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The invention relates to a method for making oligomeric isocyanates by reacting diisocyanates in the presence of a catalyst, wherein the catalyst comprises a saline compound prepared from an anion selected from 1,2,3- or 1,2,4-triazole, a substituted species of 1,2,3- or 1,2,4-triazole and carbocyclically and/or heterocyclically annellated species of 1,2,3- or 1,2,4-triazole and the cation selected from an alkali metal, alkaline-earth metal and/or monovalent ammonium cation and/or phosphonium cation of formula (5), wherein the E, R1, R2, R3, R4 are as defined in the descriotion.

本发明涉及一种制备低聚异氰酸酯的方法,包括二异氰酸酯在催化剂的存在下进行反应,其中所述催化剂由盐化合物组成,该盐化合物由选自1,2,3-或1,2,4-三唑、1,2,3-或1,2,4-三唑的取代系列者、1,2,4-三唑的碳环稠合系列者、1,2,3-或1,2,4-三唑的杂环稠合系列者的化合物及其混合物的阴离子和选自碱金属、碱土金属和/或通式(5)的一价铵阳离子和/或磷友衾胱拥难衾胱又票福其中E、R 1 、R 2 、R 3 和R 4 如说明书中所定义。

The hapten can be synthesized with a spacer attached at the aromatic moiety of the pyrethroid, through the middle of the molecule and at the cyclopropane moiety.

半抗原的合成入手点主要为菊酯分子的三碳环、中间和芳环部分,连接一个连接臂作为半抗原。

In this thesis, we want to describe the new one-carbon chain extension and ring expansion of 1,3-diketones, which is the first report based on our knowledge.

本文在前人的研究基础上,首次发现了开链1,3-二酮增加一个碳原子的自由基链增长反应和环状1,3-二酮增加一个碳原子的自由基扩环反应。

Which is made up of long carbon chain by N-alkylation or acylation,The surface activity is greatly enhanced because of structure of borate surfactants and the basic property of long carbon chain.

它们将长碳链通过N烷基化和酰化联接在一起的一类含硼表面活性剂,由于是含四配位硼氧杂环结构的表面活性剂和结合长碳链的基本性质从而极大的提高了表面活性。

Glucose an aldohexose, exists as D and L forms. The furthest asymmetric carbon from the aldehyde group is C-5. D-glucose is called D because the configuration of the atoms bonded to C-5 is the same as for D-gly- ceraldehyde. Similarly D-fructose﹙a ketohexose﹚ is designated D because the configuration

环状结构:醛基或酮基跟一个羟基反应共价闭合,形式上一个糖的醛基和羟基反应生成了一个半缩醛,而一个酮基与一个羟基反应生成一个半缩酮,在同一分子内这个反应能进行,单糖的开链式形成了糖环,葡萄糖环形成一个六碳环。

The Xray diffraction analysis of the compounds (3) and (4) shows the presence of an intramolecular coordination of oxygen to the tin atom giving rise to a fivemembered ring in which the metal exhibits a distorted trigonal bipyramidal geometry.

并通过X-射线衍射测定了(3)和(4)的晶体结构,其空间群均为P2〓/c,晶胞内分子数Z=4,分子结构是以锡原子为中心金属原子、含分子内O→Sn配位键五员环的扭曲三角双锥结构,碳碳双键的两个氢是顺式构型。

A method for eliminating the internal oxide structure in the gas-phase carbon-nitrogen osmosis of gear features that the CCL4 is added to the kensene as carburizer and then is decomposed to generate Cl2 for reducing the oxide, the ammonia gas as nitrizing agen passes through the cylinder of silica gel or granular calcium chloride for adsorbing residual water vapour and then through the cylinder of 5A molecular sieve for adsorbing residual O2, and the resistance wire is wound on igniting pipe at furnace top to prevent the NH4Cl in exhausted gas from being condensed.

本方法采用在气体渗碳剂煤油中,加入6~8%的CCl 4 ,使共渗炉内的CCl 4 分解出新生的Cl 2 ,使已形成的合金元素内氧化物还原;在渗碳剂氨气入共渗炉前,先经过硅胶瓶或桶及粒状氯化钙瓶或桶过滤,吸附掉氨气中的残留水蒸汽,再经过5A分子筛瓶或桶吸附掉氨气中的残留氧;在靠近炉顶位置的点火管周围缠绕带瓷环的电阻丝,靠电阻丝的副带加热,使排气中的NH 4 Cl不冷凝结块等措施实现内氧化组织的消除。

They suggested that radicals with a double bond 13 to the carbon bearing the peroxy groups (which can only arise from acids containing more than two double bonds) cyclize to form peroxides with five-membered rings.

他们认为连接过氧基的碳原子有一个双键的游离基(只有多于两个双键的酸可形成)环化形成五元环的过氧化物。

Itis main raw material of tetradecane,others applications include:liquid mosquito-repellent incense,hydraulic oil of large-scale punch,paraffin chloride,anticorrosive paint.powder paint,and top-grade melt adhesive,its derivative is chainpoly-anhydride of 14c binary acid,it is very useful chenical and medical intermediate,it can be used ad curing agent of epoxy and propylene resin,polyester improved additive etc.

外观与性状无色液体,溶解性不溶于水,可混溶于乙醇、乙醚是生产十四碳烷烃的主要原料,其它应用包括:液体蚊香、大型冲压机的液压油、氯化石蜡、防腐涂料、粉末涂料也可用作高档热熔胶,其衍生产品十四碳二元酸的直链聚酐,是一种非常有用的化工及医药中间体,可用于环氧及丙烯树脂固化剂、聚酯改性添加剂等等。

The results indicate that the difference between the Y-shaped CNT and the pristine one is remarkable due to the influence of the defects in the junctions of the former.

研究结果表明,由于缺陷环的影响,Y型碳纳米管与直型管的性质明显不同,而且,Y型碳纳米管的结构和性质与分支管长度存在一定的关系。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

The new PS20 solar power tower collected sunlight through mirrors known as "heliostats" to produce steam that is converted into electricity by a turbine in Sanlucar la Mayor, Spain, Wednesday.

聚光:照片上是建在西班牙桑路卡拉马尤城的一座新型PS20塔式太阳能电站。被称为&日光反射装置&的镜子将太阳光反射到主塔,然后用聚集的热量产生蒸汽进而通过涡轮机转化为电力