterationwere K-feldsparization, biotitization, sericitization, silication, epidotization,chloritization and carbonatization. From early to late, these alteration could dividedinto three epochs: early-stage was K-feldsparization-biotitization, middle-stage wasquartzification -sericitization, late-stage was silication, carbonatization, epidotizationand chloritization.

通过野外观察及室内研究表明,围岩蚀变类型主要有钾长石化、黑云母化、绢云母化、硅化、绿帘石化、绿泥石化和碳酸盐化,从早至晚可分为三期:早期为钾长石-黑云母化;中期为石英-绢云母化;晚期为硅化、碳酸盐化和绿泥石、绿帘石化。

The main products are: calcium sulfate / calcium nitrate / calcium carbonate / copper sulfate / chloride, copper / zinc sulfate / nitric acid zinc / zinc chloride / potassium sulfate / potassium chloride / potassium bromide / potassium aluminum sulfate / potassium dihydrogen phosphate / 2 of potassium hydrogen phosphate / sodium bromide / sodium chloride / sodium nitrate / sodium fluoride / trisodium phosphate / sodium dihydrogen phosphate / disodium hydrogen phosphate / crystallization of sodium carbonate / anhydrous sodium carbonate / aluminum sulfate / nitrate aluminum / crystallization of aluminum chloride / aluminum hydroxide / nitrate Fe / hydrobromide / oxalic acid / boric acid / citric acid / barium chloride / Azone / magnesium sulfate / magnesium nitrate / magnesium chloride / ammonium chloride / ammonium sulfate / Bifluoride ammonium / ammonium aluminum sulfate / ferrous ammonium sulfate / ammonium dihydrogen phosphate / diammonium hydrogen phosphate / bromide / tetrabutylammonium bromide / chloride, nickel / nickel nitrate / sulfate nickel / cadmium chloride / cadmium sulfate / nitrate Cadmium / Cadmium Carbonate / Strontium / strontium nitrate / sulfuric acid manganese / manganese chloride / 50% manganese nitrate solution / stannous chloride / zinc chloride, such as crystallization of the four largest packing of chemical reagents AR and CP level.

主要产品有:硫酸钙/硝酸钙/碳酸钙/硫酸铜/氯化铜/硫酸锌/硝酸锌/氯化锌/硫酸钾/氯化钾/溴化钾/硫酸铝钾/磷酸二氢钾/磷酸氢二钾/溴化钠/氯化钠/硝酸钠/氟化钠/磷酸三钠/磷酸二氢钠/磷酸氢二钠/结晶碳酸钠/无水碳酸钠/硫酸铝/硝酸铝/结晶三氯化铝/氢氧化铝/硝酸铁/氢溴酸/草酸/硼酸/柠檬酸/氯化钡/氮酮/硫酸镁/硝酸镁/氯化镁/氯化铵/硫酸铵/氟化氢铵/硫酸铝铵/硫酸亚铁铵/磷酸二氢铵/磷酸氢二铵/溴化铵/四丁基溴化铵/氯化镍/硝酸镍/硫酸镍/氯化镉/硫酸镉/硝酸镉/碳酸镉/碳酸锶/硝酸锶/硫酸锰/氯化锰/50%硝酸锰溶液/氯化亚锡/结晶四氯化锌等大包装化学试剂的AR和CP级别。

Monochloroethylene carbonate is prepared by chlorination of ethylene carbonate with sulfuryl chioride ,a solution of monochloroethylene carbonate in ethylene carbonate is reacted with triethylamine to give vinylene carbonate.A parameter design method was applied to select the optimum synthesis conditions.63.3% and 78% yields superior to the conventional for monochloroethylene carbonate and vinylene carbonate were obtained respectively,and the process was also simplified .

以碳酸乙烯酯为原料,用磺酰氯作为氯化剂生成一氯代碳酸乙烯酯,三乙胺为脱卤化剂在碳酸乙烯酯溶剂中合成碳酸亚乙烯酯,对一氯代碳酸乙烯酯和碳酸亚乙烯酯制备的工艺参数进行优化,收率分别达到63.3%和78%,均超过了传统方法,且简化了工艺,缩短了反应时间,易于工业化生产。

The target compound was synthesized from clarithromycin via hydrolyzation,acetylation,cyclic carbonatation,oxidation,decarbonatation,acylation,cyclic carbamatation and cyclization.

方法以克拉霉素为起始原料,经水解、乙酰化、环碳酸酯化、氧化、脱碳酸酯化、酰化、环氨基甲酸酯化和环合等反应合成目标化合物。

The synthetic methods of dialkyl carbonate , through ester exchange, oxidative carbonylation, decarbonylation , synthesis with carbon dioxide , have been reviewed in this article.

简述了近年来碳酸二酯合成方法的研究进展,介绍了酯交换法、氧化羰化法、脱羰基法和二氧化碳直接合成法等,并着重介绍了碳酸二甲酯、碳酸二乙酯、碳酸二苯酯合成工艺中催化剂的研究与开发情

Seven of them have not been reported.Their structures were confirmed by IR,~1HNMR,MS,and element analysis. 4.Meanwhile,the green methylation procedure of imides was developed by using dimethyl carbonate as methylation reagent.A series of imides,for example,phthalimide,3,4-dibromo-maleimide and succincide were used for substrates.The effects of DABCO(1,4-diazabicyclo [2.2.2]octane)and DBU(1,8-diazabicyclo[5.4.0]undec-7-ene)as a catalyst in this kind of reactions were investigated.2-Bromo-3-(1-methylindolyl-3-yl)-1-methyl-1H-pyrrole-2,5-dione was prepared by using dimethyl carbonate,which further expanded the use of dimethyl carbonate,as a green agent in organic synthesis.

在以硫酸二甲酯为甲基化试剂对3,4-二溴马来酰亚胺进行N-甲基化反应合成3,4-二溴-N-甲基马来酰亚胺的同时,以碳酸二甲酯为甲基化试剂,对3,4-二溴马来酰亚胺、邻苯二甲酰亚胺、琥珀酰亚胺等酰亚胺类化合物的N-甲基化反应进行了研究;考察了1,4-二氮杂双环[2.2.2]辛烷,1,8-二氮杂双环[5.4.0]十一碳-7-烯、碳酸钾和四丁基溴化铵等作为催化剂对碳酸二甲酯N-甲基化反应的反应时间和收率等的影响,并应用碳酸二甲酯为甲基化试剂,合成了N-甲基-3-溴-4-(1-甲基-吲哚-3)-马来酰亚胺。

The invention relates to a preparation method of vinylene carbonate, which comprises halogenated ethylene carbonate and dehydrohalogenation agent which are subject to contact reaction. The dehydrohalogenation agent is ammonia with a purity of not less than 99.9 percent.

一种碳酸亚乙烯酯的制备方法,该方法包括将一卤代碳酸乙烯酯与脱卤化氢剂进行接触反应,其中,所述脱卤化氢剂为纯度不低于99.9%的氨气。

Lithium perfluoroalkylphosphonate was synthesized by LiF and perfluoroalkylphosphonate acid obtained by electrochemically fluorinating chlorodiisopropylphosphine. Some properties of a kind of electrolyte that was made from dissolving the lithium perfluoroalkylphosphonate in the mixed solvent with ethylene carbonate and dimethyl carbonate mass ratio 1∶1 were investigated, such as conductivity, stability toward hydrolysis and oxidative decomposition potential, and so on.

选取氯代二异丙基膦(C6H14PCl)为原料,利用电化学氟化方法,得到全氟烷基膦酸[(C3F7)2PF3],(C3F7)2PF3与氟化锂反应得到全氟烷基膦酸锂Li[(C3F72PF4],将其溶于碳酸乙烯酯和碳酸二甲酯质量比为1∶1的混合溶剂中得到电解液,考察电解液的电导率、抗水性及氧化分解电位。

The experimental research on the carbonization precipitation of sodium aluminate solution with high content Al2O3 (170~190g/L) is carried out.

摘 要:对高浓度铝酸钠溶液碳酸化分解过程中Na2O的析出行为和产品中Na2O的存在形式进行了实验研究。

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