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Retention of cations such as quats on Hypercarb is dueto the interaction with the electron cloud on the graphite; also,these are flat molecules which can align themselves closely to thesurface

而百草枯和敌草快在 Hypercarb 上保留依赖的是电子云和石墨化碳的作用,同时,这个平面分子和以很近的吸附在石墨化碳的表面

Using ethyne as source gas, CNTs were successfully synthesized by CVD method. By comparing different synthesis technics, the influences of parameter to the grow of CNTs, such as catalysts, growth time, reaction temperature and ratio of all kinds of carrier gases were investigated. The results showed that the influence of carrier gas, reaction temperature, and the growth time on synthesis of CNTs was significant. In conclusion, a better condition for carbon nanotube growth was obtained. Through analyzing Raman Spectrum of samples, GM and SWNTs' characteristic peak-RBM was indicated.

采用乙炔为碳源、氢气和氩气为载气,利用气相催化热解法在AAO模板上成功的制备出了纳米碳管,用TEM,SEM,EDS,Raman等表征方法研究了生长温度、裂解时间、载气含量和不同催化剂对碳纳米管的石墨化程度、产物形态的影响,指出了单壁碳纳米管的特征振动模式—径向呼吸振动模以及拉伸振动模式G模,缺陷导致的D模,并采用蒸金后的样品进行了场发射的测试,得到了F-N曲线,与理论符合较好。

The retention mechanism of dencichine on a porous graphitic carbon column seems to be mainly hydrophobic interaction according to the study.

对三七素在石墨化碳柱上的保留及其影响因素的研究结果表明:三七素在石墨化碳柱上的保留机理仍主要是疏水相互作用。

According to the distribution of the positive charges inthe surface of the cage, it can be expected that two -OH groups finally adding at two sites which arewithin one hexacyclic ring and in different sides of equator, which is accord with the conclusion resultedfrom thermodynamics

通过寻找并分析过度态的结构,发现酸化阳离子中处于赤道带6-6类碳原子上的羟基和两极区域5-5类碳原子上的羟基都有朝邻近赤道带碳原子上迁移的可能,结合碳笼上正电荷的分布特征,预计亲核水解作用将发生在赤道异侧六员环的对位,说明考虑动力学因素,最终获得1,4-加成富勒醇的可能性最大,该结论与热力学的结果一致。

Seven of them have not been reported.Their structures were confirmed by IR,~1HNMR,MS,and element analysis. 4.Meanwhile,the green methylation procedure of imides was developed by using dimethyl carbonate as methylation reagent.A series of imides,for example,phthalimide,3,4-dibromo-maleimide and succincide were used for substrates.The effects of DABCO(1,4-diazabicyclo [2.2.2]octane)and DBU(1,8-diazabicyclo[5.4.0]undec-7-ene)as a catalyst in this kind of reactions were investigated.2-Bromo-3-(1-methylindolyl-3-yl)-1-methyl-1H-pyrrole-2,5-dione was prepared by using dimethyl carbonate,which further expanded the use of dimethyl carbonate,as a green agent in organic synthesis.

在以硫酸二甲酯为甲基化试剂对3,4-二溴马来酰亚胺进行N-甲基化反应合成3,4-二溴-N-甲基马来酰亚胺的同时,以碳酸二甲酯为甲基化试剂,对3,4-二溴马来酰亚胺、邻苯二甲酰亚胺、琥珀酰亚胺等酰亚胺类化合物的N-甲基化反应进行了研究;考察了1,4-二氮杂双环[2.2.2]辛烷,1,8-二氮杂双环[5.4.0]十一碳-7-烯、碳酸钾和四丁基溴化铵等作为催化剂对碳酸二甲酯N-甲基化反应的反应时间和收率等的影响,并应用碳酸二甲酯为甲基化试剂,合成了N-甲基-3-溴-4-(1-甲基-吲哚-3)-马来酰亚胺。

Sulphonated carbon materials made from glucose were used as the solid acid and the support of Fe(superscript 2+) in the Fenton reaction, and the effects of the structure of carbon materials prepared by different methods on the Fe(superscript 2+) loading and the degradation efficiency of methyl orange were measured.

以葡萄糖为原料制备的磺化碳材料作为Fenton反应过程中固体酸及载体,研究了磺化碳材料结构对Fe(上标 2+)的负载能力及其对甲基橙降解反应的催化性能。

The enhance nient of the corrosion resistance laser dadoling of the CNTs/Ni60 coatings is due to that the reserved carbon nanotubes in the coatings segregate the corrosive medium and promote N-based alloy passivation, the formed phases of the carbide and the reserved carbon nanotubes homogenous distribution in the claddings resist die corrosion.

碳纳米管/镍基激光熔覆层耐腐蚀的原因在于熔覆层保留的碳纳米管使熔覆层更加致密,隔离了腐蚀介质,促进了镍基合金的钝化,从而提高了熔覆层的耐蚀性;同时,熔覆层中保留下来的碳纳米管和被分解的碳纳米管与金属基体形成碳化物,作为增强相均匀弥散在熔覆层中,它们的存在阻止了腐蚀坑的长大,因而蚀坑较小,耐腐蚀性得到提高。

Silicon oxide/Fluorinated amorphous carbon/Silicon oxide multiple-layered films and one-layered Fluorinated amorphous carbon films were prepared using Microwave electron cyclotron chemical vapor deposition reactor with SiH4, O2, CHF3 and CH4 as source gas and were annealed in nitrogen ambience in order to investigate their thermal stability.

食用80%Ar稀释的SiH4,O2,CHF3和CH4作为前驱气体,利用微波电子回旋共振等离子体化学气相沉积方法制备了氧化硅/氟化非晶碳膜/氧化硅(SiO_x/a-C:F/SiO_x)多层膜与单层的氟化非晶碳膜,并在N_2氛围退火处理中考察其热稳定性。

Due to the suppression of reverse water gas shift reaction by adding steam in feed gas, more CO〓 participated in and promoted CO〓 reforming of CH〓 reaction, higher catalytic activity and less carbon deposition were obtained. On the surface of used catalyst there were two kinds of carbon species deposited on catalyst, one was decomposed CH〓 fragment, and the another was graphiticlike carbon.

在反应后催化剂表面有两类碳物种,一类在250~350℃出现的少量α-碳,应主要是活性高的CH〓解离碎片,一类是在700℃附近出现的β-碳,应是导致催化剂失活的类石墨化碳。

Type shown above, the lower temperature as allyl methyl carbocations (1) is greater than the stability of carbocations (2), so the potential energy diagram in the reaction pathway for the carbon embodied in the positive ion hybrid resonance body and Chloride Cl-if by 1,4 - addition will have to experience higher ...

如上式所示,较低温度下由于烯丙基甲基碳正离子(1)的稳定性大于碳正离子(2),所以在反应历程势能图中体现为碳正离子共振杂化体与氯离子Cl-若按1,4-加成则要经历较高。。。

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