碳正离子

These methanols were treated with BF3 in CH2Cl2 to generate the diferrocenylmethyl carbocations. Without separation from the reaction mixture, the ions were treated with some amines RNH2 [R=C2H5, n-C3H7, n-C4H9, HOCH2CH2, HOCH(CH3)CH2, HOCH2CH(C2H5)] to afford the ferrocenylamines in high yields. The present methodology for preparing α-ferrocenylamines from α-ferrocenyl alcohols enjoys such advantages as simple procedure and inexpensive starting materials.

它们对酸的敏感性很高，与BF3在二氯甲烷中作用可形成稳定的二茂铁基甲基碳正离子，无需从溶液中分离出来，便可与胺RNH2[R=C2H5，n-C3H7，n-C4H9，HOCH2CH2，HOCH(CH3)CH2，HOCH2CH(C2H5)]作用得到产率颇高的二茂铁基胺，这种由α-二茂铁基醇制备α-二茂铁基胺的方法具有简单、快速和原料廉价的特点。

On NaZSM-5, acetylene reacts with the water adsorbed on Na^＋ sites to form vinyl alcohol bound to the cations in zeolite through static attraction, corresponding to the weakly adsorbed species.

乙炔与HZSM-5中B酸中心上的水作用形成乙烯醇，后者在升温时变为碳正离子结合在分子筛的Al-O^--Si上构成强吸附物种。

In this paper the study on optimizing the esterification of cellulose and some character of CAB(the degree of substitution of cellulose, solubility, the thermal properties and molecular weight) was discussed. The mechanism of the esterification of cellulose in butyric acid/ acetic acid/ butyric anhydride which comprises the creation of the acetic butyric anhydride, acetyl cation and butyryl cation was investigated by the study of the effect of the content of the organic acid and anhydride on the degree of acetyl and butyryl substitution of cellulose.

最后本文根据纤维素在丁酸/乙酸/丁酸酐中的酯化反应中有机酸以及酸酐的添加量对最后产物纤维素醋酸丁酸酯中乙酯或者丁酯取代度的影响，提出纤维素在丁酸/乙酸/丁酸酐中的酯化反应经历一个混和酸酐以及乙酰碳正离子、丁酰碳正离子的生成过程。

It would be expected that carbonium ions are very susceptable to nucleo-philic attack by water.

碳正离子对于水的亲核作用非常灵敏，这是意料中的事。

The central carbonium ion is an important center of interaction between the dye and GaP.

碱性品红分子的中央碳正离子与GaP表面具有孤对电子的氧原子形成配位键。

If there are five or more bonds to a single carbon atoms, it will be short of electrons and have a positive charge - this species is called a carbonium ion, a form of carbocation.

阳碳：如果有五个甚至更多的键连接在一个碳原子上，碳原子由于缺乏电子而带正电，这种物质称为阳碳，这是碳正离子的一种。

According to Wurtz reaction, if we can control solvothermal reactive condition to make the four C-Cl bonds in the carbon tetrachloride broken incompletely, according to the mechanism of Wurtz reaction, some kinds of free radicals or carbonium ions will be produced in solvothermal condition.

那么，如果控制反应条件，使四氯化碳等小分子碳氯化合物中的氯原子不完全脱掉，根据Wurtz反应机理，反应体系中将产生大量的碳氯自由基或碳正离子，它们在溶剂热条件下按照一定的生长规律进行组合，必将生成大量的多氯代多环芳香化合物。

The speed of electrophilic addition reaction of Alkene is inferenced greatly by the electron-withdrawing group or electron-releasing group on C=C of Alkene And the main addition product is decided by stability of carbonium ion.

烯烃C=C上连有供电子基和吸电子基时，对于烯烃亲电加成反应速度的影响是很大的。加成产物是由碳正离子中间体的稳定性来决定。

A positively-charged chemical species where the positive charge is localised on a carbon atom. Both carbenium ions (which have three bonds to a positively charged carbon) and carbonium ions (which may have five or more bonds to a positively charged carbon) are examples of carbocations.

碳阳离子：正电荷位于碳原子上的一种正电性的化学物种，碳正离子（三个键连接在带正电的碳上）和碳鎓离子（有五个甚至更多的键连接在正电性的碳上）都属于碳阳离子。

Type shown above, the lower temperature as allyl methyl carbocations (1) is greater than the stability of carbocations (2), so the potential energy diagram in the reaction pathway for the carbon embodied in the positive ion hybrid resonance body and Chloride Cl-if by 1,4 - addition will have to experience higher ...

如上式所示，较低温度下由于烯丙基甲基碳正离子(1)的稳定性大于碳正离子(2)，所以在反应历程势能图中体现为碳正离子共振杂化体与氯离子Cl-若按1，4-加成则要经历较高。。。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。