碳环的

Study on the Crystallization Process of Labeled GL-7-ACA Acylase CA130 Complex 7β-bromoacetyl amino cephalosporanic acid (BA-7-ACA), an analog of glutaryl-7-amino cephalosporanic acid (GL-7-ACA), can inhibit and specifically alkylate GL-7-ACA acylase (CA130) from Pseudomonas sp. 130, forming a carbon-carbon bond between BA-7-ACA and the C-2 on indole ring of Trp-β4 residue of CA130.Here we reported that BA-7-ACA labeled CA130 (BA-C130) could self-catalyze the hydrolysis of BA-7-ACA during crystallization process. The hydrolysis was confirmed to be a reaction analogous to the one of GL-7-ACA by comparative MALDI-TOF (matrix-assisted laser desorption/ionization-time of flight) spectrometry analysis.

二、GL-7-AcA酰化酶CA130标记复合物的结晶过程研究溴乙酰氨基头孢烷酸（7β-bromoacetyl amino cephalosporanic acid，BA-7-ACA）作为戊二酰-7-氨基头孢烷酸（GL-7-ACA）的类似物，不仅能够抑制GL-7-ACA酰化酶CA130的活力，而且能通过在BA-7-ACA和CA130的β亚基第四位色氨酸吲哚环二位碳原子之间形成碳-碳共价键而将CA130特异的烷基化。

In order to find the difference of the isotopic composition of different organic compounds before and after complexation, the autogamy standard sample is performed by molecular sieve adsorption to study the variation of the isotope compositions of n-alkanes, isoalkanes and cyclanes.

通过对自配标准样品进行S分子筛吸附试验，测定了用5分子筛吸附法分离前后正构烷烃、异构烷烃和环烷烃碳同位素值，探讨试验前后碳同位素值的变化。

From the structure, tetraazaparacyclophane is a ring compound with benzene rings connected by nitrogen-containing carbon bridges. It has a well-defined hydrophobic cavity.

四氮杂环蕃从结构来看是由氮杂碳桥将芳香环连起来的环状化合物，分子内具有空腔，该空腔上的芳环呈侧立状，具有一定的深度，并具有疏水性。

According to Wurtz reaction, if we can control solvothermal reactive condition to make the four C-Cl bonds in the carbon tetrachloride broken incompletely, according to the mechanism of Wurtz reaction, some kinds of free radicals or carbonium ions will be produced in solvothermal condition.

那么，如果控制反应条件，使四氯化碳等小分子碳氯化合物中的氯原子不完全脱掉，根据Wurtz反应机理，反应体系中将产生大量的碳氯自由基或碳正离子，它们在溶剂热条件下按照一定的生长规律进行组合，必将生成大量的多氯代多环芳香化合物。

Then a hexacyclic-ring system formed as a result of molecular recombination, based on which further dehydrogenation occurred.

然后经过重排又转变成了一个具有碳碳双键的六员环体系，并在此基础上进一步发生脱氢反应。

Keywords: Organozinc reagents; cis-Addition Products; Ring-expansion; Chain-extension

中文关键词：有机锌试剂；环氧的顺式开环；酮酯的扩环；碳链增长

Organozinc reagents; cis-Addition Products; Ring-expansion; Chain-extension

中文主题词：有机锌试剂；环氧的顺式开环；酮酯的扩环；碳链增长

This thesis mainly focuses on the catalytic carbon-carbon bond formation using gold catalysts.

本论文主要是在研究金属金催化剂，催化环化碳-碳键生成的反应。

Alkylbenzene, normal alkanes and alkylcyclohexane on the pyrolysates of P. Boryanum at 300℃ had uniform distribution and the relative content of them was similar, indicating that they originated from same precursors. Fatty acids, alcohol and ketone in algal cell are the possible precursors. For example, the precursor of relatively abundant C〓 alkylbenzene and alkylbenzene with C〓 side chain perhaps related with palmitic acid. N-alkylnaphthalene in pyrolysates at 300℃ probably derived from alkylation of cleavage products of aromatic steranes and terpanes.

在盘星藻300℃热解产物中，烷基苯、正烷烃和烷基环己烷碳数分布一致、各化合物的相对含量接近，表明它们有相同的来源，藻类体内的脂肪酸、醇和酮及细胞壁等物质可能是其母质，相对含量较高的碳数为16及侧链碳数为16的烷基苯类化合物，其前身物可能与软脂酸有关。300℃热解产物中的正烷基萘类化合物，可能由芳香甾、萜类的降解产物与直链烃类加成烷基化而形成。

Diels-Alder reaction has been one of the cornerstone reactions in organic chemistry for the construction of six-membered rings and the formation of carbon-carbon binds.

Diels-Alder 反应是有机化学中建构六员环和碳碳键生成最为重要的反应之一。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。