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碳二亚胺

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In addition, the reactions of the carbodiimide with alkanol and substituted phenol were studied firstly.

研究了4-酯基吡唑-5-碳二亚胺(Pyrazole-5-N=C=N-Ar)与NH_3,RNH_2,R_2NH和RNHNH_2成环反应的选择性。

This is probably due to the geometry of the intermediate. 3. The cyclization of carbodiimide 2 with 1H-1, 2, 4-triazole in presence of solid potassium carbonate was studied firstly. The interesting color change was observed during the reaction process. The condition for cyclization was researched.

首次研究了碳二亚胺2与1H-1,2,4-三唑在固体碳酸钾存在下的成环反应,结果表明该反应仅生成1-N产物,而且在反应过程中出现了有趣的颜色变化,研究了该成环反应的条件。

Because of recent research in our laboratory on carbodiimide chemistry and isocyanate prepolymer synthesis, we have found a versatile facile approach of making macro-ring compounds.

由於本实验室近年来致力於碳二亚胺化学及合成异氰酸盐预聚物之研究,由延伸其领域而发现快速又简易的方法可制备反应型巨环状高分子中间体。

The reaction of carbodiimide 14 with various neucleophiles was investigated. The selectivity of cyclization of the carbodiimide 14 with NH_3, RNH_2, R_2NH and NH_2NH_2 were studied, some of the gualidene-type intermediates were isolated and the possible mechanism was suggested.

探讨了碳二亚胺14与各种亲核试剂如NH_3、RNH_2、R_2NH以及水合肼的成环反应的选择性,并分离得到了部分胍中间体,提出了反应可能的机理,对反应的选择性进行了合理的解释。

In the final step of the synthetic pathway leading to cabergoline, an allylic acid intermediate of Formula is reacted with N-(3-dimethylaminopropyl)-N-ethyl carbodiimide to produce cabergoline, i.e.

在卡麦角林合成路径的最后一步,分子式中的一个烯丙酸基中间体同碳二亚胺耦联剂反应生成卡麦角林,如

The cyclization of carbodiimide 2 with substituted phenol in presence of solid potassium csrtjonaic was studied TiisX'iy. Tne resuYls show that It is a new mM method fOT preparing of 2-aryloxyimidazolones.

首次研究了碳二亚胺2与酚在碱催化条件下的成环反应,结果表明这是一种温和的制备2-芳氧基咪唑啉酮的新方法。

The carboxyl groups of QDES were used to couple the free amino groups of EAH Sepharose 4B with the carbodiimide coupling method, and immobilized density was 5μmol/ml.

通过碳二亚胺反应将四肽配基QDES固定在商品介质EAH Sepharose 4B上制备出了配基固定化密度为5μmol/ml的亲和吸附介质,并利用亲和色谱柱考察了其吸附蛋白质特性。

Three immobilization modes of antigen to the polymers in the pH-sensitive phase separation immunoassay were investigated and compared. The results showed that the immobilization mode in the presence of N-ethyl-N'-(3-dimethylaminopropyl)carbodiimide hydrochloride rendered the most desirable results. The immobilization efficiencies and immunological reaction activities of immobilized antigen of this mode were improved over the other two modes.

本文研究并比较了pH敏感相分离免疫分析中抗原在高分子上的三种固定化模式,结果显示由碳二亚胺偶联的固定模式效果最好,固定化效率、固定抗原的免疫反应活性较之另外两种模式均得到了提高。

The conjugation of MMS and Ab (ready for Reagent 1, R1): Chose the 3μm diameter Carboxyl MMS and use the carbodiimide cross-link technique activate the MMS with EDC and NHS in different concentration, then linked mice anti-HBsAg-IgG and mice anti-HCcAg-IgG on them.

磁微粒的活化及其与抗体的连接:选择粒径3μm的羧基化磁微粒,采用碳二亚胺共价交联法,在活化剂EDC与NHS的不同浓度组合条件下活化磁微粒,选择最适的活化剂浓度组合。

Peptides are traditionally synthesized in liquid phase, such methods are DCC, mixed anhydrides, acyl chloride and azide etc., which provide more choices for peptides synthesis.

传统的肽类合成多采用液相化学合成,常用的包括碳二亚胺法,混合酸酐法、酰氯法、叠氮物法等等,为多肽的合成提供了多种选择。

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