碳正离子

Two special structural features of the sulfonium salt were proved to stabilize its corresponding ylide and depress the 2,3-sigma rearrangement. One is that there is a trimethylsilyl in the end of the allylic double band. This silicon atom can stabilize a α-carbon anion and the corresponding ylide. Another is that there is hydroxy group in the beta-position of sulfonium atom. The oxygen of this hydroxy group may stabilize the sulfonium cation.

为了稳定生成的烯丙基硫叶立德，并抑制它的2， 3-sigma 重排反应，在硫叶立德结构上做了两方面的考虑：一是在烯丙基双键的未端引入硅基，利用硅原子对 a -碳负离子的稳定作用来稳定烯丙基硫叶立德；二是在硫原子的 b -位引入羟基，利用羟基氧对硫正离子的作用来稳定硫叶立德。

The central carbonium ion is an important center of interaction between the dye and GaP. The oxygen atom with one lone pair of electron on the GaP surface acts as the electron donor.

碱性品红分子的中央碳正离子与GaP表面具有孤对电子的氧原子形成配位键。

Study on synthesis and thermo-stability of ladderlike polymethyl/phenylsilsesquioxane

利用气相色谱技术对氟代仲丁烷的热稳定性进行了考察，并通过对氟代仲丁烷的热消除产物的定性定量分析，讨论了其热分解机理，以四圆环状过渡态历程和碳正离子重排历程对热消除反应的产物形成进行解释。

Eleven α-V-group cation-substituted toluenes (1) and acetophenones (2)were synthesized. The equilibrium acidities of these compounds were determined indimethyl sulfoxide solution by the "Overlapping Indicator Method" and the homolytic C-Hbond dissociation energies were derived from a thermodynamic cycle combining pKawith oxidation potential of carbanion.

合成了α-位有第V、Ⅵ主族元素杂正离子取代基的甲苯系列（1）和苯乙酮系列（2）共11个Ylide前体化合物，用重迭指示剂法首次测定了其在二甲亚矾溶剂中的酸性解离常数PKa，同时结合碳负离子氧化电位的测定，通过热力学循环估测了它们的气相均裂键能。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。