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In this paper, acetanilide used as start material was chlorosulfonated, then reacted with alkylamines with different length of carbon chain to prepare 4 p-acetylaminophenylsulfonylalkylamine.

本文以乙酰苯胺为起始原料,经氯磺化后分别和不同碳链的正烷基胺反应制得4种不同碳链长度的对乙酰氨基苯磺酰烷基胺,将其水解后制得了对氨基苯磺酰正丁胺、对氨基苯磺酰正辛胺、对氨基苯磺酰正十二胺和对氨基苯磺酰正十八胺。

The aromatization performance of Mo/HZSM-5 with different molybdenum species has not been well investigated.

另一方面,使用MoO_3/HZSM-5进行甲烷芳构化反应时,反应过程中钼物种会被还原和碳化形成多种钼物种,但关于这些不同钼物种的Mo/HZSM-5催化剂的芳构化性能尚不清楚或存在争议。

The research showed that one of the main causes of forming soot was excessive carbonization during depositing pyrolytic carbon.

研究表明:热解碳沉积过程中炭黑形成的主要原因之一是反应物气体在气相中过度碳化。

And then the functionalized carbon nanotube, partial platinum salt and all transition metal M salt are stirred and reflow for certain time, added with rest platinum salt to continue to reflow, cooled, washed centrifugally, dried and carried out heating treatment in a hydrogen atmosphere, thus obtaining the anchoring platinum catalyst of the transition metal on the carbon nanotube.

然后将功能化的碳纳米管与部分铂盐和全部过渡金属M盐在多元醇溶剂中搅拌回流一定时间后,加入剩余的铂盐继续回流,冷却,离心洗涤,烘干,最后在氢气气氛中热处理,得到碳纳米管上过渡金属锚定铂催化剂。

The carbon molecules combine to form an equilateral triangle, the most ideal and stable type of structure.

这电离罩是利用高电压使碳分子电离化,再用分子工程技术加压降温,重整碳晶体的结构。

The quantities of the carbide in these samples were determined by gas mass spectrometer.

本文讨论碳—铝复合丝高温浸渍中的行为,在高温下碳纤维和铝发生了界面反应,反应形成了碳化铝脆性层。

By using the a device being similar to water segregator and by controlling the temperature, cyclization of the intermediate product in chloroform reduced carbonization and gave 2-dodecaneanthraquinane in 68.1% yielding.

以十二烷基苯和苯酐为起始原料,经酰基化、关环和磺化三步反应合成了3-十二烷基蒽醌磺酸;并进一步改进和优化了合成工艺条件:即在催化剂三氯化铝过量50%并有三乙胺存在的条件下,中间体2-(4-十二烷基苯甲酰基)苯甲酸收率为72.45%;关环反应采用氯仿作溶剂,利用类似分水器的装置有效控制反应温度以减少碳化,2-十二烷基蒽醌的收率为68.1%。

The CNTs prepared by temperature programming CVD method were characterized with diameters of 8~12 nm, surface purity, good graphitic and a high yield.

程序升温CVD法制得的纳米碳管管径在8-12nm之间、管壁洁净、石墨化程度好,纳米碳管的产量很高。

The present dissertation deals with:(1) Exploring the feasibility of the CO〓 methanation and the conversion CH〓/H〓 into C〓 hydrocarbons under plasma with catalyst at ambient temperature and atmosphere.(2) Designing a reactor and preparing some catalysts suited for the conversion of carbon dioxide via the cooperation effect of plasma and catalysts.(3) Optimizing reaction conditions of conversion carbon dioxide to C〓 hydrocarbons in the proposed process.(4) Studying the reaction mechanism of conversion carbon dioxide to C〓 hydrocarbons under plasma by using in situ OES technology.(5) By the results of characterizing coked catalysts, exploring the reasons that result in the coking of catalyst and the paths for decreasing the deposit in the catalyst under plasma.(6) Analyzing the energy efficiency of the plasma catalysis and exploring the paths for improving the energy efficiency.

论文的主要研究工作包括:(1)探索脉冲电晕等离子体与催化剂共同作用CO〓/H〓甲烷化和由CH〓/H〓合成C〓烃反应的可行性;(2)研制等离子体催化CO〓转化的反应器和适配的催化剂;(3)优化等离子体催化CO〓转化制C〓烃反应的工艺条件和电参数;(4)利用原子发射光谱原位技术对等离子体反应的诊断结果,对等离子体催化CO〓转化制C〓烃反应的机理进行推断;(5)通过对积碳催化剂的表征结果,分析积碳的类型及其成因,并探讨减少积碳的途径;(6)通过对等离子体催化CO〓转化制C〓烃反应能量效率的分析,探讨提高等离子体催化反应能量效率的途径。

The experimental results denoted that the finer pearlite along the austenite boundaries in the as-cast Cr30Ni20NRE steel disappeared first under long-term and high-temperature service condition, and that an umber of Cr- richened carbides were formed due to unila-teral carburizing at long-term and high- temperature, consequently causing Ni to concentrate, bulging and calalyzing decomposition of the carburizing gas.

试验结果表明,长期在高温条件下服役,铸态Cr30Ni20NRE耐热钢中沿奥氏体晶界的珠光首先融入奥氏体,长期高温单边渗碳形成大量富铬碳化物,促使镍富集并起泡形成瘤状物,催化含碳气体的分解;表层瘤状物使辐射管表层疏松,表面积扩张,加快了碳向基体的渗入,提供了碳化物持续长大的条件,并引起沿碳化物周边开裂和奥氏体基体严重萎缩;合金元素的重新分布造成主合金元素铬和镍产生两极分化,镍和硅的富集促使石墨化,与侵入的氧形成内部氧化空洞和膨胀疏松,最终导致构件穿孔失效。

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