碳化的

THE FIRST TOTAL SYNTHESIS OF TAXAMAIRIN B Taxamairin B, representive of rare naturally-occuring rearrang-ed 9(10→20)-abeo-8, 11, 13-triene diterpenoids, has been firstsynthesized by a eleven-step route in an overall yield of 8.19%,starting from commercially available catechol and 1,3-cyclohexan-dione. The improved Friedel-Crafts annulation, thermodynamicallycontrolled-geminal pairing methylation, the selective oxidation ofallyl group and the selective reduction of the less-hindrancecarbon-carbon double bond are the key steps.

二。美丽红豆杉素B的全合成研究 1，美丽红豆杉素B的首次全合成以价廉，易得的邻苯二酚和1，3-环己二酮为原料，经过改良的Friedel-Crafts烷基化反应，热力学控制的α，β-不饱和酮结构的α一位双烷基化，烯丙位的选择性氧化，以及选择性还原位阻较小的碳碳双键等十一步反应，以8.19％的总收率首次完成了美丽红豆杉素B的全合成。

One method of preparation new membrane materials was presented with putting multi-wall carbon nanotube and carboxylic multi-wall carbon nanotube in collodion solution.

分别将碳纳米管和羧基化碳纳米管均匀分散在火棉胶溶液中，采用流涎法制备出碳纳米管复合膜；并用分光光度法对样液、滤液中的间苯二酚和茜素红的吸光度进行了对比测定，以考察膜的吸附性能。

According the research, by inducing TiC into conventional carbon/ graphite materials, their flexural strength increased 13.4%, compressive strength increased 38.1%, void ratio decreased 16.9% in respective. The reason of the performance improvement is as follows: TiC decomposed during the process and hence Ti accelerate the graphitize process, which can increase the mechanical performance of the carbon/ceramic composite materials.

从研究结果可以看出，TiC掺杂可使碳陶瓷复合材料的抗折强度提高13.4%，抗压强度提高38.1%，气孔率降低16.9%；其机理在於TiC掺杂在碳陶瓷复合材料制备过程中能促进碳陶瓷石墨化，使晶体更加完整、细化，有利於力学性能的提高。

Considering the curvature effect on hooping of nearest-neighboring carbon atoms of armchair carbon nanotubes, the energy band, density of state and velocity of electron of armchair SWNT were analytically derived by using the tight-binding model and Born-Karman boundary condition.

在考虑曲率效应对扶手椅型碳纳米管最近邻碳原子交叠积分影响的情况下，利用紧束缚模型和玻恩－卡门边界条件解析地推导扶手椅型SWNT的能带、态密度和电子公有化运动速度，对扶手椅型SWNT电子性质的分析发现：考虑曲率效应后扶手椅型SWNT仍然是金属管，但其能带的总能减小，其态密度的导电平台变窄且其电子公有化运动速度变小。

Chiral centers of C5 and C8 are directly constructed in the key step of the diastereoselective propargylation from D--tartrate. The methylation and subsequent methoxycarbonylation result in desymmetrization of the terminal dialkynes. The α,β-unsaturated δ-lactone is synthesized after partial hydrogenation and lactonization.

由非天然酒石酸出发，利用双向非对映选择性的炔丙基化反应，在一步反应中同时构建C5和C8手性中心；然后通过末端炔基的甲基化、甲酯基化，延长碳链并对分子去对称化；内酯化得到关键中间体α，β-不饱和六元内酯，再经多步反应转化得到8-epi--Boronolide。

The properties such as high hardness,low friction coefficient,excellent wearability and photics properties,can provide the profound foundation for the application of carbon nitride materials in many fields.

许多研究小组已经合成出具有独特性能的氮化碳，其高硬度、低摩擦系数、良好的耐磨性、较好的光学性质等对氮化碳在广阔领域里的应用提供了坚实的基础。

The one carbon unit transfer reaction involving in the tetrahydrofolate coenzymes has caused great interest which is very important in the living system and has played an important role in the designing and syntheses compounds (especially the anti-cancer and LCD materials). In our study it was found that benzimidazolium salt has the ability to transfer one or two one-carbon unit and is a kind of new tetrahydrofolate coenzymes model. This research provides new method for biomimetic synthesis.

在非酶催化条件下，不仅实现了与生物体内相类似的一碳单元转移反应，而且可以转移具有不同官能团的取代&一碳单元&，使这种一碳单元转移反应传递的功能化一碳单元更加多样化，这方面强劲的研究工作进展，将为异常活跃的合成化学提供更多常规合成方法难以实现或实现不理想的仿生合成新方法。

The results available now indicate that glass-like carbon synthesized from phenolic resin is a non-graphitizing carbon, and consists of both sp 2-hybridized carbon atoms that form imperfect graphite structure and sp 3-hybridized carbon atoms that are due to the presence of disordered carbon; and in the fullerene-related structure of glass-like carbon, there exist some pentagons and heptagons carbon rings.

玻璃炭作为一种特殊炭材料已广泛应用于许多领域，其制备、性质、应用以及基本结构的研究已经取得了很大的进展，已有的研究结果表明酚醛树脂基玻璃炭是一种典型的非石墨化炭材料，由 sp2杂化态碳原子和 sp3杂态碳原子组成，且在其类富勒烯结构中存在五元环和七元环。

Carbon nanotubes are coated with Ni by a series of processes of optimization (oxidations, sensitization and activation) used to add activated sites on the surface of CNTs before electroless plating.

通过对镀Ni前碳纳米管的氧化、敏化和活化处理，在碳纳米管表面增加活化点，成功地在破纳米管表面镀上一层金属Ni，并用TEM对镀Ni前后的碳纳米管进行了表征。

The results indicated that OC in crop root and stubble was available for balance of soil OC in plough horizon, but was not enough generally as only mineral fertilizers were supplied. With no fertilizer, the biomass and the amount of OC of crop root and stubble both decreased year after year.

试验结果还表明，根茬有饥碳对维持耕层土壤有机碳的平衡有相当大的贡献，但在单施化肥时大多不足以补充矿化消牦；在不施肥时，根茬生物量和有机碳量均逐年下降。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。