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They were eucalyptol, bicyclo[2.2.1]heptan-2-one,1,7,7-trimethyl-,(1R)-, borneol, 1-methyl-2-(1-methyl ethenyl)-(1R-cis)-cyclobutaneethanol, limonene, 1-hydroxymethyl-7,7-dimethy lbicyclo[2.2.1]heptan-2-one,-spathulenol, 3,7,11,15-Tetramethyl-2-hexadecen-1-ol, isocitronellol,-9-Octadecenoic acid, heneicosane, respectively.

阿给中共有11个阿给炭没有检测出的成分,包括桉油精、D-樟脑、冰片、(1R-cis)- 1-甲基-2-(1-甲基乙烯基)环丁基乙醇、二戊烯、1-羟甲基-7,7-二甲基-双环[2.2.1]庚-2-酮、-匙叶桉油烯醇、3,7,11,15-四甲基-2-十六碳烯-1-醇、异香茅醇、-9-十八碳烯酸和廿一烷。

Methanol molecule participates in the proton transfer process, which takes place by a intermolecular six-membered proton-transfer transition state structure instead of the intramolecular four- membered. Consequently, the activation energy of the proton-transfer process is reduced greatly,resulting in the carbon-carbon bond formation process become the rate-determining step. The results are consistent with Aggarwal's the latest dynamics experiments.

CH3OH分子参与质子转移过程,使得原本通过四元环结构过渡态的质子转移过程通过六元环结构过渡态实现,从而极大地降低了质子转移过程的活化能,碳-碳键形成过程进而成为反应的速度控制步骤,研究结果与Aggarwal等的最新动力学研究成果相吻合。

CH3OH could attack the phosphor atom in 1,3,2-dioxaphopholane of compiound (1) to give O-methyl O-hydroxyethyl-O-phthalimidoethyl thiophosphate in 85% yield; in the presence of potassium hydroxide aryl selenol could attack the carbon atom in 1,3,2-diox-aphopholane of the cyclic phospholipid conjugate of N^1-(2-furanidyl)-N^3--5-fluorouracil to give the corresponding product of ring-opening in high yields.

在室温下,以异丙醇作溶剂,苯硒酚与化合物2不反应。在氢氧化钾存在下,以异丙醇/水作溶剂(体积比20:1,在室温下,硒酚可以有效地进攻中化合物2中1,3,2-二氧磷杂环戊烷中的碳原子生成相应的开环产物。按照这一反应条件,顺利实现了硒酚对N^1-(2-呋喃基)-N^3-羟烷基-5-氟脲嘧啶硫代环甘油磷脂缀合物的亲核开环,生成甘油骨架的端碳原子上带有芳硒基新颖的磷脂核苷缀合物。

All of these products have the carbon-carbon linkage to the cyclopentadiene ring.

由^1H NMR、IR、元素分析等确认R和环戊二烯上碳直接相连,具有典型的碳碳连结。

This invention pertains to compounds of Formula I, their N-oxides and suitable salts wherein A is O or S; G is a 5- or 6-membered heteroaromatic ring or a 5- or 6-membered nonaromatic heterocyclic ring optionally including one or two ring members selected from the group consisting of C, SO or S2, each ring optionally substituted with from one to four R; each J is independently a phenyl ring, a 5- or 6-membered heteroaromatic ring or an aromatic 8-, 9- or 10-membered fused carbobicyclic or heterobicyclic ring system, wherein each ring or ring system is optionally substituted with from one to four R; and R, R, R, R and n are as defined in the disclosure.

本发明涉及式I的化合物、其N-氧化物和适当盐,其中A是O或S;G是任选地包含一个或两个独立选自C、SO或S 2 的环成员的5-或6-员杂芳环或5-或6-员非芳族杂环,各环任选地被1-4个R 2 取代;各J独立地是苯环,5-或6-员杂芳环或芳族8-,9-或10-员稠合的碳二环或杂二环系,其中各环或环系任选地被1-4个R 3 取代;R 1 ,R 2 ,R 3 ,R 4 和n如说明书中定义。

The reaction of cyclic b-keto esters with CF3CO2ZnCH2I provides the corresponding ring-expanded products with the advantage of mild condition in moderate to good yields. A simple and efficient procedure has been developed for a variety of 1,3-diketones converted into the corresponding 1,4-diketones and trans-1,2-disubstituted cyclopropanols in high yields. In conclusion, this new type of organozinc reagents has been developed for many useful reaction in organic synthesis.

利用有机锌试剂所具有的双重特性,在新型的Baylis-Hillman反应中,可以直接与炔基酮和醛反应一锅制得多官能团的三取代的顺式烯;在b-酮酯化合物的扩环反应中,取得了重要进展,得到了增加一个碳的扩环产物,&一步法&合成,反应条件温和、环境友好;在1,3-二酮分子中成功地插入1个碳,合成出1,4-二酮和环丙醇,为现代有机合成提供了新的合成方法,具有良好的应用前景。

Chiral epoxides produced by alkene epoxidation are extremely useful building blocks for asymmetric synthesis.

碳碳双键经不对称环氧化得到的光学活性环氧化物是一类重要的手性元,可以合成许多有价值的手性化合物。

Using different colors shows resistance specification. 4 color ring is generally carbon film resistors.its three-ring show resistance, with a color ring showing error. 5 color ring is generally Metal Film Resistors.Its four-ring show resistance,with other showing error.

就是在电阻器上用不同颜色的环来表示电阻的规格。4个色环一般是碳膜电阻,用3个色环来表示阻值,用1个色环表示误差。5环电阻一般是金属膜电阻,用4个色环表示阻值,另一个色环也是表示误差。

The results available now indicate that glass-like carbon synthesized from phenolic resin is a non-graphitizing carbon, and consists of both sp 2-hybridized carbon atoms that form imperfect graphite structure and sp 3-hybridized carbon atoms that are due to the presence of disordered carbon; and in the fullerene-related structure of glass-like carbon, there exist some pentagons and heptagons carbon rings.

玻璃炭作为一种特殊炭材料已广泛应用于许多领域,其制备、性质、应用以及基本结构的研究已经取得了很大的进展,已有的研究结果表明酚醛树脂基玻璃炭是一种典型的非石墨化炭材料,由 sp2杂化态碳原子和 sp3杂态碳原子组成,且在其类富勒烯结构中存在五元环和七元环。

The cyclization of carbodiimides 2 and 6 with phenol or alcohol was studied and the results showed that the cyclization of carbodiimides 2 and 6 with phenol in the presence of solid potassium at room temperature to 40℃, the cyclization of carbodiimides 2 and 6 with alcohol should in the presence of RONa.

进一步研究了碳二亚胺2和6与酚和醇的成环反应,结果表明该碳二亚胺与酚反应在碱(固体K_2CO_3)催化条件下,室温或加热到40℃便可顺利关环,与醇反应需要用到更强的碱醇钠催化才可以顺利关环。

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啊!不用提了。提到肉,真是糟透了。

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