碳环的

The gasification efficiency increased and the molar fraction of H2 decreased with an increase in the reaction temperature. The decomposition of PVA was more complete at higher temperatures. At 24 MPa, 500℃ and 120 s, the TOC remove rate, the carbon gasification rate and the hydrogen gasification rate were up to 71.46%, 67.97% and 157.24% respectively. A change in the residence time had no significant effect on the molar fraction of gas production but an increase in the residence time could enhance the gasification efficiency of PVA. It was found that the intermediates were mainly alkane, cycloparaffin, aromatic hydrocarbons, and low-molecular weight acids. It was supposed that PVA was degraded into small molecules through breaking of C-C bonds. Parts of the molecules were converted into H2, CO, CH4 and CO2 while some was converted into aromatic hydrocarbons.

过程探索发现：反应温度的升高能提高PVA气化效率，但气体产物中H2的含量随反应温度的升高有所下降；随着反应温度的升高，PVA分解趋于彻底，在压力24MPa、温度500℃、停留时间120s的条件下，TOC去除率、有机碳气化率和氢气化率分别达到71.46%，67.97%和157.24%；停留时间的变化对气体产物含量没有明显的影响，但延长停留时间能提高PVA的气化效率；PVA气化反应中间产物主要为链状烷烃、环烷烃、芳香烃及小分子酸，根据中间产物出现的顺序推测PVA的降解为由C-C键断裂形成小分子物质，这些小分子物质一部分转化为H2，CO，CH4和CO2，一部分形成难降解的芳香族化合物。

In this paper,many achievements of studying on the synthesis,thermal decomposition properties and characteristics of the energetic complexes based on high-energetic compounds containing many nitrogen atoms such as carbohydrazide and 5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one as well as tetrazole,etc.

概述了以高能多氮直链化合物如碳酰肼，富氮杂环化合物如三唑、四唑类为配体的配合物的合成、热行为以及性能的研究情况，同时简要地从分子或原子结构描述了一些其他多氮含能配体如肼、肼基甲酸甲酯等所形成的配合物的晶体结构以及热分解行为，并对含能配合物的发展方向进行了展望。

Therefore, the previous data of heats of formation of polynitrocubanes estimated from groupadditivity method are corrected.3. Calculations indicate that, for polynitrocubanes, there are parallel relationships between their experimental kinetic acidities pKa, the average s characters in the exocyclic carbon orbital used for the C-H bonds within each molecule, and the average C-H stretching frequencies within each molecule.

计算结果表明，多硝基立方烷的实验动力学酸性pK_a、分子内用于形成C-H键的环外碳轨道平均s成分和分子内的平均C-H伸缩频率之间，存在平行的递变关系，这对基于s_a或v_a的数值预估动力学酸性pK_a、进而指导多硝基立方烷和其它相关化合物的合成有助。

Therefore, the previous data of heats of formation of polynitrocubanes estimated from groupadditivity method are corrected.3. Calculations indicate that, for polynitrocubanes, there are parallel relationships between their experimental kinetic acidities pKa, the average s characters in the exocyclic carbon orbital used for the C-H bonds within each molecule, and the average C-H stretching frequencies within each molecule.

计算结果表明，多硝基立方烷的实验动力学酸性pK_a、分子内用于形成C-H键的环外碳轨道平均s成分和分子内的平均C-H伸缩频率(来源：AB0eC论文网www.abclunwen.com)之间，存在平行的递变关系，这对基于s_a或v_a的数值预估动力学酸性pK_a、进而指导多硝基立方烷和其它相关化合物的合成有助。

The logarithm difference values of partition coefficients of the compounds in butyl ether/water and in cyclohexane/water system were used for the measurement of the Lewis acidity, while the logarithm difference values of partition coefficients in trichloromethane/water and in tetrachloromethane/water system were used for the measurement of the Lewis basicity, and they were used successfully to differentiate the relative strength of Lewis acidity and basicity for 59 benzene and its derivates.

以化合物在正丁醚/水和环己烷/水溶剂体系中分配系数的对数差作为酸性指数，以其在氯仿/水和四氯化碳/水溶剂体系分配系数的对数差作为碱性指数，提出了一种新的度量有机物Lewis酸碱性的方法，按此方法成功地区分了59种苯系物Lewis酸碱性的相对强弱；并成功地将上述酸碱性指数引入定量结构—性质/活性相关研究之中，探讨了苯系物的正辛醇/水分配系数、水溶解度和土壤有机碳吸附系数等常见理化性质与其Lewis酸碱性间的相关性并建立了相应的定量模型，发现它们之间存在良好的相关性。

In the course of our study the chemistry of arenes contaning allylic acetates moiety under the catalysis of palladium, we found an efficient synthesis of benzocycles via intramolecular Friedel-Crafts reaction of halogen free 6-acetoxy-4alkenyl arens.

我们在设计钯催化的碳—氢键活化时，发现了含有烯丙基醋酸酯侧链的芳烃的三氟醋酸促进的分子内的Friedel-Crafts反应，从而为有效合成苯并六元环结构提供了一个方便的方法。

The recent progress in molecular design and synthesis of polyborosilazane precurosors for SiBCN ceramics is reviewed.Especially the borazine modified polyborosilazane,monofunctional borane modified polyborosilazane on side chai...

本文分4个方面，即基于硼吖嗪的聚硼硅氮烷、侧基含有环硼氮烷或单硼烷的聚硼硅氮烷、基于多官能硼烷构筑的聚硅氮烷和含硼聚硅基碳化二亚胺，从聚硼硅氮烷分子结构设计、改性、合成及在多维尺寸材料中初步应用的角度综述了该领域国内外研究的新进展，指出了聚硼硅氮烷陶瓷前驱体设计合成研究发展中值得关注的新方向。

The conjugated macrocycle,which is built by 20 carbon atoms and 4 nitrogen atoms,prospers the whole nature and the chemical research field due to its particular property,so it has attracted more and more attention.

这种由20个碳原子和4个氮原子组成的共轭大环以其独特的魅力不光丰富了自然界也丰富了人类化学研究领域，越来越多的目光被卟啉化合物所发出的光彩所吸引，卟啉化合物也在大家的关注中得到迅速的发展和应用。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。